ChemicalBook--->CAS DataBase List--->15396-00-6

15396-00-6

15396-00-6 Structure

15396-00-6 Structure
IdentificationMore
[Name]

3-Isocyanatopropyltrimethoxysilane
[CAS]

15396-00-6
[Synonyms]

3-ISOCYANATOPROPYLTRIMETHOXYSILANE
3-(trimethoxysilyl)propyl isocyanate
GAMMA-ISOCYANOPROPYLTRIMETHOXYSILANE
Trimethoxy(3-isocyanotopropyl)silane
(3-isocyanatopropyl)trimethoxy-silan
3-Isocyanatopropyltrimethyoxysilane
Silane,(3-isocyanatopropyl)trimethoxy-
3-isocyanatepropyltrimethoxysilane
[EINECS(EC#)]

239-415-9
[Molecular Formula]

C7H15NO4Si
[MDL Number]

MFCD00044990
[Molecular Weight]

205.28
[MOL File]

15396-00-6.mol
Chemical PropertiesBack Directory
[Appearance]

Colorless clear liquid
[Melting point ]

<0°C
[Boiling point ]

95-98°C 10mm
[density ]

1,084 g/cm3
[vapor pressure ]

0-12790Pa at 20-25℃
[refractive index ]

1.421
[Fp ]

108°C
[storage temp. ]

RT, stored under nitrogen
[form ]

clear liquid
[color ]

Colorless to Almost colorless
[Specific Gravity]

1.073
[Water Solubility ]

1000g/L at 20℃
[Hydrolytic Sensitivity]

7: reacts slowly with moisture/water
[InChI]

InChI=1S/C7H15NO4Si/c1-10-13(11-2,12-3)6-4-5-8-7-9/h4-6H2,1-3H3
[InChIKey]

FMGBDYLOANULLW-UHFFFAOYSA-N
[SMILES]

[Si](CCCN=C=O)(OC)(OC)OC
[LogP]

-4--0.82 at 20℃
[CAS DataBase Reference]

15396-00-6(CAS DataBase Reference)
[EPA Substance Registry System]

15396-00-6(EPA Substance)
Questions And AnswerBack Directory
[Preparation]

Preparation method of 3-Isocyanatopropyltrimethoxysilane: Specifically includes the following steps: 1) Add 3-aminopropyltrimethoxysilane, dry urea, dimethyl sulfoxide, and a small amount of trimethyl orthoacetate to a reactor; 2) Heat the system to 65–95°C under stirring, and react under vacuum of -0.08–-0.09 MPa to remove ammonia for 6–10 hours until no obvious bubbles emerge from the reaction system, then stop vacuuming to obtain a mixture of ureapropylsilane and solvents; 3) Add a small amount of catalyst to the reaction system, and dilute 98% concentrated sulfuric acid with dimethyl sulfoxide at a mass ratio of 1:0.5–0.8 to obtain a mixed diluted solution. Slowly add this mixed diluted solution dropwise to the system while stirring, controlling the reaction temperature at 75–95°C and the dropwise addition time at 4–6 hours; 4) Stop adding the diluted mixture when the pH of the system drops to 6-7; then cool to below 50°C, seal and filter to remove the generated ammonium salt and other solids; obtain the filtrate, and separate the filtrate by vacuum distillation to obtain the 3-Isocyanatopropyltrimethoxysilane product.
[Application]

3-Isocyanopropyltrimethoxysilane is a silane with isocyanate functional groups. This product is used as a crosslinking agent and adhesion promoter in adhesives and sealants. It can adhere to a wide variety of substrates, both common and uncommon; it exhibits excellent wet adhesion properties on glass, metals, and other inorganic substrates; it also adheres well to difficult-to-adhere substrates, such as nylon and other plastic products. It hydrolyzes rapidly in the presence of atmospheric humidity and possesses very good thermal, chemical, and UV stability.
Safety DataBack Directory
[Symbol(GHS) ]

Corrosion (GHS05)Skull and Crossbones (GHS06)Exclamation Mark (GHS07)Health Hazard (GHS08)
GHS05,GHS06,GHS07,GHS08
[Signal word ]

Danger
[Hazard statements ]

H302+H312-H314-H317-H330-H334
[Precautionary statements ]

P260-P264-P270-P271-P272-P280-P284-P301+P330+P331+P310-P303+P361+P353+P310+P363-P304+P340+P310-P305+P351+P338+P310-P403+P233-P405-P501
[Risk Statements ]

R21/22:Harmful in contact with skin and if swallowed .
R26:Very Toxic by inhalation.
R34:Causes burns.
R42:May cause sensitization by inhalation.
[Safety Statements ]

S23:Do not breathe gas/fumes/vapor/spray (appropriate wording to be specified by the manufacturer) .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
[RIDADR ]

2927
[TSCA ]

TSCA listed
[REACH Registrations]

Active
[HazardClass ]

6.1/8
[PackingGroup ]

II
[HS Code ]

29319090
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

Trimethoxy(3-isocyanotopropyl)silane(15396-00-6).msds
Hazard InformationBack Directory
[Chemical Properties]

Colorless clear liquid
[Flammability and Explosibility]

Notclassified
Spectrum DetailBack Directory
[Spectrum Detail]

3-Isocyanatopropyltrimethoxysilane(15396-00-6)1HNMR
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