ChemicalBook--->CAS DataBase List--->14285-68-8

14285-68-8

14285-68-8 Structure

14285-68-8 Structure
IdentificationMore
[Name]

RHENIUM CARBONYL
[CAS]

14285-68-8
[Synonyms]

DECACARBONYLDIRHENIUM
DIRHENIUM DECACARBONYL
DODECACARBONYLDIRHENIUM
RHENIUM CARBONYL
RHENIUM DECACARBONYL
decacarbonyldi-rheniu(thetae-thetae)
Re2(CO)10
Rhenium carbonyl (Re2(CO)10)
Rhenium, decacarbonyldi-,
Rhenium, decacarbonyldi-, (Re-Re)
Dirhenium decacarbonyl, made from 99.99% pure raw material, sublimed
Rheniumcarbonyl,98%
Decacarbonyldirhenium, 95+%
Dirhenium decacarbonyl, sublimed
[EINECS(EC#)]

238-202-8
[Molecular Formula]

C10O10Re2
[MDL Number]

MFCD00011198
[Molecular Weight]

652.52
[MOL File]

14285-68-8.mol
Chemical PropertiesBack Directory
[Appearance]

white to pale yellow crystalline solid
[Melting point ]

170 °C (dec.)(lit.)
[density ]

2,87 g/cm3
[storage temp. ]

Store below +30°C.
[solubility ]

soluble in Dichloromethane
[form ]

crystal
[color ]

white to yellow
[Specific Gravity]

2.87
[Water Solubility ]

soluble in most organic solvents [KIR82]
[InChI]

1S/10CO.2Re/c10*1-2;;
[InChIKey]

ZIZHEHXAMPQGEK-UHFFFAOYSA-N
[SMILES]

[ReH].[ReH].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+]
[CAS DataBase Reference]

14285-68-8(CAS DataBase Reference)
[EPA Substance Registry System]

Rhenium, decacarbonyldi-, (Re-Re) (14285-68-8)
Hazard InformationBack Directory
[Chemical Properties]

light greenish-yellow crystals
[Uses]

Decacarbonyldirhenium is a key starting material used for the synthesis of other rhenium carbonyl complexes. It plays an important role in metathesis, reforming and hydrogenation reactions. It is used as a catalyst to promote silation of alcohols and in the preparion of silyl ethers.
[reaction suitability]

core: rhenium
reagent type: catalyst
[storage]

stable to air and to strong acids; may be stored indefinitely at ambient temperature; ignites in air above 140 °C.
Safety DataBack Directory
[Hazard Codes ]

Xn
[Risk Statements ]

R20:Harmful by inhalation.
[Safety Statements ]

S36:Wear suitable protective clothing .
[RIDADR ]

UN 3466 6.1/PG 3
[WGK Germany ]

3
[TSCA ]

Yes
[HazardClass ]

6.1
[PackingGroup ]

III
[HS Code ]

29310099
[Storage Class]

6.1C - Combustible acute toxic Cat.3
toxic compounds or compounds which causing chronic effects
[Hazard Classifications]

Acute Tox. 3 Inhalation
Spectrum DetailBack Directory
[Spectrum Detail]

RHENIUM CARBONYL(14285-68-8)IR
RHENIUM CARBONYL(14285-68-8)Raman
RHENIUM CARBONYL(14285-68-8)FT-IR
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Dirhenium decacarbonyl, 98%(14285-68-8)
[Alfa Aesar]

Decacarbonyldirhenium, 96%(14285-68-8)
[Sigma Aldrich]

14285-68-8(sigmaaldrich)
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