ChemicalBook > Product Catalog >Chemical pesticides >Pesticide Intermediates >1,3-Cyclopentadiene

1,3-Cyclopentadiene

1,3-Cyclopentadiene Suppliers list
Company Name: Henan DaKen Chemical CO.,LTD.
Tel: +86-371-55531817
Email: info@dakenchem.com
Products Intro: Product Name:1,3-Cyclopentadiene
CAS:542-92-7
Purity:99.00% Package:100g,500g,1KG,10KG,100KG
Company Name: Henan Tianfu Chemical Co.,Ltd.
Tel: 0371-55170693
Email: info@tianfuchem.com
Products Intro: CAS:542-92-7
Purity:99% Package:500G;1KG;5KG;25KG
Company Name: Mainchem Co., Ltd.
Tel: +86-0592-6210733
Email: sales@mainchem.com
Products Intro: Product Name:1,3-Cyclopentadiene
CAS:542-92-7
Company Name: career henan chemical co
Tel: +86-371-86658258
Email: sales@coreychem.com
Products Intro: Product Name:1,3-Cyclopentadiene
CAS:542-92-7
Purity:98% Package:1KG;1USD
Company Name: Chengdu HuaXia Chemical Reagent Co. Ltd  Gold
Tel: 400-1166-196 QQ:800101999
Email: cdhxsj@163.com
Products Intro: CAS:542-92-7
Purity:99% HPLC Package:5g;25g;100g;500g;1Kg

