Identification | Back Directory | [Name]
HEPTENOPHOS | [CAS]
23560-59-0 | [Synonyms]
RAGADAN hoe2982 xoe2982 hostavik OMS 1845 hoe2982oj Hoe 02982 HEPTENOFOS HOSTAQUICK HEPTENOPHOS Heptanophos heftenophos Heptenophos D6 HEPTENOPHOS STANDARD heptenophos (bsi, iso) HEPTENOPHOS PESTANAL 250 MG Heptenophos@1000 μg/mL in Methanol 7-CHLOROBICYCLO[3.2.0]HEPTA-2,6-DIEN-6-YL DIMETHYL PHOSPHATE 5-(o,o-dimethylphosphoryl)-6-chlorobicyclo(3.2.0)hepta-1,5-dien o,o-dimethyl-o-(6-chlorobicyclo(3.2.0)heptadien-1,5-yl)phosphate o,o’-dimethyl-o-(6-chlorobicyclo(3.2.0)heptadiene-1,5-yl)phosphate O,O-Dimethyl-0-(7-chlorobicyclo[3,2,0]penta-2,6-dien-6-yl)phosphate (7-chlorobicyclo(3.2.0)hepta-3,6-dien-6-yloxy)-phosphonicacidimethyles phosphoricacid,(7-chloro-bicyclo(3.2.0)hepta-2,6-dien-6-yl)dimethylester Phosphoric acid, 7-chlorobicyclo[3.2.0]hepta-2,6-dien-6-yl dimethyl ester heptenophos (ISO) 7-chlorobicyclo(3.2.0)hepta-2,6-dien-6-yl dimethyl phosphate | [EINECS(EC#)]
245-737-0 | [Molecular Formula]
C9H12ClO4P | [MDL Number]
MFCD00055303 | [MOL File]
23560-59-0.mol | [Molecular Weight]
250.62 |
Chemical Properties | Back Directory | [Definition]
A nonpersistent contact and systematic phosphate insecticide. | [Appearance]
Pale amber liquid; miscible in most organic solvents; soluble in xylene, acetone, and methanol. | [Melting point ]
25°C | [Boiling point ]
bp0.001 94-95° | [density ]
d420 1.294 | [vapor pressure ]
6.5 x 10-2 Pa (15 °C) | [Fp ]
2 °C | [storage temp. ]
APPROX 4°C
| [form ]
liquid | [Water Solubility ]
2200 mg l-1 (20 °C) | [EPA Substance Registry System]
Heptenophos (23560-59-0) |
Hazard Information | Back Directory | [Chemical Properties]
Pale amber liquid; miscible in most organic solvents; soluble in xylene, acetone, and methanol. | [Uses]
Insecticide. | [Hazard]
Poison; moderately toxic. | [Description]
Heptenophos is a light brown liquid or crystalline mass. It is soluble
in water (2.2 g/L at 20 ?C) and miscible with most organic
solvents, except aliphatic hydrocarbons. Log Kow = 2.32.
Heptenophos is hydrolyzed in acidic and alkaline media. | [Metabolic pathway]
Metabolism of heptenophos in soils is by hydrolysis to 7-chloro-bicyclo[3.2.0]hept-2-en-6-one, further transformations of which involve
microbially-mediated Baeyer-Villiger oxidations of the cyclobutanone
moiety, ring opening of the resultant lactones, dechlorination and
dehydrochlorination followed by ultimate mineralisation to CO2 and conversion to unextractable soil-bound residues. In rats, 7-chlorobicyclo[3.2.0]hept-2-en-6-one is further transformed to give the Favorskiirearranged product bicyclo[3.l.0]hex-2-en-6-exo-carboxylic acid as a
urinary metabolite. | [Metabolism]
In rats 90% of heptenophos is
excreted in the urine and 6% in the feces as water-soluble
metabolites within 6 days after oral administration. In
plant (lettuce), it is completely transformed to watersoluble
metabolites without accumulation within 4 d. In
soil, it is rapidly degraded bymicroorganisms, DT50 (20 ?C)
being less than 4 h. | [Degradation]
Heptenophos is hydrolysed in acidic and alkaline media (PM). | [Toxicity evaluation]
Acute oral LD50 for rats is
96–121 mg/kg. Inhalation LC50 (4 h) for rats is 0.95 mg/L
air. NOEL (2 yr) for rats is 15 mg/kg diet (0.75 mg/kg/d).
ADI is 3 μg/kg b.w. |
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