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18497-13-7

18497-13-7 Structure

18497-13-7 Structure
IdentificationMore
[Name]

CHLOROPLATINIC ACID HEXAHYDRATE
[CAS]

18497-13-7
[Synonyms]

CHLOROPLATINIC ACID
CHLOROPLATINIC ACID, 6-HYDRATE
CHLOROPLATINIC ACID HEXAHYDRATE
CHLOROPLATINIC ACID HEXAHYDRATE(IV)
DIHYDROGEN HEXACHLOROPLATINATE HEXAHYDRATE
DIHYDROGEN HEXACHLOROPLATINATE(IV)
HEXACHLOROPLATINIC ACID
HEXACHLOROPLATINIC ACID HEXAHYDRATE
HEXACHLOROPLATINIC(IV) ACID HEXAHYDRATE
HEXACHLORO PLATINUM(IV) ACID HEXAHYDRATE
HYDROGEN HEXACHLOROPLATINATE(+4)HEXAHYDRATE
HYDROGEN HEXACHLOROPLATINATE(IV) HEXAHYDRATE
PLATINIC CHLORIDE HEXAHYDRATE
PLATINUM CHLORIDE
PLATINUM CHLORIDE, HEXAHYDRATE
PLATINUM (IV) CHLORIDE
PLATINUM(IV) CHLORIDE ACID HEXAHYDRATE
PLATINUM(IV) CHLORIDE HEXAHYDRATE
Chloroplatinicacid,hexahydrat
chloroplatinicacidhexahydrate*acs
[EINECS(EC#)]

241-010-7
[Molecular Formula]

Cl6H14O6Pt
[MDL Number]

MFCD00149910
[Molecular Weight]

517.9
[MOL File]

18497-13-7.mol
Chemical PropertiesBack Directory
[Appearance]

orange to orange-brown powder or chunks
[Melting point ]

60 °C
[density ]

2.430
[storage temp. ]

2-8°C
[solubility ]

H2O: soluble0.5M, clear, orange
[form ]

Solid Powder
[color ]

orange
[Water Solubility ]

Soluble in water, ethanol, ether, ethyl acetate and acetone. Insoluble in nitric acid.
[Sensitive ]

Hygroscopic
[Exposure limits]

ACGIH: TWA 0.002 mg/m3
NIOSH: IDLH 4 mg/m3; TWA 0.002 mg/m3
[Stability:]

Hygroscopic
[InChI]

InChI=1S/6ClH.H2O.Pt/h6*1H;1H2;/q;;;;;;;+4/p-5
[InChIKey]

KVERJCFPWMYIII-UHFFFAOYSA-J
[SMILES]

[Pt+4]([Cl-])([Cl-])([Cl-])([Cl-])([Cl-])[Cl-].[H+].O
[CAS DataBase Reference]

18497-13-7(CAS DataBase Reference)
[Storage Precautions]

Moisture sensitive;Light sensitive
[EPA Substance Registry System]

Platinate(2-), hexachloro-, dihydrogen, hexahydrate, (OC-6-11)- (18497-13-7)
Safety DataBack Directory
[Symbol(GHS) ]

Corrosion (GHS05)Skull and Crossbones (GHS06)Health Hazard (GHS08)
GHS05,GHS06,GHS08
[Signal word ]

Danger
[Hazard statements ]

H301-H314-H317-H334
[Precautionary statements ]

P260-P270-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338
[Hazard Codes ]

T
[Risk Statements ]

R42/43:May cause sensitization by inhalation and skin contact .
R34:Causes burns.
R25:Toxic if swallowed.
[Safety Statements ]

S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S22:Do not breathe dust .
[RIDADR ]

UN 2507 8/PG 3
[WGK Germany ]

1
[RTECS ]

TP1510000
[TSCA ]

Yes
[HazardClass ]

8
[PackingGroup ]

III
[HS Code ]

28439000
[Storage Class]

6.1D - Non-combustible acute toxic Cat.3
toxic hazardous materials or hazardous materials causing chronic effects
[Hazard Classifications]

Acute Tox. 3 Oral
Eye Dam. 1
Resp. Sens. 1
Skin Corr. 1B
Skin Sens. 1
[Safety Profile]

Poison by intraperitoneal route. When heated to decomposition it emits toxic fumes of Pt and Cl-.
[Toxicity]

mouse,LD50,intraperitoneal,82mg/kg (82mg/kg),Toxicology and Applied Pharmacology. Vol. 49, Pg. 41, 1979.
Hazard InformationBack Directory
[Chemical Properties]

orange to orange-brown powder or chunks
[Uses]

Dihydrogen hexachloroplatinate(IV) hexahydrate is used for the determination of potassium. It is also used for the purification of platinum by treating it with ammonium chloride flowed by heating of ammonium hexachloroplatinate with hydrogen yields elemental platinum. It also finds application in catalysis, electroplating, photography, platinum mirrors, printing for etching of zinc, producing fine color in glass and porcelain, indelible ink and microscopy. It is a precursor for the preparation of other platinum catalysts.
[General Description]

Chloroplatinic acid hexahydrate (H2PtCl6.6H2O) is an inorganic platinum salt. Pure quadrupole resonance frequencies of Cl35 in H2PtCl6.6H2O have been evaluated by spectrophotometric investigations.
[reaction suitability]

reagent type: catalyst
core: platinum
Spectrum DetailBack Directory
[Spectrum Detail]

CHLOROPLATINIC ACID HEXAHYDRATE(18497-13-7)IR1
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Hydrogen hexachloroplatinate(IV) hexahydrate, 38 to 40% Pt, 99.90%(18497-13-7)
[Alfa Aesar]

Dihydrogen hexachloroplatinate(IV) hexahydrate, low nitrate, Premion, 99.95% (metals basis), Pt 37.5% min(18497-13-7)
[Sigma Aldrich]

18497-13-7(sigmaaldrich)
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