Lastest Price from 1,3-Cyclopentadiene manufacturers

  • 1,3-Cyclopentadiene
  • US $1.00 / KG
  • 2018-08-17
  • CAS:542-92-7
  • Min. Order: 1G
  • Purity: 98%
  • Supply Ability: 100KG
1,3-Cyclopentadiene Basic information
Product Name:1,3-Cyclopentadiene
Synonyms:1,3-Cyclopentadiene;2,4-Cyclopentadiene;Cyclopentadiene;pentole;pyropentylene;r-pentine
CAS:542-92-7
MF:C5H6
MW:66.10114
EINECS:208-835-4
Product Categories:
Mol File:542-92-7.mol
1,3-Cyclopentadiene Structure
1,3-Cyclopentadiene Chemical Properties
Melting point -85°; mp 32.5°
Boiling point bp760 41.5-42.0°
density d40 0.8235; d410 0.8131; d420 0.8021; d425 0.7966; d430 0.7914
refractive index nD16 1.44632
pka16(at 25℃)
Stability:Stable at room temperature. Incompatible with oxidizing agents, acids and a wide variety of other compounds. May form peroxides in storage. May undergo spontaneous polymerisation. Decomposes on heating. Highly flammable. Mixtures with air are explosive.
Safety Information
RIDADR 1993
HazardClass 3.2
PackingGroup III
ToxicityLD50 of dimer orally in rats: 0.82 g/kg (Smyth)
MSDS Information
1,3-Cyclopentadiene Usage And Synthesis
Chemical Propertiescolourless liquid
Chemical PropertiesCyclopentadiene is a flammable, colorless liq- uid with a sweet odor, like turpentine.
Usesmanufacture of resins; in organic synthesis as the diene in the Diels-Alder reaction producing sesquiterpenes, synthetic alkaloids, camphors.
General Description1,3-Cyclopentadiene is a colorless liquid with an irritating, terpene-like odor. Bp: 42.5°C; Flash point: 77°F. Density: 0.805 g cm-3.
Reactivity Profile1,3-Cyclopentadiene is incompatible with strong oxidizing agents. Ignites on contact with oxygen (O2) and ozone (O3). Explodes on contact with fuming nitric acid or a mixture of sulfuric acid and nitrogen tetroxide. Reacts vigorously on contact with potassium hydroxide and other strong bases. Mixtures with air are explosive. Presents a moderate explosion hazard when exposed to heat or flame. Decomposes violently at high temperature and pressure. May form explosive peroxides in storage. Undergoes a spontaneous dimerization at room temperature to give DI1,3-Cyclopentadiene (C10H12, CAS No: 77-73-6), which is a low-melting solid (melting point: 32.5°C). The reaction is strongly exothermic (Hazardous Chemicals Desk Reference, p. 360 (1987)), but occurs sufficiently slowly that 1,3-Cyclopentadiene can be said to be stable at room temperature. The dimerization accounts for the partial or complete solidification of liquid 1,3-Cyclopentadiene in storage. Polymerization occurs more rapidly and extensively at higher temperatures. When heated to 180-200°C, 1,3-Cyclopentadiene gives poly1,3-Cyclopentadiene, a white waxy solid. Stronger heating breaks down poly1,3-Cyclopentadiene and re-generates the monomeric 1,3-Cyclopentadiene as a vapor. The vapor decomposes violently at higher temperatures and pressures.
Safety ProfileLow toxicity by ingestion. A dangerous fire hazard when exposed to heat or flame; can react with oxidizing materials. Moderate explosion hazard in the form of gas when exposed to heat or by chemical reaction. It decomposes violently at hgh temperatures and pressures. dimerization is highly exothermic. Explosive reaction with fuming nitric acid,dinitrogen tetroxide, sulfuric acid. Reaction with nitrogen oxide + oxygen forms an explosive product. Reaction with oxygen forms a flame-sensitive explosive product. Ignites on contact with oxygen + ozone. Reacts vigorously on contact with potassium hydroxide. Incompatible with oxides of nitrogen, sulfuric acid. When heated to decomposition it emits acrid smoke and fumes.
Potential ExposureCyclopentadiene is used as an inter- mediate in the manufacture of resins, insecticides, fungi- cides, and other chemicals.
First aidIf this chemical gets into the eyes, remove any contact lenses at once and irrigate immediately for at least 15 minutes, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts the skin, remove contaminated clothing and wash immediately with soap and water. Seek medical attention immediately. If this chemical has been inhaled, remove from exposure, begin rescue breathing (using universal precautions, includ- ing resuscitation mask) if breathing has stopped and CPR if heart action has stopped. Transfer promptly to a medical facility. When this chemical has been swallowed, get medi- cal attention. Do NOT induce vomiting.
ShippingUN1993 Flammable liquids, n.o.s., Hazard Class: 3; Labels: 3-Flammable liquid, Technical Name Required.
Purification MethodsDry the diene with Mg(ClO4)2 and distil it rapidly as it dimerises readily at room temperature. It should be used immediately or stored in a Dry Ice or an ice-salt bath. HIGHLY FLAMMABLE. [Moffett Org Synth Coll Vol IV 238 1963.] Cyclopentadiene Dimer (4,7-methano-3a,4,7,7a-tetrahydroindene) has [77-73-6], M 132.3, m 33o, b 170o/atm, and d2 5 0.986; add ~0.05% of 2,6-di-tert-butyl-4-methylphenol as stabilizer. Cyclopentadiene is prepared when required by de-polymerising the technical grade dimer by heating it carefully under a fractionating column [Wilkinson Org Synth Coll Vol IV 467 1963], as described by Moffett (above reference), or by adding the dimer at a steady rate onto mineral oil heated at 240-270o (Korach et al. Org Synth 42 50 1962). [Beilstein 5 II 391.]
IncompatibilitiesVapors may form explosive mixture with air. Converted (dimerized) to higher-boiling dicyclopenta- diene upon standing in air and @ 32 F/0 C; this conversion may be violent and exothermic; this reaction is accelerated by peroxides or trichloroacetic acid. Reacts violently with potassium hydroxide. Violent reaction with strong oxidi- zers; strong acids; dinitrogen tetroxide; magnesium. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoa- cids, epoxides, alkaline earth metals, nitrogen oxides. May accumulate static electrical charges, and may cause ignition of its vapors.
Waste DisposalDissolve or mix the material with a combustible solvent and burn in a chemical incinera- tor equipped with an afterburner and scrubber. All federal, state, and local environmental regulations must be observed.
Tag:1,3-Cyclopentadiene(542-92-7) Related Product Information
Cyclohexene Cyclopentene PENTAMETHYL CYCLOPENTADIENE-1,2,3,4,5-PENTACARBOXYLATE Hexachlorocyclopentadiene DIPHENYLFULVENE 5-(1-Methylethylidene)-1,3-cyclopentadiene, 5-Isopropylidene-1,3-cyclopentadiene,5-(1-Methylethylidene)-1,3-cyclopentadiene, 5-Isopropylidene-1,3-cyclopentadiene (CYCLOPENTADIENYLIDENE)TRIPHENYLPHOSPHORANE 1,2,3,4,5-PENTAPHENYL-1,3-CYCLOPENTADIENE,1,2,3,4,5-PENTAPHENYL-1,3-CYCLOPENTADIENE,1,2,3,4,5-Ppentaphenyl-1,3-cyclopentadiene,99%,1,2,3,4,5-Ppentaphenyl-1,3-cyclopentadiene,99% 1,2,3,4,5-pentamethyl-1,3-cyclopentadiene,1,2,3,4,5-pentamethyl-1,3-cyclopentadiene 2,5-Dimethyl-3,4-diphenylcyclopentadienone CYCLOPENTADIENYLTRIMETHYLSILANE SODIUM CYCLOPENTADIENIDE 5-BROMO-1,2,3,4,5-PENTAPHENYL-1,3-CYCLOPENTADIENE Guaiazulene 1,2,3,4-TETRAPHENYL-1,3-CYCLOPENTADIENE 98%,1,2,3,4-TETRAPHENYL-1,3-CYCLOPENTADIENE 98% TETRAPHENYLCYCLOPENTADIENONE ETHYLTETRAMETHYLCYCLOPENTADIENE LITHIUM CYCLOPENTADIENIDE