ChemicalBook--->CAS DataBase List--->25152-84-5

25152-84-5

25152-84-5 Structure

25152-84-5 Structure
IdentificationMore
[Name]

trans,trans-2,4-Decadien-1-al
[CAS]

25152-84-5
[Synonyms]

2,4-DECADIEN-1-AL
2,4-DECADIENAL
2E,4E-DECADIENAL
DDA
DECA-2,4-DIENAL
DECA-2(TRANS),4(TRANS)-DIENAL
DECADIENEALDEHYDE
(E,E)-2,4-DECADIENAL
FEMA 3135
T2 T4 DECADIENAL
TRANS-2,4 DECADIEN-1-AL
TRANS-2, TRANS-4-DECADIENAL
TRANS,TRANS-2,4-DECADIENAL
(2E,4E)-2,4-Decadienal
(E)-2,(E)-4-decadienal
(E,E)-2,4-Decanedienal
(e,e)-4-decadienal
(E,E)-deca-2,4-dienal
2,4-trans,trans-Decadienal
2-trans-4-trans-Decadienal
[EINECS(EC#)]

246-668-9
[Molecular Formula]

C10H16O
[MDL Number]

MFCD00007007
[Molecular Weight]

152.23
[MOL File]

25152-84-5.mol
Chemical PropertiesBack Directory
[Appearance]

clear yellow liquid
[Boiling point ]

114-116 °C/10 mmHg (lit.)
[density ]

0.872 g/mL at 20 °C(lit.)
[vapor density ]

>1 (vs air)
[FEMA ]

3135
[refractive index ]

n20/D 1.515(lit.)
[Fp ]

214 °F
[storage temp. ]

Refrigerator (+4°C)
[solubility ]

DMF: 10 mg/ml; DMSO: 10 mg/ml; Ethanol: 10 mg/ml; Ethanol:PBS (pH 7.2) (1:2): .15 mg/ml
[form ]

Liquid
[color ]

Clear yellow
[Odor]

at 1.00 % in dipropylene glycol. oily cucumber melon citrus pumpkin nut meat
[biological source]

synthetic
[Odor Type]

fatty
[Water Solubility ]

insoluble
[Sensitive ]

Air Sensitive
[JECFA Number]

1190
[BRN ]

1704897
[Stability:]

Light Sensitive
[Major Application]

cleaning products
cosmetics
flavors and fragrances
food and beverages
personal care
[Cosmetics Ingredients Functions]

PERFUMING
[InChI]

1S/C10H16O/c1-2-3-4-5-6-7-8-9-10-11/h6-10H,2-5H2,1H3/b7-6+,9-8+
[InChIKey]

JZQKTMZYLHNFPL-BLHCBFLLSA-N
[SMILES]

[H]C(=O)\C=C\C=C\CCCCC
[LogP]

3.18
[CAS DataBase Reference]

25152-84-5(CAS DataBase Reference)
[NIST Chemistry Reference]

2,4-Decadienal, (E,E)-(25152-84-5)
[EPA Substance Registry System]

25152-84-5(EPA Substance)
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H315-H319
[Precautionary statements ]

P264-P280-P302+P352-P305+P351+P338-P332+P313-P337+P313
[Hazard Codes ]

Xi
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
R36/38:Irritating to eyes and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
S37/39:Wear suitable gloves and eye/face protection .
[WGK Germany ]

2
[RTECS ]

HD3000000
[F ]

10-23
[TSCA ]

Yes
[PackingGroup ]

III
[HS Code ]

29121900
[Storage Class]

10 - Combustible liquids
[Hazard Classifications]

Eye Irrit. 2
Skin Irrit. 2
[Safety Profile]

Combustible liquid. When heated to decomposition it emits acrid smoke and irritating fumes.
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Hydrogen peroxide-->METHYL LINOLEATE-->decadienal,(E,Z)-2,4-decadienal-->2,4-Pentadienal, 5-bromo-, (2E,4Z)--->(2E,4Z)-2,4-Decadien-1-ol-->Arachidonic acid
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

trans,trans-2,4-Decadien-1-al(25152-84-5).msds
Hazard InformationBack Directory
[Chemical Properties]

2-trans, 4-trans-Decadienal has a powerful, oily, chicken fat odor and a sweet, orange-like odor at high concentration. It has a grapefruit- or orange-like taste on dilution.
[Physical properties]

Yellow liquid with a strong smell of chicken and chicken fat. The boiling point is 104°C [933Pa (7mmHg)]. The flash point is above 100°C. The liquid is soluble in ethanol and most non-volatile oils, but it is insoluble in water. It is naturally present in orange peel, bitter orange, lemon, strawberry, and roast chicken, among other natural products.
[Occurrence]

Reported as occurring in peanut oil and, as a volatile component, in fried potatoes, the trans, trans- form is reported found among the volatile flavor components of potato chips and tomato. Also found in citrus peel oils, orange juice, tangerine juice, guava fruit, strawberry fruit, cabbage, carrot, raw potato, bell pepper, butter, cooked chicken, beer, rum, tea, peanut oil, popcorn, potato chips, corn tortilla, oatmeal, Brazil nut, roasted almonds, roasted peanuts and pecans, soybeans, cassava, caviar, cooked beef, lamb, mutton, and fish.
[Uses]

trans,trans-2,4-Decadienal is an aldehyde with a fat flavor aroma characteristic of chicken but has a citrus odor at lower concentrations. trans,trans-2,4-Decadienal can be found in butter, cooked bee f, fish, potato chips, roasted peanut, buckwheat and wheat bread crumb.
[Definition]

ChEBI: (2E,4E)-deca-2,4-dienal is a polyunsaturated fatty aldehyde that is decanal which has undergone formal dehydrogenation to introduce trans- double bonds at the 2-3 and 4-5 positions. A product of lipid peroxidation in cell membranes and a component of cooking oil fumes. It has a role as a nematicide and an apoptosis inducer.
[Preparation]

By autooxidation of methyl (trans, trans)-linolate hydroperoxide.
[Aroma threshold values]

Detection: 0.07 to 10 ppb. Aroma characteristics at 0.1%, rich fatty, aldehydic, green melon, chicken fat, oily and creamy with chicken stock and chicken meat nuances.
[Taste threshold values]

Taste characteristics at 2 ppm: rich oily fatty, aldehydic, green, chicken meat with tropical fruit and cilantro nuances
[Synthesis Reference(s)]

Tetrahedron Letters, 36, p. 4223, 1995 DOI: 10.1016/0040-4039(95)00704-G
[General Description]

trans,trans-2,4-Decadienal reacts with cytochrome c to form an adduct.
[storage]

Store at -20°C
Spectrum DetailBack Directory
[Spectrum Detail]

trans,trans-2,4-Decadien-1-al(25152-84-5)MS
trans,trans-2,4-Decadien-1-al(25152-84-5)1HNMR
trans,trans-2,4-Decadien-1-al(25152-84-5)IR1
trans,trans-2,4-Decadien-1-al(25152-84-5)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

trans,trans-2,4-Decadienal, tech., 95%(25152-84-5)
[Alfa Aesar]

trans,trans-2,4-Decadienal, 90+%, remainder mainly trans,cis isomer(25152-84-5)
[Sigma Aldrich]

25152-84-5(sigmaaldrich)
[TCI AMERICA]

trans,trans-2,4-Decadienal,>90.0%(GC)(25152-84-5)
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