| Identification | More | [Name]
(4-NITROBENZYL)TRIPHENYLPHOSPHONIUM BROMIDE | [CAS]
2767-70-6 | [Synonyms]
(4-NITROBENZYL)TRIPHENYLPHOSPHONIUM BROMIDE
(P-NITROBENZYL)TRIPHENYLPHOSPHONIUM BROMIDE
TRIPHENYL(4-NITROBENZYL)PHOSPHONIUM BROMIDE
(p-nitrobenzyl)triphenyl-phosphoniubromide | [EINECS(EC#)]
220-444-0 | [Molecular Formula]
C25H21BrNO2P | [MDL Number]
MFCD00032108 | [Molecular Weight]
478.32 | [MOL File]
2767-70-6.mol |
| Chemical Properties | Back Directory | [Appearance]
white to light yellow powder | [Melting point ]
275 °C (dec.)(lit.) | [storage temp. ]
Inert atmosphere,Room Temperature | [solubility ]
soluble in Methanol | [form ]
solid | [pka]
20.1(Solvent: 1-Butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide) | [color ]
White to Almost white | [InChI]
1S/C25H21NO2P.BrH/c27-26(28)22-18-16-21(17-19-22)20-29(23-10-4-1-5-11-23,24-12-6-2-7-13-24)25-14-8-3-9-15-25;/h1-19H,20H2;1H/q+1;/p-1 | [InChIKey]
IPJPTPFIJLFWLP-UHFFFAOYSA-M | [SMILES]
[Br-].[O-][N+](=O)c1ccc(C[P+](c2ccccc2)(c3ccccc3)c4ccccc4)cc1 | [CAS DataBase Reference]
2767-70-6(CAS DataBase Reference) |
| Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing . | [WGK Germany ]
3
| [RTECS ]
TA2390000
| [HS Code ]
29319000 | [Storage Class]
11 - Combustible Solids | [Hazard Classifications]
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3 | [Toxicity]
mouse,LD50,intravenous,18mg/kg (18mg/kg),U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. Vol. NX#00884, |
| Hazard Information | Back Directory | [Chemical Properties]
white to light yellow powder | [Uses]
(4-Nitrobenzyl)triphenylphosphonium Bromide acts as a reagent in the preparation of substituted benzyl triphenyl phosphonium halides as antibacterial agents by quaternization of triphenylphosphine with benzyl halides. | [Uses]
Reactant for the synthesis of:
- PPAR agonists derived from LXR antagonists
- Stilbene derivatives for use in detection of nerve agents and for attaching to polymers to elicit fluorescent behavior
- Distyrylfurans
- Pyrethoids with insecticidal activity
- Pyridinylidene amines with antimalarial activity
| [reaction suitability]
reaction type: C-C Bond Formation |
|
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