| Identification | More | [Name]
Tetrabutylammonium hydroxide | [CAS]
2052-49-5 | [Synonyms]
IPC-TBA-OH
TBH
TETRABUTYLAMMONIUM HYDROXIDE
TETRABUTYLAMMONIUM HYDROXIDE IN WATER
TETRABUTYLAMMONIUM HYDROXIDE TITRANT
TETRA-N-BUTYLAMMONIUM HYDROXIDE
1-Butanaminium,N,N,N-tributyl-,hydroxide
1-ButanaminiumN,N,N-tributyl-,hydroxide
aqueoussolution
n,n,n-tributyl-1-butanaminiuhydroxide
n,n,n-tributyl-1-butanaminiumhydroxide
n-n-n-tributyl-1-butanaminiuhydroxide
tetrabutyl-ammoniuhydroxide
tetrabutylammoniumhydroxide,1.0maqueoussolution
tetrabutylammoniumhydroxide,1.0msolutioninmethanol
tetrabutylammoniumhydroxide,25%solutioninmethanol
tetrabutylammoniumhydroxide,55%(wiw)aqueoussolution
tetrabutylammoniumhydroxide,solution
Tetrabutylammoniumhydroxides
tetrabutylammoniumhydroxidetitrant,0.4msolutioninwater | [EINECS(EC#)]
218-147-6 | [Molecular Formula]
C16H37NO | [MDL Number]
MFCD00009425 | [Molecular Weight]
259.47 | [MOL File]
2052-49-5.mol |
| Chemical Properties | Back Directory | [Appearance]
Aqueous solution. | [Melting point ]
27-30 °C(lit.)
| [Boiling point ]
100 °C
| [density ]
0.995
| [vapor density ]
1 (vs air)
| [vapor pressure ]
2.3 kPa (@ 20°C) | [refractive index ]
1.4 | [Fp ]
7°C | [storage temp. ]
2-8°C
| [solubility ]
Miscible with organic solvents. | [form ]
Solution | [color ]
APHA: ≤30 | [Specific Gravity]
0.8586 | [Odor]
Odorless | [PH]
14 (20°C in H2O) | [PH Range]
14 | [explosive limit]
5.5-36.5% (v/v) Methanol) | [Water Solubility ]
Soluble in water, methanol. | [Sensitive ]
Air Sensitive/Hygroscopic | [Detection Methods]
T | [BRN ]
3571228 | [Exposure limits]
ACGIH: TWA 200 ppm; STEL 250 ppm (Skin)
OSHA: TWA 200 ppm(260 mg/m3)
NIOSH: IDLH 6000 ppm; TWA 200 ppm(260 mg/m3); STEL 250 ppm(325 mg/m3) | [Stability:]
Volatile | [InChIKey]
VDZOOKBUILJEDG-UHFFFAOYSA-M | [LogP]
1.517 at 25℃ | [CAS DataBase Reference]
2052-49-5(CAS DataBase Reference) | [EPA Substance Registry System]
2052-49-5(EPA Substance) |
| Safety Data | Back Directory | [Hazard Codes ]
C,T,F | [Risk Statements ]
R34:Causes burns.
R36/38:Irritating to eyes and skin .
R23/24/25:Toxic by inhalation, in contact with skin and if swallowed .
R11:Highly Flammable.
R67:Vapors may cause drowsiness and dizziness.
R39/23/24/25:Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed .
R36:Irritating to the eyes.
R65:Harmful: May cause lung damage if swallowed.
R63:Possible risk of harm to the unborn child.
R38:Irritating to the skin. | [Safety Statements ]
S7:Keep container tightly closed .
S16:Keep away from sources of ignition-No smoking .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S36/37:Wear suitable protective clothing and gloves .
S62:If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label .
S27:Take off immediately all contaminated clothing . | [RIDADR ]
UN 3267 8/PG 2
| [WGK Germany ]
1
| [RTECS ]
BS5425000
| [F ]
9-34 | [Hazard Note ]
Highly Flammable/Toxic/Corrosive/Air Sensitive/Hygroscopic | [TSCA ]
Yes | [HazardClass ]
3 | [PackingGroup ]
II | [HS Code ]
29239000 |
| Hazard Information | Back Directory | [Chemical Properties]
Aqueous solution. | [Uses]
TBAOH may be used as an ion-pairing reagent in mobile phase preparation for reverse phase ion-pair high performance liquid chromatography during chromium (III) and chromium (VI) determination. | [Uses]
Tetrabutylammonium hydroxide solution (TBAOH) may be used in the following studies:
For the dissolution of 10wt% cellulose under room temperature conditions.
As a catalyst during the synthesis of 1,2,4-oxadiazoles.
Preparation of TBAOH salts of fatty acids. | [Preparation]
Tetrabutylammonium hydroxide was prepared by the ion exchange between gel type strong basic anion exchange resin(OH-) and aqueous solution of tetrabutylammonium bromide. | [General Description]
The product is 54.0-56.0% solution of tetrabutylammonium hydroxide in H2O. Tetrabutylammonium hydroxide has been synthesized from tetrabutylammonium iodide. TBAOH dissolved in anhydrous isopropyl alcohol is widely employed as titrant for weak acids. | [Flammability and Explosibility]
Flammable |
|
|