ChemicalBook--->CAS DataBase List--->1450-74-4

1450-74-4

1450-74-4 Structure

1450-74-4 Structure
IdentificationMore
[Name]

1-(5-Chloro-2-hydroxyphenyl)ethanone
[CAS]

1450-74-4
[Synonyms]

1-(5-CHLORO-2-HYDROXYPHENYL)-1-ETHANONE
1-(5-CHLORO-2-HYDROXYPHENYL)ETHAN-1-ONE
1-(5-CHLORO-2-HYDROXYPHENYL)ETHANONE
2'-HYDROXY-5'-CHLORO ACETOPHENONE
2-HYDROXY-5-CHLORO ACETOPHENONE
5'-CHLORO-2'-HYDROXYACETOPHENONE
5-CHLORO-2-HYDROXYACETOPHENONE
AKOS BB-6937
ASISCHEM D38764
SALOR-INT L497495-1EA
2-Acetyl-4-chlorophenol
Acetophenone, 5'-chloro-2'-hydroxy-
Acetophenone,5-chloro-2-hydroxy-
5'-Chloro-2'-Hydroxy Acetophenone 2'-Hydorxy-5'-Chloro Acetophenone
2'-Hydorxy-5'-ChloroAcetophenone
[EINECS(EC#)]

215-916-8
[Molecular Formula]

C8H7ClO2
[MDL Number]

MFCD00067788
[Molecular Weight]

170.59
[MOL File]

1450-74-4.mol
Chemical PropertiesBack Directory
[Appearance]

slightly yellow crystalline powder or chunks
[Melting point ]

54-56 °C(lit.)
[Boiling point ]

126-128 °C28 mm Hg(lit.)
[density ]

1.2315 (rough estimate)
[refractive index ]

1.5590 (estimate)
[Fp ]

107-109°C/12mm
[storage temp. ]

Sealed in dry,Room Temperature
[pka]

9.72±0.18(Predicted)
[BRN ]

1365589
[InChIKey]

XTGCUDZCCIRWHL-UHFFFAOYSA-N
[CAS DataBase Reference]

1450-74-4(CAS DataBase Reference)
[NIST Chemistry Reference]

Ethanone, 1-(5-chloro-2-hydroxyphenyl)-(1450-74-4)
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
S37/39:Wear suitable gloves and eye/face protection .
[WGK Germany ]

3
[Hazard Note ]

Irritant
[HS Code ]

29147000
Hazard InformationBack Directory
[Chemical Properties]

slightly yellow crystalline powder or chunks
[Uses]

5′-Chloro-2′-hydroxyacetophenone (5-chloro-2- hydroxyacetophenone) may be used in the synthesis of:
  • 6-chloro-2-methyl-4H-chrome-4-one
  • 1-(2-hydroxyphenyl)-5-phenyl-2,4-pentadien-1-ones
  • 1-(2-hydroxyphenyl)-5-phenyl-2,4-pentadien-1-ones
  • 2-styrenyl allyl ether
[Preparation]

Preparation by Fries rearrangement of 4-chlorophenyl acetate with aluminium chloride without solvent between 110° and 200°(90–100% yield).
[General Description]

5′-Chloro-2′-hydroxyacetophenone (5-chloro-2- hydroxyacetophenone) on condensation with salicylhydrazide yields Schiff base, which is reported to form copper(II) complexes. Dipole moment of 5-chloro-2- hydroxyacetophenone has been evaluated in benzene solution.
Spectrum DetailBack Directory
[Spectrum Detail]

1-(5-Chloro-2-hydroxyphenyl)ethanone(1450-74-4)MS
1-(5-Chloro-2-hydroxyphenyl)ethanone(1450-74-4)IR1
1-(5-Chloro-2-hydroxyphenyl)ethanone(1450-74-4)IR2
1-(5-Chloro-2-hydroxyphenyl)ethanone(1450-74-4)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

5'-Chloro-2'-hydroxyacetophenone, 99%(1450-74-4)
[Alfa Aesar]

5'-Chloro-2'-hydroxyacetophenone, 99%(1450-74-4)
[Sigma Aldrich]

1450-74-4(sigmaaldrich)
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