ChemicalBook--->CAS DataBase List--->2695-37-6

2695-37-6

2695-37-6 Structure

2695-37-6 Structure
IdentificationMore
[Name]

Sodium p-styrenesulfonate
[CAS]

2695-37-6
[Synonyms]

4-STYRENESULFONIC ACID, SODIUM SALT HYDRATE
4-VINYLBENZENESULFONIC ACID SODIUM SALT HYDRATE
P-STYRENESULFONIC ACID SODIUM SALT HYDRATE
SODIUM P-STYRENESULFONATE HYDRATE
4-ethenyl-benzenesulfonicacisodiumsalt
Benzenesulfonicacid,4-ethenyl-,sodiumsalt
4-Vinylbenzenesulphonic acid sodium salt hydrate
Sodium p-vinylbenzenesulphonate~Styrene-4-sulphonic acid sodium salt
Styrene Sulfonic Acid Sodium
4-Vinylbenzenesulfonic Acid Sodium
P-STYRENESULFONIC ACID NA SALT
sodium p-vinylbenzenesulfonate
4-VINLBENZENESULFONIC ACID SODIUM
SODIUMPARA-VINYLBENZENESULPHONATE
4-ethenyl-benzenesulfonic acid sodium salt
4-VINYLBENZENESULFONIC ACID SODIUM SALT HYDRATE: TECH., 90%
4-STYRENESULFONIC ACID
p-Vinylbenzenesulphonic acid sodium salt
Sodium 4-vinylbenzenesulphonate
Sodium p-styrenesulfonate
[EINECS(EC#)]

220-266-3
[Molecular Formula]

C8H7NaO3S
[MDL Number]

MFCD03092905
[Molecular Weight]

206.19
[MOL File]

2695-37-6.mol
Chemical PropertiesBack Directory
[Appearance]

white to light beige powder
[Melting point ]

151-154 °C
[Boiling point ]

111-112 °C
[density ]

1.043 g/mL at 25 °C
[vapor pressure ]

0Pa at 25℃
[refractive index ]

n20/D 1.387
[Fp ]

78 °F
[storage temp. ]

Keep in dark place,Sealed in dry,Room Temperature
[form ]

Powder
[color ]

White
[Stability:]

Stable. Incompatible with strong oxidizing agents.
[Water Solubility ]

Soluble in water.
[Hydrolytic Sensitivity]

0: forms stable aqueous solutions
[BRN ]

3575931
[InChI]

1S/C8H8O3S.Na/c1-2-7-3-5-8(6-4-7)12(9,10)11;/h2-6H,1H2,(H,9,10,11);/q;+1/p-1
[InChIKey]

XFTALRAZSCGSKN-UHFFFAOYSA-M
[SMILES]

[Na+].[O-]S(=O)(=O)c1ccc(C=C)cc1
[LogP]

-3.44 at 24℃
[CAS DataBase Reference]

2695-37-6(CAS DataBase Reference)
[EPA Substance Registry System]

2695-37-6(EPA Substance)
Safety DataBack Directory
[Symbol(GHS) ]

Flame (GHS02)Corrosion (GHS05)Exclamation Mark (GHS07)
GHS02,GHS05,GHS07
[Signal word ]

Danger
[Hazard statements ]

H226-H315-H318-H335-H336
[Precautionary statements ]

P210-P280-P305+P351+P338+P310-P370+P378
[Hazard Codes ]

Xn,Xi
[Risk Statements ]

R22:Harmful if swallowed.
R36/37/38:Irritating to eyes, respiratory system and skin .
R41:Risk of serious damage to eyes.
R37/38:Irritating to respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37:Wear suitable protective clothing and gloves .
S36:Wear suitable protective clothing .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
[RIDADR ]

UN 1987 3/PG 3
[WGK Germany ]

3
[F ]

8-23
[TSCA ]

Yes
[REACH Registrations]

Active
[HS Code ]

29049090
[Storage Class]

11 - Combustible Solids
[Hazard Classifications]

Acute Tox. 4 Oral
Eye Dam. 1
Skin Irrit. 2
STOT SE 3
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Ethanol-->Bromine-->4-(2-Bromoethyl)benzenesulfonic acid
[Preparation Products]

Sodium 4-formylbenzenesulfonate-->Benzenesulfonic acid, 4-ethenyl--->Lithium-p-styrenesulfonate
Questions And AnswerBack Directory
[Chemical Reactivity]

Sodium p-styrenesulfonate (NaSS) is a functional monomer having a radical polymerizable vinyl group, a hydrophobic benzene ring having π electrons, and a sulfonic acid (salt) group that is a strong electrolyte and has been valued in various industrial fields.
With the inductive effect of sulfo radical on the para position against vinyl group, sodium p-styrenesulfonate (NaSS) possesses the highest reactivity (polymerization activity) among all sulfonated vinyl monomers. It performs radical polymerization in such polar solvents as DMF, DMSO and water using common or redox polymerization initiators. For example, it has been used as a reactive emulsifier in order to improve stability of an emulsion and water resistance or cationic dye dyeability of a (emulsion) polymer.
[Application]

Sodium p-styrenesulfonate has been used as a reactive emulsifier in order to improve stability of an emulsion and water resistance or cationic dye dyeability of a (emulsion) polymer. Further, a polymer or a copolymer of sodium p-styrenesulfonate has been used as a dispersant for producing various aqueous dispersions of pigments, antioxidants, various polymers (tackifier resins, chloroprene rubber, polyacrylic acid esters, polyesters, styrene-butadiene copolymers, polyvinyl chloride, poly-acrylonitrile, polysilicones, conductive polymers and the like), nanocarbon materials, silica particles for hot forging release agents or abrasives, battery electrode materials (carbon, lithium iron phosphate, lithium manganese phosphate and the like), photographic silver halides and the like.
Furthermore, the polymer of sodium p-styrenesulfonate has been utilized as synthetic starch for clothing finishing such as an ironing agent, a hair care product, an antistatic agent, a resist acid generator, a water treatment agent, an allergen scavenger, an ion-exchange resin, a plating solution additive, a detergent for production of semiconductors and hard disks, an additive to fluids for shale oil drilling and a flame retardant for resins.
Hazard InformationBack Directory
[Chemical Properties]

white to light beige powder
[Uses]

Styrene-4-sulfonic acid sodium salt is grafted on poly(ethersulfone) membrane to determine the fractionation of proteins with similar molecular weights. It is used as sodium based ion exchange membranes for membrane capacitive deionization (MCDI) for synthesis. It is used in the study of copolymerization characteristics of sodium styrenesulfonate.
[Flammability and Explosibility]

Nonflammable
Spectrum DetailBack Directory
[Spectrum Detail]

Sodium p-styrenesulfonate(2695-37-6)1HNMR
Sodium p-styrenesulfonate(2695-37-6)IR1
Well-known Reagent Company Product InformationBack Directory
[Alfa Aesar]

4-Vinylbenzenesulfonic acid sodium salt hydrate, tech. 90%(2695-37-6)
[Sigma Aldrich]

2695-37-6(sigmaaldrich)
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