| Identification | More | [Name]
ALPHA-PINENE OXIDE | [CAS]
1686-14-2 | [Synonyms]
2,3-EPOXYPINANE
(-)-ALPHA-PINENE OXIDE
ALPHA-PINENE OXIDE
AURORA KA-478
DL-ALPHA-PINENE OXIDE
EPOXY ALPHA PINENE
PINENE OXIDE, ALPHA-
.alpha.-Pinene epoxide (Isomer 1)
.alpha.-Pinene epoxide (Isomer 2)
2,3-epoxy-pinan
2,7,7-trimethyl-3-oxatricyclo(4.1.1.0(sup2,4))octane
2-pineneoxide
3-Oxatricyclo[4.1.1.0(2,4)]octane, 2,7,7-trimethyl-
4))octane,2,7,7-trimethyl-3-oxatricyclo(4.1.1.0(sup
4]octane,2,7,7-trimethyl-3-oxatricyclo[4.1.1.0
alpha-Pinene epoxide
alpha-Pinene oxyde
alpha-pineneepoxide
Pinane, 2,3-epoxy-
2,7,7-trimethyl-3-oxatricyclo[4.1.1.02,4]octane | [EINECS(EC#)]
216-869-6 | [Molecular Formula]
C10H16O | [MDL Number]
MFCD00066955 | [Molecular Weight]
152.23 | [MOL File]
1686-14-2.mol |
| Safety Data | Back Directory | [RIDADR ]
2810 | [WGK Germany ]
3
| [RTECS ]
TK4565000
| [HS Code ]
2910.90.9100 | [HazardClass ]
6.1 | [PackingGroup ]
III |
| Hazard Information | Back Directory | [Definition]
ChEBI: Alpha-pinene oxide is an epoxide of alpha-pinene. It has a role as a fragrance, a bacterial xenobiotic metabolite and a human metabolite. It is a pinane monoterpenoid and an epoxide. It derives from a hydride of an alpha-pinene. | [Preparation]
a-Pinene oxide is prepared industrially by
using percarboxylic acid. Processes
based on air oxidation are also known. | [Uses]
An industrially important reaction of optically
active a-pinene oxide is rearrangement to
campholene aldehyde (e.g., in the presence of
zinc bromide). Subsequent aldol condensation
with lower aliphatic aldehydes or ketones (e.g.,
propionaldehyde, butyraldehyde, or acetone)
provides unsaturated aldehydes or ketones that can be reduced to the corresponding
saturated alcohols. These are used in
the fragrance industry as a sandalwood scent. |
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