| Identification | More | [Name]
Rhodium carbonyl chloride | [CAS]
14523-22-9 | [Synonyms]
1-TETRACARBONYLDI-MU-CHLORODIRHODIUM(I)
BIS(CHLORODICARBONYL)RHODIUM
CHLORODICARBONYLRHODIUM(I) DIMER
CHLORODICARBONYL RHODIUM (II) DIMER
DI-MU-CHLORO-TETRACARBONYLDIRHODIUM
RHODIUM CARBONYL CHLORIDE
RHODIUM(I) DICARBONYL CHLORIDE DIMER
Tetracarbonyldi--chlorodirhodium(I)
TETRACARBONYLDI-MU-CHLORODIRHODIUM(I)
TETRACARBONYLDI-U-CHLORODIRHODIUM(I)
Bis(dicarbonylrhodium chloride)
Chlorodicarbonylrhodium dimer
Dicarbonylchlororhodium dimer
Dichlorodirhodiumtetracarbonyl
Di-mu-Chlorotetracarbonyldirhodium(I)
mu-Dichlorotetracarbonyldirhodium
Rhodium carbonyl chloride dimer
Rhodium dicarbonyl chloride dimer
Rhodium, tetracarbonyldi-mu-chlorodi-
Rhodium, tetracarbonyltetrachlorodi- | [EINECS(EC#)]
238-540-6 | [Molecular Formula]
CH2Cl3ORh | [MDL Number]
MFCD00135610 | [Molecular Weight]
239.29 | [MOL File]
14523-22-9.mol |
| Chemical Properties | Back Directory | [Appearance]
red to brownish crystals, crystalline powder or | [Melting point ]
120-125 °C (dec.)(lit.)
| [storage temp. ]
2-8°C
| [solubility ]
It is soluble in organic or non-aqueous solvent. | [form ]
crystal | [color ]
red | [Water Solubility ]
soluble in most organic solvents; insoluble aliphatic hydrocarbons [MER06] | [Sensitive ]
Air & Moisture Sensitive | [Detection Methods]
T | [Merck ]
14,8187 | [Exposure limits]
ACGIH: TWA 1 mg/m3
NIOSH: IDLH 100 mg/m3; TWA 0.1 mg/m3 | [InChI]
InChI=1S/4CO.2Cl.2Rh/c4*1-2;;;;/q;;;;2*+1;2*-1 | [InChIKey]
ODYPMWFHWPMOKS-UHFFFAOYSA-N | [SMILES]
[Cl+]1[Rh-][Cl+][Rh-]1.[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-] | [CAS DataBase Reference]
14523-22-9(CAS DataBase Reference) | [NIST Chemistry Reference]
Dirhodium tetracarbonyl dichloride(14523-22-9) | [Storage Precautions]
Moisture sensitive |
| Hazard Information | Back Directory | [Chemical Properties]
red to brownish crystals, crystalline powder or | [Uses]
Catalyst for organic reactions.
| [reaction suitability]
core: rhodium
reagent type: catalyst | [Synthesis]
Synthesis of tetracarbonyl dichlorodirhodium, RhCl3-3H2O+CO→Rh2Cl2(CO)4+COCl2Appropriate amount of rhodium(II) chloride trihydrate crystals was ground into a fine powder of 30-100 mesh with a mortar and pestle, and it was uniformly spread on a sand cor |
| Safety Data | Back Directory | [Symbol(GHS) ]
GHS07 | [Signal word ]
Warning | [Hazard statements ]
H302 | [Precautionary statements ]
P264-P270-P301+P312a-P330-P501a | [Hazard Codes ]
T | [Risk Statements ]
R36/38:Irritating to eyes and skin .
R25:Toxic if swallowed. | [Safety Statements ]
S22:Do not breathe dust .
S24/25:Avoid contact with skin and eyes . | [RIDADR ]
UN3466 | [WGK Germany ]
3
| [F ]
10-21-23 | [TSCA ]
No | [HazardClass ]
6.1 | [PackingGroup ]
III | [HS Code ]
28439000 |
|
| Company Name: |
J & K SCIENTIFIC LTD.
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| Telephone: |
18210857532 18210857532 |
| Website: |
https://www.jkchemical.com |
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Alfa Aesar
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400-6106006 |
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http://chemicals.thermofisher.cn |
| Company Name: |
Energy Chemical
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400-0056266 |
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www.energy-chemical.com |
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