ChemicalBook--->CAS DataBase List--->1435-52-5

1435-52-5

1435-52-5 Structure

1435-52-5 Structure
IdentificationMore
[Name]

1,4-DIBROMO-2-FLUOROBENZENE
[CAS]

1435-52-5
[Synonyms]

1,4-DIBROMO-2-FLUOROBENZENE
2,5-DIBROMO-FLUOROBENZENE
2-FLUORO-4-BROMOBROMOBENZENE
1,4-Dibromo-2-fluorobenzene 98%
1,4-Dibromo-2-fluorobenzene98%
1,4-Dibromo-2-fluorobenzene, 99+%
[EINECS(EC#)]

629-432-3
[Molecular Formula]

C6H3Br2F
[MDL Number]

MFCD00010603
[Molecular Weight]

253.89
[MOL File]

1435-52-5.mol
Chemical PropertiesBack Directory
[Appearance]

white crystalline mass
[Melting point ]

33-36 °C (lit.)
[Boiling point ]

216 °C (lit.)
[density ]

2.0491 (rough estimate)
[refractive index ]

1.5770 (estimate)
[Fp ]

215 °F
[storage temp. ]

Sealed in dry,Room Temperature
[form ]

powder to lump to clear liquid
[color ]

White or Colorles to Yellow to Orange
[Water Solubility ]

Insoluble in water.
[FreezingPoint ]

32.0 to 34.0 ℃
[BRN ]

3236451
[InChI]

InChI=1S/C6H3Br2F/c7-4-1-2-5(8)6(9)3-4/h1-3H
[InChIKey]

WNSNPGHNIJOOPM-UHFFFAOYSA-N
[SMILES]

C1(Br)=CC=C(Br)C=C1F
[CAS DataBase Reference]

1435-52-5(CAS DataBase Reference)
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H315-H319-H335
[Precautionary statements ]

P261-P264-P271-P280-P302+P352-P305+P351+P338
[Hazard Codes ]

Xi,Xn
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
R22:Harmful if swallowed.
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
S37/39:Wear suitable gloves and eye/face protection .
[WGK Germany ]

3
[Hazard Note ]

Irritant
[HazardClass ]

IRRITANT
[HS Code ]

29039990
[Storage Class]

11 - Combustible Solids
[Hazard Classifications]

Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Ethanol-->Sodium hydroxide-->Hydrochloric acid-->Sodium nitrite-->Stannous chloride dihydrate-->Fluoroboric acid-->2,5-Dibromonitrobenzene
[Preparation Products]

2,5-Dibromoanisole-->5-Bromo-2,3-dihydro-1-benzofuran-->2-Fluoro-4-(methoxycarbonyl)benzeneboronic acid-->1,4-Diethynyl-2-fluorobenzene-->(2,5-dibroMo-4- fluoroaniline
Hazard InformationBack Directory
[Chemical Properties]

white crystalline mass
[Uses]

1,4-Dibromo-2-fluorobenzene was used in preparation of 1,4-bis(2-hydroxy-2-methyl-3-butynyl)-2-fluorobenzene.
[General Description]

The Suzuki-Miyaura reaction of 1,4-dibromo-2-fluorobenzene with arylboronic acids yields fluorinated para-terphenyls.
Spectrum DetailBack Directory
[Spectrum Detail]

1,4-DIBROMO-2-FLUOROBENZENE(1435-52-5)MS
1,4-DIBROMO-2-FLUOROBENZENE(1435-52-5)1HNMR
1,4-DIBROMO-2-FLUOROBENZENE(1435-52-5)13CNMR
1,4-DIBROMO-2-FLUOROBENZENE(1435-52-5)IR1
1,4-DIBROMO-2-FLUOROBENZENE(1435-52-5)IR2
1,4-DIBROMO-2-FLUOROBENZENE(1435-52-5)Raman
Well-known Reagent Company Product InformationBack Directory
[Alfa Aesar]

1,4-Dibromo-2-fluorobenzene, 98%(1435-52-5)
[Sigma Aldrich]

1435-52-5(sigmaaldrich)
[TCI AMERICA]

1,4-Dibromo-2-fluorobenzene,>98.0%(GC)(1435-52-5)
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