ChemicalBook--->CAS DataBase List--->2602-46-2

2602-46-2

2602-46-2 Structure

2602-46-2 Structure
IdentificationBack Directory
[Name]

CI NO 22610
[CAS]

2602-46-2
[Synonyms]

blue2b
CI 22610
CI 262610
nci-c54579
modrprima6
blue2bsalt
DIRECT BLU
benzobluegs
phenoblue2b
directbluea
directbluek
DIRECT BLUE
CI NO 22610
indigoblue2b
kayakudirect
directbluebb
directbluegs
diazolblue2b
nipponbluebb
DIAMINE BLUE
BENZO BLUE 2B
diazineblue2b
diamineblue2b
diaminebluebb
directbluem2b
fenaminblue2b
fixanolblue2b
cidirectblue6
amanilblue2bx
azocardblue2b
azomineblue2b
NIPPON BLUE B
DIRECT BLUE 6
DIRECT BLUE 2B
belamineblue2b
bencidalblue2b
benzanilblue2b
atlanticblue2b
hispaminblue2b
enianilblue2bn
diphenylbluekf
vondacelblue2b
paramineblue2b
phenaminebluebb
Pyra-zolBlue2BX
diphenylbluem2b
benzobluebba-cf
benzobluebbn-cf
cresotineblue2b
diacottonbluebb
chlorazolbluebp
C.I.Directblue6
airedaleblue2bd
NIAGARA BLUE 2B
iredale Blue 2BD
chloramineblue2b
atuldirectblue2b
naphtamineblue2b
CHLORAZOL BLUE B
DIPHENYL BLUE 2B
CALCOMINE BLUE 2B
diaphtaminebluebb
brasilaminablue2b
PONTAMINE BLUE BB
aizendirectblue2bh
kayakudirectbluebb
tertrodirectblue2b
Direct Blue 2B H/C
mitsuidirectblue2bn
chromeleatherblue2b
abcoldirectblue2b(s)
directblue6(technical
Direct blue 6 (C.I. 22610)
BENZO BLUE 2B C.I.NO.22610
C.I.Direct Blue 6:C.I.22610
directblue6(technicalgrade)
Benzo Blue 2B Nippon Blue B
ESSEX DIRECT BLUE 2 B CONC.
c.i.directblue6,tetrasodiumsalt
Direct Blue 6@100 μg/mL in MeOH
Direct Blue 2B (C.I. Direct Blue 6)
sodiumdiphenyl-4,4’-bis-azo-2"-8"-amino-1"-naphthol-3",6"-disulphonate
3,3’-((4,4’-biphenylylene)bis(azo))bis(5-amino-7-naphthalenedisulfonicacid
2,7-naphthalenedisulfonicacid,3,3’-((1,1’-biphenyl)-4,4’-diylbis(azo))bis(5-a
2,7-naphthalenedisulfonicacid,3,3’-[[1,1’-biphenyl]-4,4’-diylbis(azo)]bis[5-a
2,7-naphthalenedisulfonicacid,3,3’-[[1,1’-biphenyl]-4,4’-diylbis(azo)]bis[5-amino-
etrasodium5,5'-(1,1'-biphenyl-4,4'-diylbisazo)-bis-7-amino-6-hydroxy-naphthalene-1,4-disulphonate
tetrasodium 5,5'-(1,1'-biphenyl-4,4'-diylbisazo)-bis-7-amino-6-hydroxy-naphthalene-1,4-disulphonate
tetrasodium 3,3'-[[1,1'-biphenyl]-4,4'-diylbis(azo)]bis[5-amino-4-hydroxynaphthalene-2,7-disulphonate]
sodiuM 3,3'-(1E,1'E)-biphenyl-4,4'-diylbis(diazene-2,1-diyl)bis(5-aMino-4-hydroxynaphthalene-2,7-disulfonate)
2,7-Naphthalenedisulfonic acid,3,3'-[[1,1'-biphenyl]-4,4'-diylbis(azo)]bis[5-amino-4-hydroxy-,tetrasodium salt
tetrasodium 3,3'-[[1,1'-biphenyl]-4,4'-diylbis(azo)]bis[5-amino-4-hydroxynaphthalene-2,7-disulphonate] C.I. Direct Blue 6
[EINECS(EC#)]

220-012-1
[Molecular Formula]

C32H20N6Na4O14S4
[MDL Number]

MFCD00068426
[MOL File]

2602-46-2.mol
[Molecular Weight]

932.75
Chemical PropertiesBack Directory
[storage temp. ]

Refrigerator
[solubility ]

Methanol (Slightly), Water (Slightly)
[Colour Index ]

22610
[form ]

Solid
[color ]

Very Dark Blue to Black
[EPA Substance Registry System]

