| Identification | Back Directory | [Name]
(2-NAPHTHYL)METHYLZINC BROMIDE | [CAS]
152329-44-7 | [Synonyms]
(2-NAPHTHYL)METHYLZINC BROMIDE
(2-naphthylmethyl)zinc bromide solution
(2-Naphthylmethyl)zinc bromide solution 0.5 in THF
(2-Naphthylmethyl)zinc bromide solution 0.5M in THF
(2-Naphthyl)methylzinc bromide 0.5 M in Tetrahydrofuran
(2-NAPHTHYLMETHYL)ZINC BROMIDE, 0.5M SOL UTION IN TETRAHYDROFURAN | [Molecular Formula]
C11H9BrZn | [MDL Number]
MFCD01311438 | [MOL File]
152329-44-7.mol | [Molecular Weight]
286.48 |
| Chemical Properties | Back Directory | [density ]
0.978 g/mL at 25 °C | [Fp ]
-17 °C | [storage temp. ]
2-8°C | [InChI]
1S/C11H9.BrH.Zn/c1-9-6-7-10-4-2-3-5-11(10)8-9;;/h2-8H,1H2;1H;/q;;+1/p-1 | [InChIKey]
IKDINBHMSAHXCA-UHFFFAOYSA-M | [SMILES]
Br[Zn]Cc1ccc2ccccc2c1 |
| Hazard Information | Back Directory | [Uses]
(2-Naphthylmethyl)zinc bromide can be used as a reagent for the synthesis of:
- 4-(5,6-dimethoxy-2-(naphthalen-2-ylmethyl)pyridin-3-yl)benzonitrile from 4-(2-bromo-5,6-dimethoxypyridin-3-yl)benzonitrile using Pd catalyst.
- (E)-stilbene, (2,2′-[1,4-phenylenedi-(1E)-2,1-ethenediyl]bis[naphthalene]) from 1,4-benzenedicarboxaldehyde in the presence of Pd catalyst and a silylating agent.
| [General Description]
(2-Naphthylmethyl)zinc bromide is an organozinc halide, which is typically used as a reagent in Negishi cross-coupling reactions. In this process, the organozinc halide reacts with organic halides or triflates to form a carbon-carbon bond in the presence of a Pd catalyst. |
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