ChemicalBook--->CAS DataBase List--->1477-55-0

1477-55-0

1477-55-0 Structure

1477-55-0 Structure
IdentificationMore
[Name]

1,3-Bis(aminomethyl)benzene
[CAS]

1477-55-0
[Synonyms]

1,3-Benzenedimethanamine
1,3-BIS(AMINOMETHYL)BENZENE
ALPHA,ALPHA'-DIAMINO-M-XYLENE
LABOTEST-BB LT00053687
m-phenylenebis(methylamine)
M-XYLENE-A,A'-DIAMINE
M-XYLENE-ALPHA,ALPHA'-DIAMINE
M-XYLENE DIAMINE
M-XYLYLENE-ALPHA,ALPHA'-DIAMINE
M-XYLYLENEDIAMINE
OMEGA,OMEGA'-DIAMINO-M-XYLENE
RARECHEM AL BW 0017
,’-Diamino-m-xylene
1,3-Bis-aminomethylbenzen
1,3-bis-aminomethylbenzen(czech)
1,3-di(aminomethyl)benzene
1,3-phenylenebismethylamine
1,3-xylenediamine
1,3-Xylylenediamine
3-(Aminomethyl)benzylamine
[EINECS(EC#)]

216-032-5
[Molecular Formula]

C8H12N2
[MDL Number]

MFCD00008119
[Molecular Weight]

136.19
[MOL File]

1477-55-0.mol
Chemical PropertiesBack Directory
[Appearance]

m-Xylene-α,α0-diamine is a colorless liquid.
[Melting point ]

14°C
[Boiling point ]

265 °C745 mm Hg(lit.)
[density ]

1.032 g/mL at 25 °C(lit.)
[vapor pressure ]

15 mm Hg ( 145 °C)
[refractive index ]

n20/D 1.571(lit.)
[Fp ]

>230 °F
[storage temp. ]

2-8°C, protect from light
[solubility ]

Chloroform (Slightly), Methanol (Slightly)
[form ]

Liquid
[pka]

9.37±0.10(Predicted)
[color ]

Clear slightly yellow
[Water Solubility ]

Miscible
[BRN ]

1099911
[InChI]

1S/C8H12N2/c9-5-7-2-1-3-8(4-7)6-10/h1-4H,5-6,9-10H2
[InChIKey]

FDLQZKYLHJJBHD-UHFFFAOYSA-N
[SMILES]

NCc1cccc(CN)c1
[LogP]

0.18 at 25℃
[Uses]

Manufacture of polyamide fibers and resins, as a curing agent.
[CAS DataBase Reference]

1477-55-0(CAS DataBase Reference)
[NIST Chemistry Reference]

1,3-Benzenedimethanamine(1477-55-0)
[EPA Substance Registry System]

1477-55-0(EPA Substance)
Safety DataBack Directory
[Symbol(GHS) ]

Corrosion (GHS05)Exclamation Mark (GHS07)
GHS05,GHS07
[Signal word ]

Danger
[Hazard statements ]

H302+H332-H314-H317-H412
[Precautionary statements ]

P273-P280-P301+P312-P303+P361+P353-P304+P340+P310-P305+P351+P338
[Hazard Codes ]

T,C
[Risk Statements ]

R21/22:Harmful in contact with skin and if swallowed .
R23:Toxic by inhalation.
R34:Causes burns.
R43:May cause sensitization by skin contact.
R52/53:Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S61:Avoid release to the environment. Refer to special instructions safety data sheet .
[OEL]

Ceiling: 0.1 mg/m3 [skin]
[RIDADR ]

UN 2735 8/PG 2
[WGK Germany ]

2
[RTECS ]

PF8970000
[F ]

2-9
[TSCA ]

TSCA listed
[REACH Registrations]

Active
[HazardClass ]

8
[PackingGroup ]

II
[HS Code ]

29215900
[Storage Class]

8A - Combustible corrosive hazardous materials
[Hazard Classifications]

Acute Tox. 4 Inhalation
Acute Tox. 4 Oral
Aquatic Chronic 3
Eye Dam. 1
Skin Corr. 1B
Skin Sens. 1B
[Safety Profile]

Moderately toxic by skin contact and ingestion. Mildly toxic by inhalation. A severe skin and eye irritant. When heated to decomposition it emits toxic fumes of NOx. Used to make polyamide fibers and resins and as a curing agent.
[Hazardous Substances Data]

