| Identification | More | [Name]
Ammonium chloroplatinate | [CAS]
16919-58-7 | [Synonyms]
AMMONIUM CHLOROPLATINATE
AMMONIUM HEXACHLOROPLATINATE
AMMONIUM HEXACHLOROPLATINATE(IV)
diammonium hexachloroplatinate
PLATINUM AMMONIUM CHLORIDE
PLATINUM(IV)-AMMONIUM CHLORIDE
Ammoniumchloroplatinate(IV)
ammoniumplatinicchloride
diammonium,(oc-6-11)-platinate(2-hexachloro-
diammoniumhexachloroplatinate(2-)
platinicammoniumchloride
Ammonium chlororhodite(II) monohydrate
AMMONIUM HEXACHLOROPLATINATE(IV), 99.999% METALS BASIS
Ammoniumhexachloroplatinate(IV),Pt44%
Ammonium hexachloroplatinate(IV), 99.999%
Ammoniumhexachloroplatinate(IV),99%
AMMONIUM HEXACHLOROPLATINATE(IV) , SEE AMMONIUM SECTION
Platinate(2-), hexachloro-, diammonium, (OC-6-11)-
Ammonium hexachloroplatinate(IV), Pt 43.4% min
Aiammonium hexachloroplatinate(2-) | [EINECS(EC#)]
240-973-0 | [Molecular Formula]
ClH4NPt | [MDL Number]
MFCD00010886 | [Molecular Weight]
248.57 | [MOL File]
16919-58-7.mol |
| Chemical Properties | Back Directory | [Appearance]
Ammonium chloroplatinate is an orange-red
crystalline cubic solid or yellow powder which decomposes
when heated. | [Melting point ]
°Cd ec.) | [density ]
3.07 g/mL at 25 °C(lit.)
| [storage temp. ]
under inert gas (nitrogen or Argon) at 2-8°C | [solubility ]
insoluble in ethanol | [form ]
Powder | [color ]
Yellow | [Specific Gravity]
3.065 | [Water Solubility ]
Slightly soluble in water. Insoluble in alcohol, ether and concentrated hydrochloric acid. | [Sensitive ]
Hygroscopic | [Merck ]
14,548 | [Exposure limits]
ACGIH: TWA 0.002 mg/m3
NIOSH: IDLH 4 mg/m3; TWA 0.002 mg/m3 | [Stability:]
hygroscopic | [CAS DataBase Reference]
16919-58-7(CAS DataBase Reference) | [EPA Substance Registry System]
16919-58-7(EPA Substance) |
| Safety Data | Back Directory | [Hazard Codes ]
T | [Risk Statements ]
R25:Toxic if swallowed.
R41:Risk of serious damage to eyes.
R42/43:May cause sensitization by inhalation and skin contact . | [Safety Statements ]
S22:Do not breathe dust .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) . | [RIDADR ]
UN 3288 6.1/PG 3
| [WGK Germany ]
1
| [RTECS ]
BP5425000
| [TSCA ]
Yes | [HazardClass ]
6.1 | [PackingGroup ]
III | [Safety Profile]
Poison by inhalation and ingestion. Human pulmonary system effects by inhalation. See also PLATINUM COMPOUNDS. An explosively unstable compound. Incompatible with KOH (boiling with alkali yields a product which, after drying, will explode @ 205' or if mixed with combustibles). When heated to decomposition it emits very toxic fumes of Cl-, NOx, and NH3. | [Hazardous Substances Data]
16919-58-7(Hazardous Substances Data) | [Toxicity]
LD50 orl-rat: 195 mg/kg GTPZAB 21(7),55,77 |
| Hazard Information | Back Directory | [Potential Exposure]
It is used in photography, platinum
plating and in the manufacture of platinum sponge. | [First aid]
If this chemical gets into the eyes, remove any
contact lenses at once and irrigate immediately for at least
15 minutes, occasionally lifting upper and lower lids. Seek
medical attention immediately. Like treatment for other platinum
salts remove victim to fresh air and give oxygen. Nasal
washing to remove salts is recommended. In case of skin or
eye contact, irrigate with water immediately. If this chemical
contacts the skin, remove contaminated clothing and wash
immediately with soap and water. Seek medical attention
immediately. If this chemical has been inhaled, remove from
exposure, begin rescue breathing (using universal precautions,
including resuscitation mask) if breathing has stopped
and CPR if heart action has stopped. Transfer promptly to a
medical facility. When this chemical has been swallowed,
get medical attention. Give large quantities of water and
induce vomiting. Do not make an unconscious person vomit. | [Shipping]
UN3288 Toxic solids, inorganic, n.o.s., Hazard
Class: 6.1; Labels: 6.1-Poisonous materials, Technical
Name Required. | [Incompatibilities]
This material is unstable and potentially
explosive. Incompatible with strong oxidizers (chlorates,
nitrates, peroxides, permanganates, perchlorates,
chlorine, bromine, fluorine, etc.); contact may cause fires
or explosions. Keep away from alkaline materials, strong
bases, strong acids, oxoacids, epoxides. | [Chemical Properties]
Ammonium chloroplatinate is an orange-red
crystalline cubic solid or yellow powder which decomposes
when heated. | [Chemical Properties]
YELLOW CUBIC CRYSTALS | [Waste Disposal]
Because of the high value of
the metal, recovery is the economically indicated disposal
method. | [Uses]
Electroplating of platinum, manufacturing of platinum spongeAmmonium hexachloroplatinate(IV) is used in electroplating of platinum and to make spongy platinum. It reacts with copper(II) acetate and hydrogen sulfide to prepare Cu2PtIIPt3IVS8 which finds application in diamagnetic materials and semiconductors. It is also used in platinum plating. Further, it acts as an analytical reagent. | [Uses]
Platinum plating; manufacture of spongy platinum. | [Definition]
ChEBI: Ammonium hexachloroplatinate is an ammonium salt comprising separate ammonium cations and octahedral [PtCl6](2-) anions. It contains a hexachloroplatinate(2-). | [Flammability and Explosibility]
Notclassified |
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