| Identification | More | [Name]
D(+)-10-Camphorsulfonyl chloride | [CAS]
21286-54-4 | [Synonyms]
(+)-10-CAMPHORSULFONYL CHLORIDE
(1S)-(+)-10-CAMPHORSULFONYL CHLORIDE
(1S)-CAMPHOR-10-SULFONIC ACID CHLORIDE
(1S)-(+)-CAMPHOR-10-SULFONYL CHLORIDE
(1S)-(+)-CAMPHOR-10-SULPHONYL CHLORIDE
(+) CAMPHOR-10-SULFONIC ACID CHLORIDE
(+)-CAMPHOR-10-SULFONYL CHLORIDE
D(+)-10-CAMPHORSULFONYL CHLORIDE
D-CAMPHOR-10-SULFONYL CHLORIDE
Bicyclo[2.2.1]heptane-1-methanesulfonyl chloride, 7,7-dimethyl-2-oxo-, (1S)-
Dextro-10-camphorsulfonyl chloride
d-2-oxobornane-10-sulphonyl chloride
(1S)-(+)-10-CAMPHORSULFONYL CHLORIDE, 97 %
D-CAMPHOR-10-SULFONYL CHLORIDE 96%
(S)-(+)-Camphor-10-SulfonylChloride
D(+)CAMPHOR SULFONYL CHLORIDE
(+)-Camphor-10-sulfonyl chloride, (1S)-Camphor-10-sulfonic acid chloride
Bicyclo[2.2.1]heptane-1-methanesulfonyl chloride, 7,7-dimethyl-2-oxo-
D-2-Oxobornane-10-sulfonyl chloride
(1S,4R)-7,7-Dimethyl-2-oxobicyclo[2.2.1]heptane-1-methanesulfochloride | [EINECS(EC#)]
244-314-8 | [Molecular Formula]
C10H15ClO3S | [MDL Number]
MFCD00064156 | [Molecular Weight]
250.74 | [MOL File]
21286-54-4.mol |
| Chemical Properties | Back Directory | [Appearance]
white to light yellow crystal powde | [Melting point ]
67-68 °C | [alpha ]
33 º (c=1, CHCl3 22 ºC) | [Boiling point ]
349.4±15.0 °C(Predicted) | [density ]
1.2078 (estimate) | [refractive index ]
32 ° (C=1, CHCl3) | [storage temp. ]
2-8°C
| [solubility ]
Chloroform (Slightly), Ethyl Acetate (Slightly) | [form ]
Crystalline Powder | [color ]
Off-white to beige | [Optical Rotation]
[α]22/D +33°, c = 1 in chloroform | [Sensitive ]
Moisture Sensitive | [Usage]
A useful synthetic intermediate. Used for asymmetric hydroxylation | [BRN ]
3205974 | [InChI]
1S/C10H15ClO3S/c1-9(2)7-3-4-10(9,8(12)5-7)6-15(11,13)14/h7H,3-6H2,1-2H3/t7-,10-/m1/s1 | [InChIKey]
BGABKEVTHIJBIW-UHFFFAOYSA-N | [SMILES]
[H][C@@]12CC[C@@](CS(Cl)(=O)=O)(C(=O)C1)C2(C)C | [CAS DataBase Reference]
21286-54-4(CAS DataBase Reference) | [NIST Chemistry Reference]
(+)-Camphor-10-sulfonyl chloride(21286-54-4) |
| Safety Data | Back Directory | [Symbol(GHS) ]
GHS05 | [Signal word ]
Danger | [Hazard statements ]
H314 | [Precautionary statements ]
P260-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338-P363 | [Hazard Codes ]
C | [Risk Statements ]
R34:Causes burns. | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) . | [RIDADR ]
UN 3261 8/PG 2
| [WGK Germany ]
3
| [F ]
10-21 | [HazardClass ]
8 | [PackingGroup ]
II | [HS Code ]
29147000 | [Storage Class]
8A - Combustible corrosive hazardous materials | [Hazard Classifications]
Skin Corr. 1B |
| Hazard Information | Back Directory | [Chemical Properties]
white to light yellow crystal powde | [Uses]
A chiral derivative of Camphor | [Uses]
A chiral derivative of Camphor. | [Uses]
As a useful synthetic intermediate, D(+)-10-Camphorsulfonyl chloride can be used for asymmetric hydroxylation
| [Purification Methods]
If free from OH bands in the IR, then recrystallise it from Et2O or pet ether; otherwise treat it with SOCl2 at 50o for 30minutes, evaporate, dry the residue over KOH in a vacuum and recrystallise it. The (±)-acid chloride has m 85o [Bartlett & Knox Org Synth 45 14 1965]. Itis characterised as the amide (prisms from EtOH) m 132o, [ ] 17 (+) and (-) 1.5o (EtOH). On repeated recrystallisation from EtOH the anilide has m 120.5-121o, [] 25 +76o (c 1, CHCl3). [Read & Storey J Chem Soc 2761 1930, Sutherland & Shriner J Am Chem Soc 58 62 1936, Halterman et al. J Am Chem Soc 109 8105 1987, Bartlet & Knox Org Synth 45 55 1945, Beilstein 11 IV 650.] |
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