| Identification | More | [Name]
Dodine | [CAS]
2439-10-3 | [Synonyms]
1-Dodecylguanidine acetate
AC 5223(R)
CUPENE(R)
CYPREX
CYPREX(R)
DODECYLGUANIDINE MONOACETATE
DODENE
DODEX
DODIN
DODINE
EFUZIN
LAURYLGUANIDINE
LAURYL GUANIDINE ACETATE
MELPREX
MELPREX(R)
N-DODECYLGUANIDIN ACETATE
N-DODECYLGUANIDINE ACETATE
VENTUROL
1-dodecylguanidiniumacetate
1-dodecylguanidiniumethanoate | [EINECS(EC#)]
219-459-5 | [Molecular Formula]
C15H33N3O2 | [MDL Number]
MFCD00034998 | [Molecular Weight]
287.44 | [MOL File]
2439-10-3.mol |
| Chemical Properties | Back Directory | [Melting point ]
136°C | [Boiling point ]
429.73°C (rough estimate) | [density ]
0.9636 (rough estimate) | [vapor pressure ]
5 x 10-6 Pa (20 °C, est.) | [refractive index ]
1.6500 (estimate) | [Fp ]
>100 °C | [storage temp. ]
0-6°C | [solubility ]
DMSO (Slightly, Heated), Methanol (Slightly) | [form ]
neat | [pka]
>13 (strong base) | [Water Solubility ]
630 mg l-1(25 °C) | [Merck ]
13,3442 | [BRN ]
6546960 | [Henry's Law Constant]
1.1×105 mol/(m3Pa) at 25℃, Duchowicz et al. (2020) | [Major Application]
agriculture
environmental | [InChI]
1S/C13H29N3.C2H4O2/c1-2-3-4-5-6-7-8-9-10-11-12-16-13(14)15;1-2(3)4/h2-12H2,1H3,(H4,14,15,16);1H3,(H,3,4) | [InChIKey]
YIKWKLYQRFRGPM-UHFFFAOYSA-N | [SMILES]
CC(O)=O.CCCCCCCCCCCCNC(N)=N | [LogP]
1.150 | [CAS DataBase Reference]
2439-10-3(CAS DataBase Reference) | [NIST Chemistry Reference]
1-dodecylguanidinium acetate(2439-10-3) | [EPA Substance Registry System]
2439-10-3(EPA Substance) |
| Safety Data | Back Directory | [Symbol(GHS) ]
 
GHS07,GHS09 | [Signal word ]
Warning | [Hazard statements ]
H302-H315-H319-H410 | [Precautionary statements ]
P264-P270-P273-P301+P312-P302+P352-P305+P351+P338 | [Hazard Codes ]
Xn;N,N,Xn | [Risk Statements ]
R22:Harmful if swallowed.
R36/38:Irritating to eyes and skin .
R50/53:Very Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S60:This material and/or its container must be disposed of as hazardous waste .
S61:Avoid release to the environment. Refer to special instructions safety data sheet . | [RIDADR ]
UN 3077 | [WGK Germany ]
3 | [RTECS ]
MF1750000 | [TSCA ]
TSCA listed | [HS Code ]
29252900 | [Storage Class]
11 - Combustible Solids | [Hazard Classifications]
Acute Tox. 4 Oral
Aquatic Acute 1
Aquatic Chronic 1
Eye Irrit. 2
Skin Irrit. 2 | [Hazardous Substances Data]
2439-10-3(Hazardous Substances Data) | [Toxicity]
LC50 in harlequin fish: 0.6 mg/l (Hourdakis) |
| Hazard Information | Back Directory | [General Description]
White crystalline solid. Used as a fungicide. | [Reactivity Profile]
Acidic organic/inorganic salts, such as DODINE(2439-10-3), are generally soluble in water. The resulting solutions contain moderate to high concentrations of hydrogen ions and have pH's of less than 7.0. They react as acids to neutralize bases. These neutralizations generate heat, but less or far less than is generated by neutralization of inorganic acids, inorganic oxoacids, and carboxylic acid. They usually do not react as either oxidizing agents or reducing agents but such behavior is not impossible. Many of these compounds catalyze organic reactions. | [Air & Water Reactions]
Soluble in hot water. | [Chemical Properties]
White Solid | [Uses]
Agricultural fungicide. | [Uses]
Dodine is used to control scab on apples, pears and pecans, leaf
spot diseases of cherries, olives, blackcurrants, celery and other crops, and
foliar diseases of strawberries. It is also used on other fruit, vegetable, nut
and ornamental crops and shade trees. | [Uses]
Used as agricultural fungicide. | [Definition]
ChEBI: An acetate salt resulting from the reaction of equimolar amounts of 1-dodecylguanidine and acetic acid. It is used as a fungicide to control black spot and foliar diseases on apples, pears, peaches, nectarines and strawberries. | [Agricultural Uses]
Fungicide, Microbiocide: Used to control black spot on apples, pears and pecans;
brown rot and foliar diseases on peaches and nectarines,
cherries, strawberries, black walnuts and sycamore
trees. In industry, used as a biocide and preservative. May
also be used to catalyze organic reactions. | [Trade name]
AC 5223®; AMERICAN CYANAMID®
5223; APADODINE®; CARPENE®; CURITAN®;
CYPREX®; CYPREX® 65W; CYTOX® 2160;
DOQUADINE®; EFUZIN®; KARPEN®; MELPREX®;
MELPREX® 65; MILPREX®; QUESTURAN®; Radspor
L; SULGEN®; SYLLIT®; SYLLIT® 65; SYLLIT®
400SC, TEBULAN®; TSITREX®; VANDODINE®;
VENTUROL®; VONDODINE® | [Metabolic pathway]
No information is available on the fate of dodine in soils but in plants it is
converted into creatine by the action of a methyltransferase, and simultaneously
the dodecyl moiety is oxidatively cleaved (PM). | [Degradation]
Dodine is stable in neutral and moderately alkaline or acidic media but
the free base is liberated by concentrated alkali (PM). |
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