ChemicalBook--->CAS DataBase List--->25470-96-6

25470-96-6

25470-96-6 Structure

25470-96-6 Structure
IdentificationBack Directory
[Name]

Rhodium (triphenylphosphine)carbonylacetylacetonate
[CAS]

25470-96-6
[Synonyms]

ROPAC
Acetylacetonatocarbo
rhodium (triphenylphosphine)carbonylacetylacetonate
ACETYLACETONATOCARBONYLTRIPHENYLPHOSPHINERHODIUM (L)
Acetylacetonato-carbonyl-triphenylphosphine-rhodium(Ⅰ)
Carbonyl(2,4-pentanedionato)(triphenylphosphine)rhodium
(ACETYLACETONATO)CARBONYL(TRIPHENYLPHOSPHINE)RHODIUM(I)
CARBONYL-2,4-PENTANEDIONATO-(TRIPHENYLPHOSPHINE)RHODIUM(I)
Carbonyl(acetylacetonato)(triphenylphosphine)rhodium(I), 99%
Carbonyl(pentane-2,4-dionato-O,O')(triphenylphosphine)rhodium
Carbonyl-2,4-pentanedionato-(triphenylphosphine)rhodium(I),Rh21%
Carbonyl-2,4-pentanedionato(triphenylphosphine)rhodium(I), Rh 21%
4-pentanedionato-o,o’)(triphenylphosphine)-carbonyl((sp-4-2)-rhodiu
carbon monoxide,(Z)-4-oxopent-2-en-2-olate,rhodium,triphenylphosphane
Acetylacetonatocarbonyltriphenylphosphinerhodium(I) ROPAC Major commercial hydroformylation catalyst
[EINECS(EC#)]

247-015-0
[Molecular Formula]

C24H22O3PRh
[MDL Number]

MFCD00064611
[MOL File]

25470-96-6.mol
[Molecular Weight]

492.31
Chemical PropertiesBack Directory
[Appearance]

Yellow Powder
[Melting point ]

200-204°C
[density ]

1.5[at 20℃]
[vapor pressure ]

0Pa at 25℃
[solubility ]

Soluble in acetone and chlorinated solvents
[form ]

solid
[color ]

yellow
[Water Solubility ]

24μg/L at 20℃
[Merck ]

14,356
[Exposure limits]

ACGIH: TWA 0.01 mg/m3; TWA 1 mg/m3
NIOSH: IDLH 2 mg/m3; IDLH 100 mg/m3; TWA 0.001 mg/m3; TWA 0.1 mg/m3
[InChI]

InChI=1S/C18H15P.C5H7O2.CO.Rh/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-4(6)3-5(2)7;1-2;/h1-15H;3H,1-2H3;;/q;-1;;/p+1
[InChIKey]

ZETXURAVPSJSPU-UHFFFAOYSA-O
[SMILES]

P(C1C=CC=CC=1)(C1C=CC=CC=1)(C1C=CC=CC=1)[Rh+]1(O=C(C)[CH-]C(C)=O1)C#O
[EPA Substance Registry System]

Rhodium, carbonyl(2,4-pentanedionato-. kappa.O,.kappa.O')(triphenylphosphine)-, (SP-4-2)-(25470-96-6)
Hazard InformationBack Directory
[Chemical Properties]

Yellow Powder
[Uses]

Hydroformylation
[Flammability and Explosibility]

Notclassified
Safety DataBack Directory
[Hazard Codes ]

Xi
[WGK Germany ]

WGK 3
[TSCA ]

Yes
[HS Code ]

28439000
[Storage Class]

11 - Combustible Solids
Questions And AnswerBack Directory
[Reaction]

Rhodium catalyzed addition of fluorinated acid chlorides to alkynes Reactions of 25470-96-6
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