ChemicalBook--->CAS DataBase List--->1447963-73-6

1447963-73-6

1447963-73-6 Structure

1447963-73-6 Structure
IdentificationBack Directory
[Name]

Palladacycle Gen. 3
[CAS]

1447963-73-6
[Synonyms]

Methanesulfonato(2-dicyclohexylphosphino-2',6'-bis(dimethylamino)-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II), 98%
[Molecular Formula]

C41H54N3O3PPdS
[MOL File]

1447963-73-6.mol
[Molecular Weight]

806.35
Chemical PropertiesBack Directory
[Melting point ]

176-178 °C (decomposition)
[form ]

Powder
[color ]

white to off-white
[InChIKey]

BYZMMBLECCTRMT-UHFFFAOYSA-N
[SMILES]

P(C1CCCCC1)(C1CCCCC1)(C1C=CC=CC=1C1C(=CC=CC=1N(C)C)N(C)C)[Pd+2]1(NC2=CC=CC=C2C2=CC=CC=[C-]12)[O-]S(=O)(=O)C
Questions and Answers (Q&A)Back Directory
[Reactions]

  1. Catalyst for the highly selective cross-coupling of secondary alkylzinc reagents with heteroaryl halides
  2. Catalyst for the completely linear-selective Negishi cross-coupling of allylzinc halides with aryl and vinyl electrophiles
Reactions of 1447963-73-6
Hazard InformationBack Directory
[General Description]

CPhos Pd G3 is a modified G3 precatalyst (G3′). It has been synthesized by Buchwald and coworkers from second generation (G2) precatalyst by methylation of the amino group present on biphenyl backbone. It is a useful catalyst for various cross-coupling reactions. They are versatile catalysts. They have long life in solution and are readily soluble in various organic solvents. G3- precatalysts have been employed in various C-N bond forming reactions.
[reaction suitability]

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
reaction type: Cross Couplings
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