| Identification | Back Directory | [Name]
Dichlorobis(trimethylphosphine)nickel(II) | [CAS]
19232-05-4 | [Synonyms]
orobis(trimethyL
DICHLOROBIS(TRIMETHYLPHOSPHINE)NICKEL(I&
Dichlorobis(trimethylphosphine)nickel(II)
(II)Dichlorobis(triMethylphosphine)nickel
dichlorobis(trimethylphosphine)nickel(ii) 2(
Dichlorobis(triMethylphosphine)nickel(II),97% | [Molecular Formula]
C6H18Cl2NiP2 | [MDL Number]
MFCD03412128 | [MOL File]
19232-05-4.mol | [Molecular Weight]
281.75 |
| Chemical Properties | Back Directory | [Melting point ]
194-199 °C(lit.) | [storage temp. ]
2-8°C, protect from light, stored under nitrogen | [form ]
solid | [Appearance]
Brown to reddish brown Solid | [λmax]
244 nm | [InChI]
1S/2C3H9P.2ClH.Ni/c2*1-4(2)3;;;/h2*1-3H3;2*1H;/q;;;;+2/p-2 | [InChIKey]
KYHNNWWCXIOTKC-UHFFFAOYSA-L | [SMILES]
Cl[Ni]Cl.CP(C)C.CP(C)C |
| Safety Data | Back Directory | [Hazard Codes ]
Xn | [Risk Statements ]
20/21/22 | [Safety Statements ]
36/37 | [WGK Germany ]
3 | [Storage Class]
11 - Combustible Solids | [Hazard Classifications]
Acute Tox. 4 Dermal
Acute Tox. 4 Inhalation
Acute Tox. 4 Oral |
| Hazard Information | Back Directory | [Uses]
Catalyst for:
- Wenkert arylation of thiophene with aryl Grignard reagents
- Regioselective [2+2+2] cycloaddition of carboryne with alkynes to give benzocarborane compounds
- Kumada-Corriu cross coupling of Grignard reagents
- Borylation of aryl chlorides
- Reductive aldol cyclization-lactonization
- Arylcyanation of alkynes
- Alkynylation of benzonitriles via C-C bond activation
| [reaction suitability]
core: nickel
reagent type: catalyst |
|
| Company Name: |
Sigma-Aldrich
|
| Tel: |
021-61415566 800-8193336 |
| Website: |
https://www.sigmaaldrich.cn |
| Company Name: |
Energy Chemical
|
| Tel: |
021-58432009 400-005-6266 |
| Website: |
http://www.energy-chemical.com |
|