1477-55-0(Hazardous Substances Data)
[Toxicity]

rabbit,LD50,skin,2gm/kg (2000mg/kg),"Documentation of the Threshold Limit Values and Biological Exposure Indices," 5th ed., Cincinnati, OH, American Conference of Governmental Industrial Hygienists, Inc., 1986Vol. 5, Pg. 638, 1986.
Raw materials And Preparation ProductsBack Directory
[Raw materials]

p-Xylene-->Motor benzol-->1,4-Dicyanobenzene-->m-xylenediamine
[Preparation Products]

3-(Isocyanomethyl)benzyl-isocyanide
Hazard InformationBack Directory
[General Description]

Colorless liquid with an amine smell. Mp: 14.1°C; bp: 273°C . Water soluble.
[Reactivity Profile]

M-XYLENE-ALPHA,ALPHA'-DIAMINE is combustible (Flash point 139°C). Incompatible with acids, acid chlorides, acid anhydrides.
[Potential Exposure]

m-Xylene-α,α0-diamine is a source of m-xylene di-isocyanate and used as an intermediate in the manufacture of epoxy and polyamide resins.
[First aid]

If this chemical gets into the eyes, remove any contact lenses at once and irrigate immediately for at least 30 minutes, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts the skin, remove contaminated clothing and wash immediately with soap and water. Seek medical attention immediately. If this chemical has been inhaled, remove from exposure, begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR if heart action has stopped. Transfer promptly to a medical facility. When this chemical has been swallowed, get medical attention. Give large quantities of water and induce vomiting. Do not make an unconscious person vomit.
[Shipping]

UN 2735A mines, liquid, corrosive, n.o.s, or Polyamines, liquid, corrosive, n.o.s., Hazard class: 8; Labels: 8-Corrosive material, Technical Name Required. UN3267 Corrosive liquid, basic, organic, n.o.s., Hazard class: 8; Labels: 8-Corrosive material, Technical Name Required.
[Incompatibilities]

Combustible; vapors may form explosive mixture with air. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, and epoxides.
[Description]

m-Xylene-α,α0-diamine is a colorless liquid.Molecular weight=136.22; Specific gravity (H2O:1)=1.032 at 25℃; Boiling point = 247.2℃; Freezing/Meltingpoint =15℃; Vapor pressure = 0.03 mmHg at 25℃; Flashpoint = 117℃. Hazard Identification (based on NFPA-704M Rating System): Health 3, Flammability 0, Reactivity 0.Soluble in water.
[Chemical Properties]

CLEAR SLIGHTLY YELLOW LIQUID
[Chemical Properties]

m-Xylene-α,α0-diamine is a colorless liquid.
[Hazard]

Moderately toxic by skin contact and ingestion. Mildly toxic by inhalation. A severe skin, eye, and gastrointestinal irritant.
[storage]

Color Code—White: Corrosive or Contact Hazard;Color Code—Blue: Health Hazard/Poison: Store in a securepoison location. Store separately in a corrosion-resistantlocation. Prior to working with this chemical you should betrained on its proper handling and storage. Store in tightlyclosed containers in a cool, well-ventilated area away fromoxidizers (such as perchlorates, peroxides, permanganates,chlorates, and nitrates) and strong acids (such as hydrochloride, sulfuric, and nitric). Store in tightly closed containersin a cool, well-ventilated area away from heat. Sources ofignition, such as smoking and open flames, are prohibitedwhere this chemical is used, handled, or stored in a mannerthat could create a potential fire or explosion hazard. Metalcontainers involving the transfer of 5 gallons or more ofthis chemical should be grounded and bonded. Drums mustbe equipped with self-closing valves, pressure vacuumbungs, and flame arresters. Use only nonsparking tools andequipment, especially when opening and closing containersof this chemical.
[Toxics Screening Level]

The ITSL for 1,3-Bis(aminomethyl)benzene is 1 μg/m3 based on a 1 hour averaging time.
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

1,3-Bis(aminomethyl)benzene(1477-55-0).msds
Spectrum DetailBack Directory
[Spectrum Detail]

1,3-Bis(aminomethyl)benzene(1477-55-0)MS
1,3-Bis(aminomethyl)benzene(1477-55-0)1HNMR
1,3-Bis(aminomethyl)benzene(1477-55-0)13CNMR
1,3-Bis(aminomethyl)benzene(1477-55-0)IR1
1,3-Bis(aminomethyl)benzene(1477-55-0)IR2
1,3-Bis(aminomethyl)benzene(1477-55-0)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

m-Xylylenediamine, 99%(1477-55-0)
[Sigma Aldrich]

1477-55-0(sigmaaldrich)
[TCI AMERICA]

m-Xylylenediamine,>98.0%(GC)(1477-55-0)
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