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3153-26-2

3153-26-2 Structure

3153-26-2 Structure
IdentificationMore
[Name]

Vanadyl acetylacetonate
[CAS]

3153-26-2
[Synonyms]

ACETYLACETONE VANADIUM(IV)OXY SALT
ACETYLACETONE, VANADYL DERIVATIVE
BIS(2,4-PENTANEDIONATO)VANADIUM(4) OXIDE
BIS(2,4-PENTANEDIONATO)VANADIUM(IV) OXIDE
BIS(ACETYLACETONATO)VANADIUM(IV) OXIDE
VANADIUM(IV)-BIS(2,4-PENTANEDIONATO)OXIDE
VANADIUM(IV)BIS(ACETYLACETONATO)OXIDE
VANADIUM(IV) OXIDE ACETYLACETONATE
VANADIUM(IV) OXIDE BIS(2,4-PENTANEDIONATE)
VANADIUM(IV)OXY ACETYLACETONATE
VANADIUM(IV)-OXY ACETYLACETONATE BOUND TO POLYANILINE
VANADIUMOXY ACETYLACETONATE
VANADYL 2,4-PENTANEDIONATE
VANADYL ACETYLACETONATE
VANADYL ACETYLACETONATE BOUND TO POLYANILINE
VANADYL ACETYLACETONE
VANADYL(IV)-ACETYLACETONATE
VANADYL PENTANEDIONATE
4-pentanedionato-o,o’)-oxobis((sp-5-21)-vanadiu
Bis(acetylacetonato)oxovanadium
[EINECS(EC#)]

221-590-8
[Molecular Formula]

C10H14O5V
[MDL Number]

MFCD00000032
[Molecular Weight]

265.16
[MOL File]

3153-26-2.mol
Chemical PropertiesBack Directory
[Appearance]

powder
[Melting point ]

235 °C (dec.)(lit.)
[mp ]

235 °C (dec.)(lit.)
[Boiling point ]

140°C 13mm
[bp ]

140°C 13mm
[density ]

1,4 g/cm3
[Fp ]

79 °C
[storage temp. ]

Store below +30°C.
[solubility ]

Moderately soluble in acetone, ether and chloroform. Soluble in ethanol and benzene
[form ]

Crystalline Powder
[color ]

Green to blue-green
[Specific Gravity]

1.4
[Stability:]

Stable, but air sensitive. May discolour upon exposure to air. Incompatible with strong oxidizing agents.
[Water Solubility ]

practically insoluble
[Hydrolytic Sensitivity]

4: no reaction with water under neutral conditions
[Detection Methods]

HPLC,SPECTRA CHEMICAL ANALYSIS,IR
[BRN ]

4138236
[InChIKey]

JFHJZWAQYMGNBE-SUKNRPLKSA-L
[CAS DataBase Reference]

3153-26-2(CAS DataBase Reference)
[Storage Precautions]

Air sensitive
[NIST Chemistry Reference]

Bis(2,4-pentanedionato)oxovanadium(iv)(3153-26-2)
[EPA Substance Registry System]

3153-26-2(EPA Substance)
Safety DataBack Directory
[Hazard Codes ]

Xn
[Risk Statements ]

R22:Harmful if swallowed.
R36/37/38:Irritating to eyes, respiratory system and skin .
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed .
[Safety Statements ]

S22:Do not breathe dust .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
[RIDADR ]

3285
[WGK Germany ]

3
[TSCA ]

Yes
[HazardClass ]

6.1
[PackingGroup ]

III
[HS Code ]

29420000
Raw materials And Preparation ProductsBack Directory
【Raw materials】

Ethanol-->Sulfuric acid-->Dichloromethane-->Sodium carbonate-->Chloroform-->Acetone-->Sodium sulfite-->Activated carbon-->Acetylacetone-->Vanadium(V) oxide-->1-Chlorobutane-->[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)-->Oxalic acid dihydrate-->Vanadium
【Preparation Products】

(R)-(+)-2-Methyl-2-propanesulfinamide-->2-Oxetanone
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

Vanadium(IV)-oxy acetylacetonate(3153-26-2).msds
Questions And AnswerBack Directory
[Reaction]

Catalyst for the hydroxyl-directed epoxidation of olefins.
Catalyst for the asymmetric oxidation of disulfides.
Catalyst for the Mannich reaction.
Catalyst for sulfoxidation of alkanes.
Hazard InformationBack Directory
[Chemical Properties]

powder
[Purification Methods]

It crystallises from acetone. [cf Fernelius & Bryant Inorg Synth V 105 1957, Beilstein 1 IV 3672.]
Spectrum DetailBack Directory
[Spectrum Detail]

Vanadyl acetylacetonate(3153-26-2) IR1
Vanadyl acetylacetonate(3153-26-2) MS
Vanadyl acetylacetonate(3153-26-2) IR2
Well-known Reagent Company Product InformationBack Directory
[Alfa Aesar]

Vanadium(IV) oxide bis(2,4-pentanedionate), 99%(3153-26-2)
[TCI AMERICA]

Bis(2,4-pentanedionato)vanadium(IV) Oxide,>95.0%(T)(3153-26-2)
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