| Identification | More | [Name]
2,3-DIMETHYLFURAN | [CAS]
14920-89-9 | [Synonyms]
2,3-DIMETHYLFURAN
2,3-Dimethylfuran, GC 99% | [EINECS(EC#)]
626-651-6 | [Molecular Formula]
C6H8O | [MDL Number]
MFCD00153893 | [Molecular Weight]
96.13 | [MOL File]
14920-89-9.mol |
| Chemical Properties | Back Directory | [Appearance]
clear colorless to light yellow liquid | [Melting point ]
-62.8°C (estimate) | [Boiling point ]
42 °C/115 mmHg (lit.) | [density ]
0.91 g/mL at 25 °C(lit.)
| [refractive index ]
n20/D 1.443(lit.)
| [Fp ]
30 °F
| [storage temp. ]
Flammables area | [form ]
clear liquid | [color ]
Colorless to Yellow to Green | [Specific Gravity]
0.919 | [Water Solubility ]
Insoluble in water. | [BRN ]
104572 | [InChI]
1S/C6H8O/c1-5-3-4-7-6(5)2/h3-4H,1-2H3 | [InChIKey]
FJSKXQVRKZTKSI-UHFFFAOYSA-N | [SMILES]
Cc1ccoc1C | [CAS DataBase Reference]
14920-89-9(CAS DataBase Reference) |
| Safety Data | Back Directory | [Hazard Codes ]
F,Xn | [Risk Statements ]
R11:Highly Flammable.
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed . | [Safety Statements ]
S16:Keep away from sources of ignition-No smoking .
S36:Wear suitable protective clothing . | [RIDADR ]
UN 1993 3/PG 2
| [WGK Germany ]
3
| [HazardClass ]
3 | [PackingGroup ]
II | [HS Code ]
29321900 | [Storage Class]
3 - Flammable liquids | [Hazard Classifications]
Acute Tox. 4 Dermal
Acute Tox. 4 Inhalation
Acute Tox. 4 Oral
Flam. Liq. 2 |
| Hazard Information | Back Directory | [Chemical Properties]
clear colorless to light yellow liquid | [Uses]
2,3-Dimethylfuran may be used in the synthesis of 2,9-dioxabicyclo[3.3.1]nonane. Ireland Alcohol was synthesized in from 2,3-dimethylfuran. | [Synthesis Reference(s)]
Synthetic Communications, 20, p. 1113, 1990 DOI: 10.1080/00397919008052818 | [General Description]
2,3-Dimethylfuran is a methyl substituted furan. The gas-phase rate constant determined by the relative rate method for the reaction of 2,3-dimethylfuran with NO3 radical was found to be (5.83 ± 0.46)×10-11 and with OH radical was (12.6 ± 0.4)×10-11 (in units of cm3 molecule-1 s-1). It is reported to be formed by the cyclization of (Z)-3-methylpent-2-en-4-yn-1-ol by various methods. |
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Sigma-Aldrich
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