ChemicalBook--->CAS DataBase List--->15356-74-8

15356-74-8

15356-74-8 Structure

15356-74-8 Structure
IdentificationBack Directory
[Name]

DIHYDROACTINIDIOLIDE
[CAS]

15356-74-8
[Synonyms]

Dihydroactinolide
DIHYDROACTINIDIODE
DIHYDROACTINIDIOLIDE USP/EP/BP
4,4,7a-Trimethyl-5,6,7,7a-tetrahydrobenzofuran-2(4H)
2,4,5,6,7,7a-Hexahydro-4,4,7a-trimethylbenzofuran-2-one
5,8,7,7-Tetrahydro-4,4,7a-trimethyl-alpha-benzofuranone
4,5,7,7a-Tetrahydro-4,4,7a-trimethyl-2(6H)benzofuranone
4,4,7a-Trimethyl-2,4,5,6,7,7a-hexahydrobenzofuran-2-one
4,4,7a-Trimethyl-5,6,7,7a-tetrahydrobenzofuran-2(4H)-one
5,6,7,7a-tetrahydro-4,4,7a-trimethylbenzofuran-2(4H)-one
4,4,7a-Trimethyl-5,6,7,7a-tetrahydro-1-benzofuran-2(4H)-one
(S)-4,4,7a-TriMethyl-5,6,7,7a-tetrahydrobenzofuran-2(4H)-one
2-Hydroxy-2,6,6-trimethylcyclohexylidene-1-acetic acid lactone
(2,6,6-trimethy1-2-hydroxycyclohexylidene)-acetic acid lactone
(+/-)-(2,6,6-TRIMETHYL-2-HYDROXYCYCLOHEXYLIDENE)ACETICACIDGAMMALACTONE
[EINECS(EC#)]

239-390-4
[Molecular Formula]

C11H16O2
[MDL Number]

MFCD06409986
[MOL File]

15356-74-8.mol
[Molecular Weight]

180.24
Chemical PropertiesBack Directory
[Melting point ]

42-43°
[Boiling point ]

296℃
[density ]

1.05
[FEMA ]

4020 | (+/-)-(2,6,6-TRIMETHYL-2-HYDROXYCYCLOHEXYLIDENE)ACETIC ACID GAMMA-LACTONE
[Fp ]

120℃
[storage temp. ]

Sealed in dry,2-8°C
[solubility ]

Chloroform (Slightly), DMSO (Slightly), Methanol (Slightly)
[form ]

Solid
[color ]

Off-White
[Odor]

at 100.00 %. ripe apricot fruity plum berry grape tropical fruit woody
[Odor Type]

fruity
[JECFA Number]

1164
[InChI]

InChI=1S/C11H16O2/c1-10(2)5-4-6-11(3)8(10)7-9(12)13-11/h7H,4-6H2,1-3H3
[InChIKey]

IMKHDCBNRDRUEB-UHFFFAOYSA-N
[SMILES]

O1C2(C)CCCC(C)(C)C2=CC1=O
[LogP]

2.26
[EPA Substance Registry System]

2(4H)-Benzofuranone, 5,6,7,7a-tetrahydro-4,4,7a-trimethyl- (15356-74-8)
Safety DataBack Directory
[Symbol(GHS) ]

Skull and Crossbones (GHS06)
GHS06
[Signal word ]

Danger
[Hazard statements ]

H300
[Precautionary statements ]

P264-P270-P301+P310-P321-P330-P405-P501
[TSCA ]

TSCA listed
Hazard InformationBack Directory
[Chemical Properties]

(+/–)-(2,6,6-Trimethyl-2-hydroxycyclohexylidene) acetic acid gamma-lactone has a powerful musky or coumarin like odor. As this compound is formed from photooxidation of carotene-like structures, its taste is related to certain fruit types at their peak of ripeness.
[Occurrence]

Reportedly present in lemongrass and sweet grass oil.
[Uses]

DIHYDROACTINIDIOLIDE is widely used in tobacco flavorings, beverage and other food flavoring formulations, and pharmaceutical intermediates.
[Definition]

ChEBI: Dihydroactinidiolide is a member of benzofurans.
[Preparation]

Prepared in a patented process by degradation of beta-carotene in the presence of nitrogen and air.
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