C.I. Direct Blue 6 (2602-46-2)
Safety DataBack Directory
[Hazard Codes ]

T
[Risk Statements ]

20/21/22-63-45
[Safety Statements ]

22-24/25-45-53
[RTECS ]

QJ6400000
[HS Code ]

3204.14.5000
[Safety Profile]

Confirmed carcinogen with experimental carcinogenic, neoplastigenic, and tumorigenic data. Experimental teratogenic and reproductive effects. Mutation data reported. When heated to decomposition it emits very toxic fumes of NOx Na2O, and SOx
[Hazardous Substances Data]

2602-46-2(Hazardous Substances Data)
[Toxicity]

rabbit,LDLo,oral,4gm/kg (4000mg/kg),Office of Toxic Substances Report. Vol. OTS,
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Benzidine-->Benzidine-->8-Amino-1-naphthol-3,6-disulfonic acid monosodium salt monohydrate
Hazard InformationBack Directory
[General Description]

Dark blue microcrystals or black powder.
[Air & Water Reactions]

Azo dyes can be explosive when suspended in air at certain concentrations. Slightly water soluble.
[Reactivity Profile]

CI NO 22610 is an azo compound. Azo, diazo, azido compounds can detonate. This applies in particular to organic azides that have been sensitized by the addition of metal salts or strong acids. Toxic gases are formed by mixing materials of this class with acids, aldehydes, amides, carbamates, cyanides, inorganic fluorides, halogenated organics, isocyanates, ketones, metals, nitrides, peroxides, phenols, epoxides, acyl halides, and strong oxidizing or reducing agents. Flammable gases are formed by mixing materials in this group with alkali metals. Explosive combination can occur with strong oxidizing agents, metal salts, peroxides, and sulfides. CI NO 22610 is incompatible with strong oxidizing agents and strong acids .
[Health Hazard]

ACUTE/CHRONIC HAZARDS: CI NO 22610 is absorbed through the skin. When heated to decomposition it emits very toxic fumes of nitrogen oxides, sodium oxides and sulfur oxides.
[Fire Hazard]

Flash point data for CI NO 22610 are not available; however, CI NO 22610 is probably combustible.
[Description]

Direct blue 6 is a benzidine-based dyestuffsomewhat analogous to Direct black 38 (which see). It is adark blue powder. Molecular weight= 932.78; Freezing/Melting point $ 400℃. Hazard Identification (based onNFPA-704 M Rating System): Health 1, Flammability 1,Reactivity 0.
[Uses]

Direct Blue 6 is a deep blue azo dye used in textiles however contributes to environmental pollution and potentially reproductive toxicity.Environmental toxin on US EPA Toxic Release Inventory list (TRI) list.
[Potential Exposure]

Mutagen; Human Data. Direct Blue 6may be used by artists. It is potentially used to dye fabric,leather, cotton, cellulosic materials, and paper; these arethen used in consumer products (CPSC, EPA). The FDAhas indicated that although Direct Blue 6 has been identified in the literature as a hair dye component, it is not presently used by the cosmetic industry. The primary source forexposure to Direct Blue 6 is at the production site. The initial production step is in a closed system. However, otherproduction operations, such as filter press, drying, andblending, may be performed in the open and, therefore, mayafford a greater potential for worker exposure. The generalpopulation may be exposed to Direct Blue 6 through the useof retail packaged dyes containing this benzidine-based dye.
[First aid]

If this chemical gets into the eyes, remove anycontact lenses at once and irrigate immediately for at least15 min, occasionally lifting upper and lower lids. Seekmedical attention immediately. If this chemical contactsthe skin, remove contaminated clothing and wash immediately with soap and water. Seek medical attention immediately. If this chemical has been inhaled, remove fromexposure, begin rescue breathing (using universal precautions, including resuscitation mask) if breathing hasstopped and CPR if heart action has stopped. Transferpromptly to a medical facility. When this chemical hasbeen swallowed, get medical attention. Give large quantities of water and induce vomiting. Do not make an unconscious person vomit
[storage]

Color Code—Blue: Health Hazard/Poison: Storein a secure poison location. Prior to working with directblue 6 you should be trained on its proper handling andstorage. Store in tightly closed containers in a cool, wellventilated area. A regulated, marked area should be established where this chemical is handled, used, or stored incompliance with OSHA Standard 1910.1045.
[Shipping]

Dyes, solid, toxic, n.o.s. require a label of“POISONOUS/TOXIC MATERIALS.” They fall in HazardClass 6.1.
[Properties and Applications]

Standard

Acid Resistance

Alkali Resistance

Light Fastness

Soaping

Water

Fading

Stain

Fading

Stain

ISO

4-5

3

1-2

1-2

1

AATCC

5

2

1

1-2

1

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