| Identification | More | [Name]
DIPHENYLIODONIUM CHLORIDE | [CAS]
1483-72-3 | [Synonyms]
DIPHENYLIODONIUM CHLORIDE
chlorodiphenyliodonium
diphenyl-iodoniuchloride
Iodonium,diphenyl-,chloride
Iodonium,diphenyl-chloride
DIPHENYLIODONIUM CHLORIDE 97%
Diphenyliodonium
Diphenyliodonium chloride, 98+% | [EINECS(EC#)]
216-049-8 | [Molecular Formula]
C12H10ClI | [MDL Number]
MFCD00011909 | [Molecular Weight]
316.57 | [MOL File]
1483-72-3.mol |
| Chemical Properties | Back Directory | [Appearance]
WHITE TO LIGHT CREAM-YELLOW POWDER | [Melting point ]
233-235 °C (subl.) (lit.) | [density ]
1.6151 (estimate) | [storage temp. ]
0-6°C | [solubility ]
soluble in Methanol | [form ]
Powder | [color ]
White to light cream-yellow | [Water Solubility ]
Soluble in water and methanol. | [Sensitive ]
Light Sensitive | [Merck ]
14,7464 | [BRN ]
3574977 | [InChI]
InChI=1S/C12H10I.ClH/c1-3-7-11(8-4-1)13-12-9-5-2-6-10-12;/h1-10H;1H/q+1;/p-1 | [InChIKey]
RSJLWBUYLGJOBD-UHFFFAOYSA-M | [SMILES]
[I+](C1C=CC=CC=1)C1C=CC=CC=1.[Cl-] | [CAS DataBase Reference]
1483-72-3(CAS DataBase Reference) | [EPA Substance Registry System]
Iodonium, diphenyl-, chloride (1483-72-3) |
| Safety Data | Back Directory | [Hazard Codes ]
T,Xi | [Risk Statements ]
R25:Toxic if swallowed.
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing . | [RIDADR ]
UN 2811 6.1/PG 3
| [WGK Germany ]
3
| [RTECS ]
NN6651666
| [F ]
8 | [TSCA ]
Yes | [HazardClass ]
6.1 | [PackingGroup ]
III | [HS Code ]
29319090 | [Storage Class]
6.1C - Combustible acute toxic Cat.3
toxic compounds or compounds which causing chronic effects | [Hazard Classifications]
Acute Tox. 3 Oral
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3 |
| Hazard Information | Back Directory | [Chemical Properties]
WHITE TO LIGHT CREAM-YELLOW POWDER | [Uses]
Diphenyliodonium chloride is used as a reagent for electrophilic phenylation . It is used as a reactant for copper-catalyzed cross coupling reactions of purinesband arylation of anilines. It is involved in the preparation of acetylenic arylselenide and (arylmethylene)oxindoles. Further, it is employed in the preparation of aryl alkynes through Sonogashira coupling reactions. | [reaction suitability]
reagent type: oxidant | [storage]
Diphenyliodonium chloride is stable; can be stored at rt without decomposition.
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