ChemicalBook--->CAS DataBase List--->16919-58-7

16919-58-7

16919-58-7 Structure

16919-58-7 Structure
IdentificationMore
[Name]

Ammonium chloroplatinate
[CAS]

16919-58-7
[Synonyms]

AMMONIUM CHLOROPLATINATE
AMMONIUM HEXACHLOROPLATINATE
AMMONIUM HEXACHLOROPLATINATE(IV)
diammonium hexachloroplatinate
PLATINUM AMMONIUM CHLORIDE
PLATINUM(IV)-AMMONIUM CHLORIDE
Ammoniumchloroplatinate(IV)
ammoniumplatinicchloride
diammonium,(oc-6-11)-platinate(2-hexachloro-
diammoniumhexachloroplatinate(2-)
platinicammoniumchloride
Ammonium chlororhodite(II) monohydrate
AMMONIUM HEXACHLOROPLATINATE(IV), 99.999% METALS BASIS
Ammoniumhexachloroplatinate(IV),Pt44%
Ammonium hexachloroplatinate(IV), 99.999%
Ammoniumhexachloroplatinate(IV),99%
AMMONIUM HEXACHLOROPLATINATE(IV) , SEE AMMONIUM SECTION
Platinate(2-), hexachloro-, diammonium, (OC-6-11)-
Ammonium hexachloroplatinate(IV), Pt 43.4% min
Aiammonium hexachloroplatinate(2-)
[EINECS(EC#)]

240-973-0
[Molecular Formula]

ClH4NPt
[MDL Number]

MFCD00010886
[Molecular Weight]

248.57
[MOL File]

16919-58-7.mol
Chemical PropertiesBack Directory
[Appearance]

Ammonium chloroplatinate is an orange-red crystalline cubic solid or yellow powder which decomposes when heated.
[Melting point ]

°Cd ec.)
[density ]

3.07 g/mL at 25 °C(lit.)
[storage temp. ]

under inert gas (nitrogen or Argon) at 2-8°C
[solubility ]

insoluble in ethanol
[form ]

Powder
[color ]

Yellow
[Specific Gravity]

3.065
[Water Solubility ]

Slightly soluble in water. Insoluble in alcohol, ether and concentrated hydrochloric acid.
[Sensitive ]

Hygroscopic
[Merck ]

14,548
[Exposure limits]

ACGIH: TWA 0.002 mg/m3
NIOSH: IDLH 4 mg/m3; TWA 0.002 mg/m3
[Stability:]

hygroscopic
[InChI]

InChI=1S/6ClH.2H3N.Pt/h6*1H;2*1H3;/q;;;;;;;;+4/p-4
[InChIKey]

PCCGQTHFYHJATL-UHFFFAOYSA-J
[SMILES]

[Pt-2](Cl)(Cl)(Cl)(Cl)(Cl)Cl.[NH4+].[NH4+]
[CAS DataBase Reference]

16919-58-7(CAS DataBase Reference)
[EPA Substance Registry System]

16919-58-7(EPA Substance)
Safety DataBack Directory
[Symbol(GHS) ]

Corrosion (GHS05)Skull and Crossbones (GHS06)Health Hazard (GHS08)
GHS05,GHS06,GHS08
[Signal word ]

Danger
[Hazard statements ]

H301-H317-H318-H334
[Precautionary statements ]

P280-P301+P310+P330-P302+P352-P305+P351+P338+P310
[Hazard Codes ]

T
[Risk Statements ]

R25:Toxic if swallowed.
R41:Risk of serious damage to eyes.
R42/43:May cause sensitization by inhalation and skin contact .
[Safety Statements ]

S22:Do not breathe dust .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
[RIDADR ]

UN 3288 6.1/PG 3
[WGK Germany ]

1
[RTECS ]

BP5425000
[TSCA ]

Yes
[REACH Registrations]

Inactive
[HazardClass ]

6.1
[PackingGroup ]

III
[Storage Class]

6.1C - Combustible acute toxic Cat.3
toxic compounds or compounds which causing chronic effects
[Hazard Classifications]

Acute Tox. 3 Oral
Eye Dam. 1
Resp. Sens. 1
Skin Sens. 1
[Safety Profile]

Poison by inhalation and ingestion. Human pulmonary system effects by inhalation. See also PLATINUM COMPOUNDS. An explosively unstable compound. Incompatible with KOH (boiling with alkali yields a product which, after drying, will explode @ 205' or if mixed with combustibles). When heated to decomposition it emits very toxic fumes of Cl-, NOx, and NH3.
[Hazardous Substances Data]

16919-58-7(Hazardous Substances Data)
[Toxicity]

LD50 orl-rat: 195 mg/kg GTPZAB 21(7),55,77
Raw materials And Preparation ProductsBack Directory
[Preparation Products]

Platinum-->Chloroplantinic acid
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

Ammonium hexachloroplatinate(IV)(16919-58-7).msds
Hazard InformationBack Directory
[Potential Exposure]

It is used in photography, platinum plating and in the manufacture of platinum sponge.
[First aid]

If this chemical gets into the eyes, remove any contact lenses at once and irrigate immediately for at least 15 minutes, occasionally lifting upper and lower lids. Seek medical attention immediately. Like treatment for other platinum salts remove victim to fresh air and give oxygen. Nasal washing to remove salts is recommended. In case of skin or eye contact, irrigate with water immediately. If this chemical contacts the skin, remove contaminated clothing and wash immediately with soap and water. Seek medical attention immediately. If this chemical has been inhaled, remove from exposure, begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR if heart action has stopped. Transfer promptly to a medical facility. When this chemical has been swallowed, get medical attention. Give large quantities of water and induce vomiting. Do not make an unconscious person vomit.
[Shipping]

UN3288 Toxic solids, inorganic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required.
[Incompatibilities]

This material is unstable and potentially explosive. Incompatible with strong oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides.
[Chemical Properties]

Ammonium chloroplatinate is an orange-red crystalline cubic solid or yellow powder which decomposes when heated.
[Chemical Properties]

YELLOW CUBIC CRYSTALS
[Waste Disposal]

Because of the high value of the metal, recovery is the economically indicated disposal method.
[Uses]

Electroplating of platinum, manufacturing of platinum spongeAmmonium hexachloroplatinate(IV) is used in electroplating of platinum and to make spongy platinum. It reacts with copper(II) acetate and hydrogen sulfide to prepare Cu2PtIIPt3IVS8 which finds application in diamagnetic materials and semiconductors. It is also used in platinum plating. Further, it acts as an analytical reagent.
[Uses]

Platinum plating; manufacture of spongy platinum.
[Definition]

ChEBI: Ammonium hexachloroplatinate is an ammonium salt comprising separate ammonium cations and octahedral [PtCl6](2-) anions. It contains a hexachloroplatinate(2-).
[Flammability and Explosibility]

Notclassified
Well-known Reagent Company Product InformationBack Directory
[Alfa Aesar]

Ammonium hexachloroplatinate(IV), Pt 43.4% min(16919-58-7)
[Sigma Aldrich]

16919-58-7(sigmaaldrich)
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