ChemicalBook--->CAS DataBase List--->149104-88-1

149104-88-1

149104-88-1 Structure

149104-88-1 Structure
IdentificationMore
[Name]

4-(METHYLSULFONYL)PHENYLBORONIC ACID
[CAS]

149104-88-1
[Synonyms]

4-(METHANESULFONYL)BENZENEBORONIC ACID
4-(METHANESULFONYL)PHENYLBORONIC ACID
4-(METHANESULPHONYL)BENZENEBORONIC ACID
4-(METHANESULPHONYL)PHENYLBORONIC ACID
4-(METHYLSULFONYL)PHENYLBORONIC ACID
4-METHYLSULPHONYLPHENYLBORONIC ACID
AKOS BRN-0147
RARECHEM AH PB 0073
4-[(Dioxo-lambda~6~-sulfanyl)methyl]phenylboronic acid
4-Boronophenyl methyl sulphone~4-(Methylsulphonyl)phenylboronic acid
4-(methylsulfonyloxy)phenylboronic acid
4-(Methylsulphonyl)benzeneboronic acid
4-Boronophenylmethylsulfone
4-(Methanesulfonyl)phenylboronic acid, 98+%
4-(Methylsulfonyl)Phenylboroni
4-methylfulfonylphenylboronic acid
4-[(methylsulfonyl)methyl]phenylboronic acid
4-(Methylsulfonyl)benzeneboronic acid, 98%
4-(Methylsulfonyl)phenylboronic Acid (contains varying amounts of Anhydride)
[EINECS(EC#)]

677-559-8
[Molecular Formula]

C7H9BO4S
[MDL Number]

MFCD01630820
[Molecular Weight]

200.02
[MOL File]

149104-88-1.mol
Chemical PropertiesBack Directory
[Appearance]

Off-white powder
[Melting point ]

275-277 °C
[Boiling point ]

445.5±51.0 °C(Predicted)
[density ]

1.39±0.1 g/cm3(Predicted)
[storage temp. ]

0-6°C
[solubility ]

soluble in Methanol
[form ]

Powder
[pka]

7.22±0.10(Predicted)
[color ]

Off-white
[CAS DataBase Reference]

149104-88-1(CAS DataBase Reference)
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S37/39:Wear suitable gloves and eye/face protection .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S24/25:Avoid contact with skin and eyes .
S22:Do not breathe dust .
[WGK Germany ]

3
[Hazard Note ]

Irritant
[HazardClass ]

IRRITANT
[HS Code ]

29163990
Hazard InformationBack Directory
[Chemical Properties]

Off-white powder
[Uses]

4-(Methanesulfonyl)phenylboronic acid may be used as reagent for:
  • sequential Suzuki cross-coupling reactions
  • Copper-catalyzed oxidative trifluoromethylthiolation of aryl boronic acids
  • directed metalation and regioselective functionalization of 3-bromofuran and related heterocycles
  • Barton-Zard pyrrole cyclocondensations and Baeyer-Villiger oxidations
  • diplar cycloaddition and palladium-catalyzed cross-coupling processes
  • continuous flow Suzuki reactions for odanacatib intermediate synthesis


Reagent used in Preparation of
  • diarylaminopyridines as potential anti-malarial agents
  • hydropyranopyrazine via chloropyrazinecarboxaldehyde and olefination
  • biaryl sulfone derivatives as antagonists of the histamine H3 receptor
  • novel kinase inhibitor scaffolds with potential antitumor effects
  • Hepatitis C virus inhibition activity of N-hydroxyisoquinoline di
[Uses]

4-(Methylsulfonyl)phenylboronic Acid is a heteroaryl boronic acid that was tested for their in vitro hormone-sensitive lipase inhibitory properties.
[Uses]

suzuki reaction
[General Description]

Contains varying amounts of anhydride
Spectrum DetailBack Directory
[Spectrum Detail]

4-(METHYLSULFONYL)PHENYLBORONIC ACID(149104-88-1)1HNMR
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

4-(Methanesulfonyl)phenylboronic acid, 98+%(149104-88-1)
[Alfa Aesar]

4-(Methylsulfonyl)benzeneboronic acid, 98%(149104-88-1)
[Sigma Aldrich]

149104-88-1(sigmaaldrich)
[TCI AMERICA]

4-(Methylsulfonyl)phenylboronic Acid  (contains varying amounts of Anhydride)(149104-88-1)
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