| Identification | Back Directory | [Name]
(1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE | [CAS]
1517-82-4 | [Synonyms]
menthyl p-toluenesulfinate
(S)-(-)-MENTHYL P-TOLUENESULFINATE
Menthyl (S)-4-methylbenzenesulfinate
(?-(1R)-Menthyl (S)-p-toluenesulfinate
(-)-(1R)-MENTHYL (S)-TOLUENE-4-SULFINATE
(-)-Menthyl (S)-4-methylbenzenesulfinate
(1R,2S,5R)-MENTHYL (S)-P-TOLUENESULFINATE
(1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFITE
(1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE
(S)-(-)-P-TOLUENESULFINIC ACID L-MENTHYL ESTER
p-Toluenesulfinic acid (1R,3R,4S)-menthyl ester
(1R,2S,5R)-(-)-Menthyl (S)-p-toluenesulfinate,98%
p-Toluenesulfinic acid (1R,3R,4S)-p-menthane-3-yl ester
(1S)-2-Isopropyl-5-methylcyclohexyl 4-methylbenzenesulfinate
4-Methylbenzenesulfinic acid (1R,3R,4S)-p-menthane-3-yl ester
p-Toluenesulfinic acid (1R,1β)-2α-isopropyl-5β-methylcyclohexyl ester
p-Toluenesulfinic acid (1R,2S,5R)-2-isopropyl-5-methylcyclohexyl ester
(S)-((1R,2S,5R)-2-isopropyl-5-Methylcyclohexyl) 4-Methylbenzenesulfinate
(S)-(-)-Menthyl p-toluenesulfinate, (-)-(1R)-Menthyl (S)-p-toluenesulfinate
4-Methylbenzenesulfinic acid (1R)-2α-isopropyl-5β-methylcyclohexane-1β-yl ester
[S(S)]-4-Methylbenzenesulfinic acid (1R,2S,5R)-5-methyl-2-(1-methylethyl)cyclohexyl ester | [Molecular Formula]
C17H26O2S | [MDL Number]
MFCD00010192 | [MOL File]
1517-82-4.mol | [Molecular Weight]
294.45 |
| Chemical Properties | Back Directory | [Appearance]
White crystalline powder | [Melting point ]
99-104 °C
| [Boiling point ]
402.3±38.0 °C(Predicted) | [density ]
1.08 | [refractive index ]
-199 ° (C=1.5, Acetone) | [storage temp. ]
−20°C
| [solubility ]
Acetone (Slightly), Chloroform (Slightly) | [form ]
Solution | [color ]
Yellow to brown or gray | [optical activity]
[α]20/D 195°, c = 2 in acetone | [BRN ]
3207468 |
| Hazard Information | Back Directory | [Chemical Properties]
White crystalline powder | [Uses]
(1R,2S,5R)-(-)-Menthyl (S)-p-Toluenesulfinate is a reactant used in the synthesis of sulfoxide pincer complexes of Mg, Rh and Ir. | [Uses]
(1R,2S,5R)-(-)-Menthyl (S)-p-toluenesulfinate can react with:
- metal ketimines to form enantiopure sulfinimines
- p-(methylthio)benzaldehyde to form (S)-(-)-N-(4-methylthiobenzylidene)-p-toluenesulfinimine
| [General Description]
(1R,2S,5R)-(-)-Menthyl (S)-p-toluenesulfinate is mainly used for the introduction of p-toluenesulfinyl group in asymmetric synthesis. |
|
|