Identification | More | [Name]
BIS(DIMETHYLAMINO)PHOSPHORYL CHLORIDE | [CAS]
1605-65-8 | [Synonyms]
BIS(DIMETHYLAMIDO)PHOSPHORIC CHLORIDE BIS(DIMETHYLAMINO)PHOSPHOROCHLORIDATE BIS(DIMETHYLAMINO)PHOSPHORYL CHLORIDE N,N,N',N'-TETRAMETHYLDIAMIDOPHOSPHOROCHLORIDATE N,N,N',N'-TETRAMETHYLPHOSPHORDIAMIDIC CHLORIDE N,N,N',N'-TETRAMETHYLPHOSPHORODIAMIDIC CHLORIDE PHOSPHORIC ACID BIS(DIMETHYLAMIDO) CHLORIDE TETRAMETHYLPHOSPHORODIAMIDIC CHLORIDE ((CH3)2N)2POCl bis-(N,N-dimethylamino)-phosphorylchloride Phosphorodiamidic chloride, N,N,N',N'-tetramethyl- Phosphorodiamidic chloride, tetramethyl- Phosphorodiamidicchloride,tetramethyl- chlorobis(dimethylamino)oxophosphorus bis(dimethylamino)phosphinic chloride BIS(DIMETHYLAMINO) PHOSPHOROCHLORIDATE, TECH., 90% Bis(dimethylamino)phosphorylchloride,95+% Tetramethyldiamidophosphoryl chloride. Bis-(dimethylamino)-phosphorochloridate, 90%,tech. Bis(dimethylamino)chlorophosphine oxide | [EINECS(EC#)]
216-517-1 | [Molecular Formula]
C4H12ClN2OP | [MDL Number]
MFCD00008302 | [Molecular Weight]
170.58 | [MOL File]
1605-65-8.mol |
Chemical Properties | Back Directory | [Appearance]
CLEAR COLOURLESS TO SLIGHTLY YELLOW LIQUID | [Boiling point ]
246-247 °C | [density ]
1.152 g/mL at 25 °C(lit.)
| [refractive index ]
n20/D 1.466(lit.)
| [Fp ]
>230 °F
| [storage temp. ]
under inert gas (nitrogen or Argon) at 2-8°C | [solubility ]
Chloroform (Sparingly), Ethyl Acetate (Slightly) | [form ]
Liquid | [pka]
-0.04±0.70(Predicted) | [color ]
Colorless | [Specific Gravity]
1.18 | [Sensitive ]
Moisture Sensitive | [BRN ]
471430 | [InChI]
InChI=1S/C4H12ClN2OP/c1-6(2)9(5,8)7(3)4/h1-4H3 | [InChIKey]
WYLQARGYFXBZMD-UHFFFAOYSA-N | [SMILES]
P(N(C)C)(N(C)C)(Cl)=O | [CAS DataBase Reference]
1605-65-8(CAS DataBase Reference) | [EPA Substance Registry System]
Phosphorodiamidic chloride, tetramethyl- (1605-65-8) |
Safety Data | Back Directory | [Hazard Codes ]
C | [Risk Statements ]
R34:Causes burns. R37:Irritating to the respiratory system. | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . S36/37/39:Wear suitable protective clothing, gloves and eye/face protection . S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) . | [RIDADR ]
UN 3265 8/PG 2
| [WGK Germany ]
3
| [HazardClass ]
8 | [PackingGroup ]
III | [HS Code ]
29299090 |
Hazard Information | Back Directory | [Chemical Properties]
CLEAR COLOURLESS TO SLIGHTLY YELLOW LIQUID | [Uses]
N,N,N′,N′-Tetramethylphosphorodiamidic chloride was used in the synthesis of (-)-allohedycaryol and C2-symmetric binaphthyl phosphortriamide. It was also used in total synthesis of neohedycaryol. | [Application]
Bis(dimethylamino) Phosphorochloridate is used as a reagent for protection of alcohols, ketones, thiols and amines; reductive deoxygenation of alcohols and
ketones. | [storage]
Bis(dimethylamino) Phosphorochloridate is moisture sensitive; store in a dry, cool environment. Handle in a well-ventilated fume hood. |
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