ChemicalBook--->CAS DataBase List--->18297-63-7

18297-63-7

18297-63-7 Structure

18297-63-7 Structure
IdentificationMore
[Name]

1,3-Bis(trimethylsilyl)urea
[CAS]

18297-63-7
[Synonyms]

BIS(TRIMETHYLSILYL)UREA
BSU
N,N'-BIS(TRIMETHYLSILYL)UREA
Bis(trimethylsilyl) derivative of Urea
n,n’-bis(trimethylsilyl)-ure
N,N'-Di(trimethylsilyl)urea
N1,N2-Bis(trimethylsilyl)urea
Urea, 1,3-bis(trimethylsilyl)-
Urea, N,N'-bis(trimethylsilyl)-
Urea, TMS
N N'-BIS(TRIMETHYLSILYL)UREA 98+%
Hexamethyl disilaurea
Bis-(Trimethylsilyl)-Urea (BSU)
Ureylenebis(trimethylsilane)
[EINECS(EC#)]

242-177-9
[Molecular Formula]

C7H20N2OSi2
[MDL Number]

MFCD00008260
[Molecular Weight]

204.42
[MOL File]

18297-63-7.mol
Chemical PropertiesBack Directory
[Appearance]

White solid with mild odor
[Melting point ]

219-221 °C(lit.)
[Boiling point ]

222°C
[density ]

0.887
[vapor pressure ]

0.002-1850Pa at 25℃
[Fp ]

65°C
[storage temp. ]

Inert atmosphere,Room Temperature
[solubility ]

pyridine: soluble100mg/mL, clear to slightly hazy, colorless to light yellow
[form ]

solid
[pka]

16.51±0.46(Predicted)
[color ]

White to Almost white
[Water Solubility ]

Reacts with water.
[Hydrolytic Sensitivity]

7: reacts slowly with moisture/water
[Sensitive ]

Moisture Sensitive
[BRN ]

1937452
[InChI]

1S/C7H20N2OSi2/c1-11(2,3)8-7(10)9-12(4,5)6/h1-6H3,(H2,8,9,10)
[InChIKey]

MASDFXZJIDNRTR-UHFFFAOYSA-N
[SMILES]

C[Si](C)(C)NC(=O)N[Si](C)(C)C
[LogP]

-2.11-2.72 at 20℃
[CAS DataBase Reference]

18297-63-7(CAS DataBase Reference)
[NIST Chemistry Reference]

Urea, n,n'-bis(trimethylsilyl)-(18297-63-7)
[EPA Substance Registry System]

18297-63-7(EPA Substance)
Safety DataBack Directory
[Hazard Codes ]

F,Xn
[Risk Statements ]

R11:Highly Flammable.
R36/37/38:Irritating to eyes, respiratory system and skin .
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed .
[Safety Statements ]

S14:Keep away from ... (incompatible materials to be indicated by the manufacturer) .
S16:Keep away from sources of ignition-No smoking .
S24/25:Avoid contact with skin and eyes .
S36:Wear suitable protective clothing .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
[RIDADR ]

UN 1325 4.1/PG 2
[WGK Germany ]

3
[F ]

3-10-21
[TSCA ]

Yes
[REACH Registrations]

Active
[HS Code ]

29310095
[Storage Class]

4.1B - Flammable solid hazardous materials
[Hazard Classifications]

Flam. Sol. 1
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

N,N'-Bis(trimethylsilyl)urea(18297-63-7).msds
Questions And AnswerBack Directory
[General Description]

Silazane is any hydride of silicon and nitrogen having a straight or branched chain of silicon and nitrogen atoms joined by covalent bonds. By extension, the word is also used for any organic derivative of such compounds. They are analogous to siloxanes, with -NH- replacing -O-. Their individual name is dependent on the number of silicon atoms in the chemical structure. 1,3-Bis(trimethylsilyl)urea is an effective silylating agent. It is used in the pharmaceutical and in the chemical industry.
Hazard InformationBack Directory
[Chemical Properties]

White solid with mild odor
[Uses]

N,N'-Bis(trimethylsilyl)urea is used as a reagent for the silylation of alcohols and carboxylic acids.
[Flammability and Explosibility]

Notclassified
Spectrum DetailBack Directory
[Spectrum Detail]

1,3-Bis(trimethylsilyl)urea(18297-63-7)1HNMR
1,3-Bis(trimethylsilyl)urea(18297-63-7)13CNMR
1,3-Bis(trimethylsilyl)urea(18297-63-7)IR1
1,3-Bis(trimethylsilyl)urea(18297-63-7)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

1,3-Bis(trimethylsilyl)urea, 98%(18297-63-7)
[Alfa Aesar]

N,N'-Bis(trimethylsilyl)urea, 98+%(18297-63-7)
[Sigma Aldrich]

18297-63-7(sigmaaldrich)
[TCI AMERICA]

N,N'-Bis(trimethylsilyl)urea,>97.0%(T)(18297-63-7)
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