1445972-29-1

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1445972-29-1 Structure

Identification	Back Directory
[Name] Methanesulfonato[2-(di-1-adamantylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl](2'-amino-1,1'-biphenyl-2-yl)palladium(II), min. 98% [AdBrettPhos Palladacycle Gen. 3]
[CAS] 1445972-29-1
[Synonyms] AdBrettPhos Pd G3 AdBrettPhos Palladacycle Gen. 3 Methanesulfonato[2-(di-1-adamantylphosphino)-3,6-dimethoxy-2... bis(1-adamantyl)-[3,6-dimethoxy-2-(2,4,6-triisopropylphenyl)phenyl]phosphane bis(adamantan-1-yl)[3,6-dimethoxy-2',4',6'-tris(pro pan-2-yl)-[1,1'-biphenyl]-2-yl]phosphane Methanesulfonato[2-(di-1-adamantylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl](2'-amino-1,1'-biphenyl-2-yl)palladium(II) Methanesulfonato[2-(di-1-adamantylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl](2'-amino-1,1'-biphenyl-2-yl)palladium(II) Methanesulfonato[2-(di-1-adamantylpChemicalbookhosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl](2'-amino-1,1'-biphenyl-2-yl)palladium(II) Methanesulfonato[2-(di-1-adamantylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl](2'-amino-1,1'-biphenyl-2-yl)palladium(II), AdBrettPhos Palladacycle Gen. 3 METHANESULFONATO[2-(DI-1-ADAMANTYLPHOSPHINO)-3,6-DIMETHOXY-2',4',6'-TRI-I-PROPYL-1,1'-BIPHENYL](2'-AMINO-1,1'-BIPHENYL-2-YL)PALLADIUM(II),MIN.98%[ADBRETTPHOSPALLADACYCLEGEN.3]
[Molecular Formula] C56H74NO5PPdS
[MDL Number] MFCD28411661
[MOL File] 1445972-29-1.mol
[Molecular Weight] 1010.66

Safety Data	Back Directory
[Symbol(GHS) ] GHS07
[Signal word ] Warning
[Hazard statements ] H319-H315
[Precautionary statements ] P264-P280-P302+P352-P321-P332+P313-P362-P264-P280-P305+P351+P338-P337+P313P

Questions And Answer	Back Directory
[Reaction] Palladium catalyst used in the highly selective monoarylation of ammonia.

Hazard Information	Back Directory
[Uses] Buchwald 3rd Generation Pd Precatalyst adorned by the bulk di-adamntyl BrettPhos ligand. This complex has been used in the monoarylation of ammonia, displaying apptitude for otherwise difficult 5-member heterocyclic substrates. Mild and Highly Selective Palladium-Catalyzed Monoarylation of Ammonia Enabled by the Use of Bulky Biarylphosphine Ligands and Palladacycle Precatalysts
[reaction suitability] reaction type: Buchwald-Hartwig Cross Coupling Reaction reaction type: Cross Couplings reaction type: Heck Reaction reaction type: Hiyama Coupling reaction type: Negishi Coupling reaction type: Sonogashira Coupling reaction type: Stille Coupling reaction type: Suzuki-Miyaura Coupling reagent type: catalyst

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