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1445972-29-1

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1445972-29-1 Structure

1445972-29-1 Structure
IdentificationBack Directory
[Name]

Methanesulfonato[2-(di-1-adamantylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl](2'-amino-1,1'-biphenyl-2-yl)palladium(II), min. 98% [AdBrettPhos Palladacycle Gen. 3]
[CAS]

1445972-29-1
[Synonyms]

AdBrettPhos Pd G3
AdBrettPhos Palladacycle Gen. 3
Methanesulfonato[2-(di-1-adamantylphosphino)-3,6-dimethoxy-2...
bis(1-adamantyl)-[3,6-dimethoxy-2-(2,4,6-triisopropylphenyl)phenyl]phosphane
bis(adamantan-1-yl)[3,6-dimethoxy-2',4',6'-tris(pro pan-2-yl)-[1,1'-biphenyl]-2-yl]phosphane
Methanesulfonato[2-(di-1-adamantylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl](2'-amino-1,1'-biphenyl-2-yl)palladium(II)
Methanesulfonato[2-(di-1-adamantylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl](2'-amino-1,1'-biphenyl-2-yl)palladium(II)
Methanesulfonato[2-(di-1-adamantylpChemicalbookhosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl](2'-amino-1,1'-biphenyl-2-yl)palladium(II)
Methanesulfonato[2-(di-1-adamantylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl](2'-amino-1,1'-biphenyl-2-yl)palladium(II), AdBrettPhos Palladacycle Gen. 3
METHANESULFONATO[2-(DI-1-ADAMANTYLPHOSPHINO)-3,6-DIMETHOXY-2',4',6'-TRI-I-PROPYL-1,1'-BIPHENYL](2'-AMINO-1,1'-BIPHENYL-2-YL)PALLADIUM(II),MIN.98%[ADBRETTPHOSPALLADACYCLEGEN.3]
[Molecular Formula]

C56H74NO5PPdS
[MDL Number]

MFCD28411661
[MOL File]

1445972-29-1.mol
[Molecular Weight]

1010.66
Chemical PropertiesBack Directory
[Melting point ]

251-253 °C
[storage temp. ]

2-8°C, protect from light, stored under nitrogen
[form ]

solid
[color ]

brown to green
[InChIKey]

OZFYYHNERORONM-UHFFFAOYSA-M
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H319-H315
[Precautionary statements ]

P264-P280-P302+P352-P321-P332+P313-P362-P264-P280-P305+P351+P338-P337+P313P
[WGK Germany ]

WGK 3
[Storage Class]

11 - Combustible Solids
Questions And AnswerBack Directory
[Reaction]

Palladium catalyst used in the highly selective monoarylation of ammonia. Reactions of 1445972-29-1
Hazard InformationBack Directory
[Uses]

Buchwald 3rd Generation Pd Precatalyst adorned by the bulk di-adamntyl BrettPhos ligand. This complex has been used in the monoarylation of ammonia, displaying apptitude for otherwise difficult 5-member heterocyclic substrates.

Mild and Highly Selective Palladium-Catalyzed Monoarylation of Ammonia Enabled by the Use of Bulky Biarylphosphine Ligands and Palladacycle Precatalysts
[reaction suitability]

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
Spectrum DetailBack Directory
[Spectrum Detail]

AdBrettPhos Pd G3(1445972-29-1)31PNMR
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