| Identification | More | [Name]
Bis(2-oxo-3-oxazolidinyl)phosphinic chloride | [CAS]
68641-49-6 | [Synonyms]
BIS(2-OXO-3-OXAZOLIDINYL)PHOSPHINIC CHLORIDE
BIS(2-OXO-3-OXAZOLIDINYL)PHOSPHONIC CHLORIDE
BIS(2-OXO-3-OXAZOLIDINYL)PHOSPHORODIAMIDIC CHLORIDE
BOP-CI
BOP-CL
N,N-BIS(2-OXO-3-OXAZOLIDINYL)PHOSPHINIC CHLORIDE
N,N-BIS(2-OXO-3-OXAZOLIDINYL)PHOSPHONIC CHLORIDE
N,N-BIS(2-OXO-3-OXAZOLIDINYL)PHOSPHORODIAMIDIC CHLORIDE
PHOSPHORIC ACID BIS(2-OXOOXAZOLIDIDE) CHLORIDE
bis(2-oxo-3-oxazolidinyl)-phosphinicchlorid
BIS(2-OXO-3-OXAZOLIDINYL)PHOSPHINIC CHLORIDE (BOP-CL)
N,N-BIS(2-OXO-3-OXAZOLIDINYL)PHOSPHORAMIDIC CHLORIDE
BOP-CL BIS(2-OXO-3-OXAZOLIDINYL)PHOSPHINIC CHLORIDE
Bis-(2-oxo-3-oxazolidinyl)-phosphinyl chloride
BOP-Cl, Phosphoric acid bis(2-oxooxazolidide) chloride
3-[Chloro-(2-oxo-1,3-oxazolidin-3-yl)phosphoryl]-1,3-oxazolidin-2-one
BOP-C
BOPDC
Bis(2-oxo-3-oxazolidinyl)phosphinic chloride ,97%
3,3'-(Chlorophosphinylidene)bis(oxazolidine-2-one) | [EINECS(EC#)]
629-561-5 | [Molecular Formula]
C6H8ClN2O5P | [MDL Number]
MFCD00010077 | [Molecular Weight]
254.56 | [MOL File]
68641-49-6.mol |
| Chemical Properties | Back Directory | [Appearance]
White solid | [Melting point ]
191 °C (dec.)(lit.)
| [Boiling point ]
332.8±25.0 °C(Predicted) | [density ]
1.71±0.1 g/cm3(Predicted) | [storage temp. ]
Store at RT. | [solubility ]
slightly sol CH2Cl2, MeCN, THF, DMF; dec H2O | [form ]
Crystalline Powder | [pka]
-2.47±0.20(Predicted) | [color ]
White to off-white | [Water Solubility ]
Hydrolyzes with water. | [Sensitive ]
Moisture Sensitive | [Detection Methods]
HNMR,PNMR | [BRN ]
3654596 | [InChI]
InChI=1S/C6H8ClN2O5P/c7-15(12,8-1-3-13-5(8)10)9-2-4-14-6(9)11/h1-4H2 | [InChIKey]
KLDLRDSRCMJKGM-UHFFFAOYSA-N | [SMILES]
P(N1CCOC1=O)(N1CCOC1=O)(Cl)=O | [CAS DataBase Reference]
68641-49-6(CAS DataBase Reference) | [Storage Precautions]
Moisture sensitive;Store under nitrogen |
| Safety Data | Back Directory | [Symbol(GHS) ]
GHS05 | [Signal word ]
Danger | [Hazard statements ]
H314 | [Precautionary statements ]
P260-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338-P363 | [Hazard Codes ]
C | [Risk Statements ]
R34:Causes burns. | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S27:Take off immediately all contaminated clothing . | [RIDADR ]
UN 3261 8/PG 2 | [WGK Germany ]
3 | [RTECS ]
SZ5871000 | [F ]
10-21 | [HazardClass ]
8 | [PackingGroup ]
II | [HS Code ]
29349990 | [Storage Class]
8A - Combustible corrosive hazardous materials | [Hazard Classifications]
Skin Corr. 1B |
| Hazard Information | Back Directory | [Description]
Bis(2-oxo-3-oxazolidinyl)phosphinic chloride is a reagent for activating carboxyl groups, converting acids to esters (including thioesters and phosphoesters), amides (including peptides and β-lactams), and anhydrides; reagent for kinetic resolution of racemic carboxylic acids and alcohols. | [Chemical Properties]
White solid | [Uses]
Bis(2-oxo-3-oxazolidinyl)phosphinic chloride was used in the preparation of hexadepsipeptide. | [storage]
Bis(2-oxo-3-oxazolidinyl)phosphinic chloride should store in a cool dry place under nitrogen to preclude contact with moisture and oxygen. Use only in a chemical fume hood. Wear suitable protective clothing and eye/face protection. Causes burns and is harmful if swallowed, inhaled, or absorbed through skin. | [Purification Methods]
the outcome of reactions can be greatly affected by the purity of the reagent; commercial samples may require to be washed with cold water and recrystallized from MeCN prior to use. |
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| Company Name: |
J & K SCIENTIFIC LTD.
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| Telephone: |
18210857532 18210857532 |
| Website: |
https://www.jkchemical.com |
| Company Name: |
Alfa Aesar
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| Telephone: |
400-6106006 |
| Website: |
http://chemicals.thermofisher.cn |
| Company Name: |
Energy Chemical
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| Telephone: |
400-0056266 |
| Website: |
www.energy-chemical.com |
| Company Name: |
Jia Xing Isenchem Co.,Ltd
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| Telephone: |
0573-85285100 18627885956 |
| Website: |
https://www.chemicalbook.com/ShowSupplierProductsList14265/0_EN.htm |
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