ChemicalBook--->CAS DataBase List--->2475-33-4

2475-33-4

2475-33-4 Structure

2475-33-4 Structure
IdentificationMore
[Name]

Vat Brown 1
[CAS]

2475-33-4
[Synonyms]

VAT BROWN 1
16,23-dihydronaphth[2',3':6,7]indolo[2,3-c]dinaphtho[2,3-a:2'3'-i]carbazole-5,10,15,17,22,24-hexone
Vat Brown BR Powder
Naphth2,3:6,7indolo2,3-cdinaphtho2,3-a:2,3-icarbazole-5,10,15,17,22,24-hexone, 16,23-dihydro-
C.I.VATBROWN1
Vat brown 1 (C.I. 70800)
Brown BR
Anthramar Brown BR
Cibanone Brown BR
Dycosthren Brown BR
Mikethrene Brown BR
Nihonthrene Brown BR
Ostanthren Brown BRG
Sandothrene Liquid Brown NBR
Trianthrene Brown BR
Youhaothrene Brown BR.
C.I. 70800
Mayvat Brown BR
16,23-Dihydronaphth[2',3':6,7]indolo[2,3-c]dinaphtho[2,3-a:2',3'-i]carbazole-5,10,15,17,22,24-hexaone
Brown SK
[EINECS(EC#)]

219-599-7
[Molecular Formula]

C42H18N2O6
[MDL Number]

MFCD00071878
[Molecular Weight]

646.602
[MOL File]

2475-33-4.mol
Chemical PropertiesBack Directory
[Boiling point ]

675.58°C (rough estimate)
[density ]

1.2856 (rough estimate)
[refractive index ]

1.4670 (estimate)
[pka]

11.33±0.20(Predicted)
[LogP]

8.52
[CAS DataBase Reference]

2475-33-4(CAS DataBase Reference)
[EPA Substance Registry System]

2475-33-4(EPA Substance)
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Aluminum chloride-->Copper(I) chloride-->Sodium hypochlorite-->1,4-Diamino anthraquinone-->1-Chloro anthraquinone-->1-Chloro anthraquinone-->1-Bromoanthraquinone-->Pyridine
[Preparation Products]

Vat Brown 1, Solubilised
Safety DataBack Directory
[TSCA ]

TSCA listed
[REACH Registrations]

Active
Hazard InformationBack Directory
[General Description]

Fine, dark brown to black crystalline powder with a slight odor.
[Reactivity Profile]

Oxidizing agents and reducing agents may destroy this chemical's color. .
[Air & Water Reactions]

Insoluble in water.
[Health Hazard]

ACUTE/CHRONIC HAZARDS: When heated to decomposition this compound may emit toxic fumes of carbon oxides and nitrogen oxides.
[Fire Hazard]

Flash point data for this chemical are not available; however, VAT BROWN 1(2475-33-4) is probably combustible. Dust clouds may form explosive mixtures with air.
[Uses]

Vat Brown 1 is mainly used for dyeing cotton fibers, exhibiting good leveling properties and moderate affinity. It is also used for dyeing viscose fibers, silk, vinylon, viscose-cotton blends, and vinylon-cotton blends. It can also be used in a co-bath hot-melt dyeing process with disperse dyes to dye polyester-cotton blends, with less staining on polyester. Vat Brown (BR) can also be blended with Vat Gray (BG) to dye coffee brown, and with Vat Gray (BG), Brown (GG), and Khaki (GG) to dye various grays and browns, making it a commonly used brown dye.
[Preparation]

1,4-Diaminoanthraquinone and 1-Bromoanthracene-9,10-dione or 1-Bromoanthracene-9,10-dione (2 Moore) condensation, its product in Pyridine with Aluminium chloride heating.
[Synthesis]

1,1' : 4,1''-Trianthrimide-2,2' : 3,2''- carbazole, (Indanthren Brown BR, is prepared from 1,1' : 4,1''- trianthrimide in AlCl3 – pyridine .
[Properties and Applications]

red light brown. Dark brown powder. Slightly soluble in hot 1, 2, 3, 4 – Tetrahydronaphthalene and thermal Xylene, insoluble in cold Xylene. In concentrated sulfuric acid to Copenhagen green, dilution after brown precipitation. Alkaline reduction leuco for yellow brown; Acid reduction leuco for dark olive. Mainly used for cotton, hemp, silk and viscose dyeing and printing, cotton yarn dyeing common varieties. Used for polyester/cotton blended fabric two bath dyeing of polyester with little color. The leuco used for dyeing cotton knitwear.
Standard Ironing Fastness Chlorine bleach Light Fastness Mercerized Oxygen bleach Soaping
Fading Stain
ISO 5 4-5 7 4-5 4-5 5 5
AATCC 5 5 8 4-5 4-5
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