ChemicalBook--->CAS DataBase List--->15159-40-7

15159-40-7

15159-40-7 Structure

15159-40-7 Structure
IdentificationMore
[Name]

4-Morpholinecarbonyl chloride
[CAS]

15159-40-7
[Synonyms]

4-CHLOROCARBONYLMORPHOLINE
4-MORPHOLINE CARBONIC ACID CHLORIDE
4-MORPHOLINECARBONYL CHLORIDE
4-MORPHOLINYLCARBONYL CHLORIDE
MORPHOLIN-4-YLCARBONYL CHLORIDE
MORPHOLINE-4-CARBONYL CHLORIDE
MORPHOLINOCARBONYL CHLORIDE
4-Morpholinecarbonyl chloride (7CI,8CI,9CI)
4-Morpholinecarbonyl chlorid...
N-CHLOROFORMYLMORPHOLINE
Morpholincarbonylchlorid
Morpholine-4-carboxylic acid chloride
[EINECS(EC#)]

239-213-0
[Molecular Formula]

C5H8ClNO2
[MDL Number]

MFCD00037053
[Molecular Weight]

149.58
[MOL File]

15159-40-7.mol
Chemical PropertiesBack Directory
[Boiling point ]

137-138 °C/33 mmHg (lit.)
[density ]

1.282 g/mL at 25 °C(lit.)
[refractive index ]

n20/D 1.498(lit.)
[Fp ]

>230 °F
[storage temp. ]

Inert atmosphere,2-8°C
[form ]

clear liquid
[pka]

-2.16±0.20(Predicted)
[color ]

Colorless to Light yellow
[BRN ]

116257
[InChI]

InChI=1S/C5H8ClNO2/c6-5(8)7-1-3-9-4-2-7/h1-4H2
[InChIKey]

XMWFMEYDRNJSOO-UHFFFAOYSA-N
[SMILES]

C(Cl)(N1CCOCC1)=O
[CAS DataBase Reference]

15159-40-7(CAS DataBase Reference)
[EPA Substance Registry System]

15159-40-7(EPA Substance)
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)Health Hazard (GHS08)
GHS07,GHS08
[Signal word ]

Warning
[Hazard statements ]

H315-H319-H351
[Precautionary statements ]

P201-P302+P352-P305+P351+P338-P308+P313
[Hazard Codes ]

Xn
[Risk Statements ]

R14:Reacts violently with water.
R36/38:Irritating to eyes and skin .
R40:Limited evidence of a carcinogenic effect.
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S30:Never add water to this product .
S36:Wear suitable protective clothing .
S38:In case of insufficient ventilation, wear suitable respiratory equipment .
[RIDADR ]

UN 3265 8/PG 2
[WGK Germany ]

3
[F ]

10-21
[TSCA ]

TSCA listed
[HazardClass ]

8
[PackingGroup ]

II
[HS Code ]

29349990
[Storage Class]

10 - Combustible liquids
[Hazard Classifications]

Carc. 2
Eye Irrit. 2
Skin Irrit. 2
Hazard InformationBack Directory
[Uses]

Photographic intermediate
[General Description]

4-Morpholinecarbonyl chloride is a photographic intermediate. Rates of solvolysis of 4-morpholinecarbonyl chloride with N-alkyl group in aqueous binary solvents of acetone, ethanol, methanol, methanol-d, 2,2,2-trifluoroethanol, pure water and D2O has been determined. Preparation of 4-morpholinecarbonyl chloride has been reported.
[Synthesis]

4-Morpholinecarbonyl chloride is prepared by reacting morpholine hydrochloride with phosgene in an inert liquid medium such as toluene and xylene, at 50W150°C, pref. 60W120°C. The morpholine hydrochloride is prepared by dissolving 1 part by weight of morpholine in ≥4 parts of an inert liquid medium and introducing a slightly excessive HCl into the solution under agitation.
Spectrum DetailBack Directory
[Spectrum Detail]

4-Morpholinecarbonyl chloride(15159-40-7)1HNMR
4-Morpholinecarbonyl chloride(15159-40-7)FT-IR
4-Morpholinecarbonyl chloride(15159-40-7)IR
4-Morpholinecarbonyl chloride(15159-40-7)Raman
Well-known Reagent Company Product InformationBack Directory
[Sigma Aldrich]

15159-40-7(sigmaaldrich)
[TCI AMERICA]

4-Morpholinylcarbonyl Chloride,>97.0%(GC)(15159-40-7)
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