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16409-45-3

16409-45-3 Structure

16409-45-3 Structure
IdentificationMore
[Name]

L-MENTHYL ACETATE
[CAS]

16409-45-3
[Synonyms]

(-)-(1R)-MENTHYL ACETATE
(1R)-(-)-MENTHYL ACETATE
(-)-ACETOXY-P-MENTHANE
FEMA 2668
L-MENTHYL ACETATE
(-)-MENTHYL ACETATE
MENTHYL ACETATE
MENTHYL ACETATE, L-
(R)-(-)-MENTHYL ACETATE
2-Isopropyl-5-methylcyclohexyl acetate
5-methyl-2-(1-methylethyl)-cyclohexanoacetate
5-methyl-2-(1-methylethyl)cyclohexanolacetate
Acetic acid, p-menth-3-yl ester, dl-
aceticacidmenthylester
Cyclohexanol,5-methyl-2-(1-methylethyl)-,acetate
femanumber:2668
l-Menthol acetate
mentholaceticester
p-menth-3-ylester,dl-aceticaci
DL-MENTHYL ACETATE 97+% FCC
[EINECS(EC#)]

220-076-0
[Molecular Formula]

C12H22O2
[MDL Number]

MFCD00001482
[Molecular Weight]

198.3
[MOL File]

16409-45-3.mol
Chemical PropertiesBack Directory
[Appearance]

Colorless liquid; menthol-like odor.Slightly soluble in water; miscible with alcohol and ether. Combustible.
[Melting point ]

<25 °C
[Boiling point ]

229-230 °C(lit.)
[density ]

0.92 g/mL at 25 °C(lit.)
[FEMA ]

2668 | MENTHYL ACETATE (ISOMER UNSPECIFIED)
[refractive index ]

n20/D 1.447(lit.)
[Fp ]

171 °F
[Odor]

at 100.00 %. tea cooling minty fruity berry
[Odor Type]

mentholic
[JECFA Number]

431
[LogP]

4.10
[Uses]

Perfumery, flavoring.
[CAS DataBase Reference]

16409-45-3(CAS DataBase Reference)
Safety DataBack Directory
[WGK Germany ]

3
[RTECS ]

AI5900000
[Safety Profile]

Mildly toxic by ingestion. A skin irritant. Combustible liquid. When heated to decomposition it emits acrid smoke and irritating fumes.
[Hazardous Substances Data]

16409-45-3(Hazardous Substances Data)
[Toxicity]

rabbit,LD50,skin,> 5gm/kg (5000mg/kg),Food and Cosmetics Toxicology. Vol. 14, Pg. 479, 1976.
Hazard InformationBack Directory
[Chemical Properties]

Colorless liquid; menthol-like odor.Slightly soluble in water; miscible with alcohol and ether. Combustible.
[Chemical Properties]

l-Menthyl acetate has a fresh odor similar to mint and rose (on dilution). It has a characteristic, fresh, pungent flavor, different from menthol (being much milder). It has a cool mouthfeel with only a trace of mint flavor.
[Occurrence]

Reported as a normal constituent of peppermint oil in varying amounts, depending on the source; the synthetic product is optically levorotatory; the commercial product is optically inactive.
[Definition]

ChEBI: (+/-)-Menthyl acetate is a p-menthane monoterpenoid.
[Preparation]

By reacting acetic anhydride with menthol in the presence of anhydrous sodium acetate.
[Taste threshold values]

Taste characteristics at 10 ppm: tea-like, cooling and fruity
[Biochem/physiol Actions]

Taste at 25 ppm
Spectrum DetailBack Directory
[Spectrum Detail]

L-MENTHYL ACETATE(16409-45-3)MS
L-MENTHYL ACETATE(16409-45-3)1HNMR
L-MENTHYL ACETATE(16409-45-3)IR1
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