ChemicalBook--->CAS DataBase List--->108-23-6

108-23-6

108-23-6 Structure

108-23-6 Structure
IdentificationMore
[Name]

Isopropyl chloroformate
[CAS]

108-23-6
[Synonyms]

CARBONOCHLORIDIC ACID 1-METHYLETHYL ESTER
CHLOROFORMIC ACID ISOPROPYL ESTER
IPCF
ISOPROPYL CHLOROCARBONATE
ISOPROPYL CHLOROFORMATE
1-methylethylchloroformate
carbonochlorideacid,1-methylethylester
Carbonochloridicacid,1-methylester
chlorocarbonicacidisopropylester
chloro-formicaciisopropylester
isopropylchloroformatesolution
isopropylchloromethanoate
isopropylesterkyselinychlormravenci
ISOPROPYL CHLOROFORMATE, 1.0M SOLUTION I N TOLUENE
ISOPROPYL CHLOROFORMATE SOLUTION, 1.0 M IN TOLUENE
ISOPROPYL CHLOROFORMATE 98%
ISOPROPYL CHLOROMATE
ISOPROPYL1-CHLOROMETHANOATE
Isopropyl chloroformate,Carbonochloridic acid, 1-methyl ester,chloro-formic aci isopropyl ester,isopropyl chlorocarbonate,Carbonochloridic acid 1-methylethyl ester,isopropylchloroformate,1-methylethyl chloroformate
1-PROPYLCHLOROFORMATE
[EINECS(EC#)]

203-563-2
[Molecular Formula]

C4H7ClO2
[MDL Number]

MFCD00075068
[Molecular Weight]

122.55
[MOL File]

108-23-6.mol
Chemical PropertiesBack Directory
[Appearance]

Clear colorless solution
[Boiling point ]

105 °C
[density ]

0.892 g/mL at 25 °C
[vapor pressure ]

27.998hPa at 20℃
[refractive index ]

n20/D 1.485(lit.)
[Fp ]

43 °F
[storage temp. ]

2-8°C
[solubility ]

Chloroform (Sparingly), Dichloromethane (Soluble), Ethyl Acetate (Slightly), Tol
[form ]

liquid
[BRN ]

506416
[Henry's Law Constant]

2.4×10-3 mol/(m3Pa) at 25℃, HSDB (2015)
[Stability:]

Moisture Sensitive
[InChI]

InChI=1S/C4H7ClO2/c1-3(2)7-4(5)6/h3H,1-2H3
[InChIKey]

IVRIRQXJSNCSPQ-UHFFFAOYSA-N
[SMILES]

C(Cl)(OC(C)C)=O
[Uses]

Chemical intermediate for free-radical polymerization initiators, organic synthesis.
[CAS DataBase Reference]

108-23-6(CAS DataBase Reference)
[EPA Substance Registry System]

Isopropyl chloroformate (108-23-6)
Safety DataBack Directory
[Symbol(GHS) ]

Flame (GHS02)Corrosion (GHS05)Skull and Crossbones (GHS06)Health Hazard (GHS08)
GHS02,GHS05,GHS06,GHS08
[Signal word ]

Danger
[Hazard statements ]

H225-H304-H314-H317-H330-H336-H361d-H373
[Precautionary statements ]

P210-P260-P280-P284-P301+P310-P305+P351+P338
[Hazard Codes ]

F,C
[Risk Statements ]

R11:Highly Flammable.
R34:Causes burns.
R48/20:Harmful: danger of serious damage to health by prolonged exposure through inhalation .
R63:Possible risk of harm to the unborn child.
R65:Harmful: May cause lung damage if swallowed.
R67:Vapors may cause drowsiness and dizziness.
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S62:If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label .
[RIDADR ]

UN 3286 3/PG 2
[WGK Germany ]

2
[RTECS ]

LQ6475000
[F ]

10-19
[TSCA ]

TSCA listed
[REACH Registrations]

Active
[HazardClass ]

6.1(a)
[PackingGroup ]

I
[HS Code ]

29159000
[Storage Class]

3 - Flammable liquids
[Hazard Classifications]

Acute Tox. 1 Inhalation
Aquatic Chronic 3
Asp. Tox. 1
Eye Dam. 1
Flam. Liq. 2
Repr. 2
Skin Corr. 1B
Skin Sens. 1
STOT RE 2
STOT SE 3
[Hazardous Substances Data]

108-23-6(Hazardous Substances Data)
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Flow Cell
[Preparation Products]

3-Formyl-azetidine-1-carboxylic acid tert-butyl ester-->DIETHOFENCARB-->Chlorpropham-->Isopropylcyclopentane-->(3-Hydroxy-phenyl)-carbamic acid isopropyl ester-->CarbaMic acid, [2-iodo-4-Methyl-5-(trifluoroMethyl)phenyl]-, 1-Methylethyl ester (9CI)-->(S)-(7-Cyano-1,2,3,4-tetrahydrocyclopenta[b]indol-2-yl)carbamic Acid Isopropyl Ester-->Benzoic acid, 5-Methyl-2-[[(1-Methylethoxy)carbonyl]aMino]-4-(trifluoroMethyl)-, Methyl ester
Hazard InformationBack Directory
[General Description]

A clear colorless volatile liquid with a pungent irritating odor. About the same density as water and insoluble in water. Floats on water Flash point 75°F. Very irritating to skin and eyes and very toxic by inhalation, ingestion and skin absorption. Used to make other chemicals.
[Reactivity Profile]

ISOPROPYL CHLOROFORMATE(108-23-6) is water reactive. A sample stored in a refrigerator exploded [Wischmeyer 1973]. Attacks many metals especially in humid atmosphere [Handling Chemicals Safely, 1980. p. 476]. May react vigorously or explosively if mixed with diisopropyl ether or other ethers in the presence of trace amounts of metal salts [J. Haz. Mat., 1981, 4, 291].
[Air & Water Reactions]

Highly flammable. Gives off HCl fumes in moist air. Insoluble in water. Decomposes slowly in water forming isopropyl alcohol, HCl, and CO2.
[Hazard]

Toxic by inhalation.
[Health Hazard]

Acute: highly toxic by inhalation, ingestion and skin absorption. Delayed: can produce delayed pulmonary edema (2-24 hours after exposure) similar to that produced by phosgene. Inhalation of material may cause death or permanent injury.
[Fire Hazard]

Extremely dangerous; this chemical has exploded while stored in refrigerator. Vapor explosion hazard indoors, outdoors or in sewers. Runoff to sewer may create fire or explosion hazard. Like other chlorides, when heated to decomposition or on contact with acids or acrid fumes, they evolve highly toxic chloride fumes. Reacts violently with phosgene. Unstable, avoid phosgene
[Chemical Properties]

Clear colorless solution
[Production Methods]

Prepared by the reaction of liquid anhydrous isopropyl alcohol with molar excess of dry, chlorine-free phosgene at low temperature.
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

Carbonochloridic acid 1-methylethyl ester(108-23-6).msds
Spectrum DetailBack Directory
[Spectrum Detail]

Isopropyl chloroformate(108-23-6)MS
Isopropyl chloroformate(108-23-6)1HNMR
Isopropyl chloroformate(108-23-6)13CNMR
Isopropyl chloroformate(108-23-6)IR1
Well-known Reagent Company Product InformationBack Directory
[Sigma Aldrich]

108-23-6(sigmaaldrich)
[TCI AMERICA]

Isopropyl Chloroformate,>97.0%(T)(108-23-6)
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