| Identification | More | [Name]
Dess-Martin periodinane | [CAS]
87413-09-0 | [Synonyms]
1,1,1-TRIACETOXY-1,1-DIHYDRO-1,2-BENZIODOXOL-3(1H)-ONE
1,1,1-TRIS(ACETYLOXY)-1,1-DIHYDRO-1,2-BENZIODOXOL-3-(1H)-ONE
1,1-DIHYDRO-1,1,1-TRIACETOXY-1,2-BENZOIODOOXOL-3(1H)-ONE
ACETIC ACID 1,1-DIACETOXY-3-OXO-1L5-IODA-2-OXA-INDAN-1-YL ESTER
DESS-MARTIN
DESS-MARTIN PERIODINANE
DESS-MARTIN REAGENT
DESSS-MARTIN PERIODINANE
RARECHEM AR PA 0035
TRIACETOXYPERIODINANE
Triacetoxyperiodinane (Dess-Martin periodinane)
DESS-MARTIN PERIODINANE, 0.3M SOLUTION &
(7,7-DIACETYLOXY-9-OXO-7$L^{5}-IODA-8-OXABICYCLO[4.3.0]NONA-1,3,5-TRIEN-7-YL) ACETATE
DesmartinPeriodinane
DmpDess-MartinPeriodinane
Dess-Martinperiodinane,97%
Dess-Martin periodinane, 15 wt.% solution in dichloromethane
1,2-Benziodoxol-3(1H)-one, 1,1,1-tris(acetyloxy)-1,1-dihydro-
1,1,1-TRIACETOXY-1,1-DIHYDRO-1,2-BENZIODOXOL-3-(1H)-ONE(DESS-MARTINPERIODINANE)
DESS-MARTINE | [EINECS(EC#)]
672-328-8 | [Molecular Formula]
C13H13IO8 | [MDL Number]
MFCD00130127 | [Molecular Weight]
424.14 | [MOL File]
87413-09-0.mol |
| Chemical Properties | Back Directory | [Appearance]
White Crystalline powder | [Melting point ]
130-133 °C (lit.) | [Boiling point ]
40 °C
| [density ]
1.369 g/mL at 25 °C
| [Fp ]
>221 °F
| [storage temp. ]
0-6°C | [solubility ]
Soluble in chloroform, acetone, acetonitrile and methylene chloride. Slightly soluble in ether and hexane. | [form ]
Liquid | [color ]
Colorless to light yellow | [Sensitive ]
Light Sensitive | [Merck ]
14,2933 | [BRN ]
4548207 | [Stability:]
Light Sensitive | [InChI]
InChI=1S/C13H13IO8/c1-8(15)19-14(20-9(2)16,21-10(3)17)12-7-5-4-6-11(12)13(18)22-14/h4-7H,1-3H3 | [InChIKey]
NKLCNNUWBJBICK-UHFFFAOYSA-N | [SMILES]
I1(OC(=O)C)(OC(=O)C)(OC(=O)C)OC(=O)C2C=CC=CC1=2 | [CAS DataBase Reference]
87413-09-0(CAS DataBase Reference) | [Storage Precautions]
Air sensitive;Store under inert gas;Moisture sensitive |
| Safety Data | Back Directory | [Hazard Codes ]
Xn,O,Xi | [Risk Statements ]
R22:Harmful if swallowed.
R36/37/38:Irritating to eyes, respiratory system and skin .
R40:Limited evidence of a carcinogenic effect.
R8:Contact with combustible material may cause fire.
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
S36/37:Wear suitable protective clothing and gloves .
S24/25:Avoid contact with skin and eyes .
S23:Do not breathe gas/fumes/vapor/spray (appropriate wording to be specified by the manufacturer) .
S17:Keep away from combustible material .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection . | [RIDADR ]
UN 1593 6.1/PG 3
| [WGK Germany ]
3
| [Hazard Note ]
Harmful/Light sensitive | [TSCA ]
No | [HazardClass ]
5.1 | [PackingGroup ]
Ⅲ | [HS Code ]
29349900 |
| Hazard Information | Back Directory | [Description]
Dess-Martin periodinane (DMP) is a hypervalent iodine compound widely used as a mild reagent for the oxidation of primary/secondary alcohols to aldehydes/ketones; oxidation of amides into imides; the dehydrogenation of amines to nitriles, and disulfides to sulfones. It is also used to selectively oxidize alkenes to epoxides. This is a useful reaction for generating three-membered cyclic ethers. Additionally, DMP is used to oxidatively cleave 1,2-diols to form aldehydes or ketones and in the synthesis of lactones. | [Chemical Properties]
White Crystalline powder | [Uses]
Dess-Martin Periodinaneis a very usefulreagent used in the oxidation of primary alcohols to aldehydes and secondary alcohols to ketones. | [Uses]
Oxidizing reagent. | [Advantages]
Benefits of using Dess-Martin periodinane (DMP) as an oxidizing reagent:
milder reaction conditions (room temperature, neutral pH)
shorter reaction times and higher yields
high chemoselectivity
tolerance of sensitive functional groups, and a long shelf life
simplified workups
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