| Identification | Back Directory | [Name]
DODEMORPH | [CAS]
1593-77-7 | [Synonyms]
F-238
doazine
MELTATOX
DODEMORPH
MILBAN(R)
MELTALOX(R)
Mehltamittel
dodemorph (bsi,iso)
cyclododecane,morpholinederiv.
4-cyclododecyl-2,6-dimethyl-morpholin
4-CYCLODODECYL-2,6-DIMETHYLMORPHOLINE
DODEMORPH MIXTURE OF CIS AND TRANS ISOME
Morpholine, 4-cyclododecyl-2,6-dimethyl-
Dodemorph Solution in Methanol, 1000μg/mL
4-CYCLODODECYL-2,6-DIMETHYLMORPHOLINACETATE
4-CYCLODODECYL-2,6-DIMETHYL-MORPHOLINIUM ACETATE
dodemorph (ISO) 4-cyclododecyl-2,6-dimethylmorpholine | [EINECS(EC#)]
216-474-9 | [Molecular Formula]
C18H35NO | [MDL Number]
MFCD00155442 | [MOL File]
1593-77-7.mol | [Molecular Weight]
281.48 |
| Chemical Properties | Back Directory | [Melting point ]
161-162℃ | [Boiling point ]
372℃ | [density ]
0.893 | [refractive index ]
nD25 1.4907 | [Fp ]
>100 °C | [storage temp. ]
-20°C | [form ]
neat | [pka]
8.56±0.60(Predicted) | [Merck ]
13,3441 | [BRN ]
511312 | [Major Application]
agriculture
environmental | [InChI]
1S/C18H35NO/c1-16-14-19(15-17(2)20-16)18-12-10-8-6-4-3-5-7-9-11-13-18/h16-18H,3-15H2,1-2H3 | [InChIKey]
JMXKCYUTURMERF-UHFFFAOYSA-N | [SMILES]
CC1CN(CC(C)O1)C2CCCCCCCCCCC2 | [LogP]
6.100 (est) | [EPA Substance Registry System]
Dodemorph (1593-77-7) |
| Safety Data | Back Directory | [Hazard Codes ]
Xi,N | [Risk Statements ]
36/37/38-51/53 | [Safety Statements ]
26-61 | [RIDADR ]
2588 | [WGK Germany ]
2 | [RTECS ]
QE0550000 | [HazardClass ]
6.1(b) | [PackingGroup ]
III | [HS Code ]
29349990 | [Storage Class]
8A - Combustible corrosive hazardous materials | [Hazard Classifications]
Aquatic Acute 1
Aquatic Chronic 1
Eye Dam. 1
Repr. 2
Skin Corr. 1C
Skin Sens. 1A
STOT RE 2 |
| Hazard Information | Back Directory | [Description]
Dodemorph is a morpholine fungicide used for fungal control. It is moderately soluble in water and most organic solvents. It is moderately persistent in soil and is non-mobile. Based on its physico-chemical parameters, dodemorph is not expected to leach to groundwater. It demonstrates a low toxicity to mammals but a moderate level of toxicity to bees, fish and aquatic invertebrates. Limited data is available on its toxicity to humans but some reports suggest it is a possible reproduction/developmental toxin as well as an irritant. | [Chemical Properties]
Stability of moringa: Stable for more than 1y in closed containers. Stable for more than 2y at 50°C. Stable in neutral, medium strength alkali or acid. Decomposes and is flammable at high temperatures. | [Uses]
A labelled form of 4-Cyclododecyl-2,6-dimethylmorpholine (C990000) which is??a morpholine pesticide and often used to control mildew in rose cultivation. 4-Cyclododecyl-2,6-dimethylmorpholine is known to inhibit ergosterol-biosynthesis and can be used to detect fungicide residues in fruits and vegetables. Useful in cannabis testing kits as a component of pesticide mixes (P698235). | [Definition]
ChEBI: A member of the class of morpholines that is 2,6-dimethylmorpholine in which the hydrogen attached to the nitrogen is replaced by a cyclododecyl group. It is a fungicide used for the control of powdery mildew, particularly in rose culture. | [Production Methods]
The commercial production of dodemorph involves synthesising a morpholine-based fungicide through a series of organic reactions that build its distinctive structure. The process begins with the formation of the 2,6-dimethylmorpholine ring, which is then alkylated with a cyclododecyl group. This alkylation step introduces two chiral centres, resulting in a mixture of cis-trans isomers, which are then purified and formulated into products. | [Mechanism of action]
Systemic with protective and curative action. Inhibits sterol biosynthesis in membranes | [Pesticide Type]
Fungicide |
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