| Identification | Back Directory | [Name]
TRANS-DICHLOROBIS(TRIETHYLPHOSPHINE)PALLADIUM(II) | [CAS]
28425-04-9 | [Synonyms]
Dichlorobis(triethylphosphine)palladium
Bis(triethylphosphine)palladium dichloride
DICHLOROBIS(TRIETHYLPHOSPHINE)PALLADIUM(II)
Bis(triethylphosphine)palladium(II) chloride
Dichlorobis(triethylphosphine)palladiuM(II),97%
TRANS-DICHLOROBIS(TRIETHYLPHOSPHINE)PALLADIUM(II) | [Molecular Formula]
C12H30Cl2P2Pd | [MDL Number]
MFCD00191831 | [MOL File]
28425-04-9.mol | [Molecular Weight]
413.64 |
| Chemical Properties | Back Directory | [Appearance]
Yellow powder | [Melting point ]
139-142 °C(lit.)
| [storage temp. ]
Inert atmosphere,2-8°C | [solubility ]
Soluble in chloroform, toluene and benzene | [form ]
Powder | [color ]
Yellow | [Sensitive ]
Hygroscopic | [InChI]
1S/2C6H15P.2ClH.Pd/c2*1-4-7(5-2)6-3;;;/h2*4-6H2,1-3H3;2*1H;/q;;;;+2/p-2 | [InChIKey]
ULYNIEUXPCUIEL-UHFFFAOYSA-L | [SMILES]
Cl[Pd]Cl.CCP(CC)CC.CCP(CC)CC |
| Hazard Information | Back Directory | [Chemical Properties]
Yellow powder | [Uses]
trans-Dichlorobis(triethylphosphine)palladium(II) is used in coupling of C-C bonds. It is also used as pharmaceutical and organic Intermediates. | [reaction suitability]
core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst | [Synthesis]
Weigh PdCl2, dissolved in 1:1 hydrochloric acid, weigh triethylphosphine, dissolved in 200 mL of anhydrous ethanol, add PdCl2 solution under stirring, heated to boiling, reflux reaction for 4 h, to get a yellow precipitate, filtered while hot, washed with |
| Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
36/37/38 | [Safety Statements ]
26-36 | [RIDADR ]
UN3464 | [WGK Germany ]
3
| [HazardClass ]
6.1 | [PackingGroup ]
III | [HS Code ]
28439090 | [Storage Class]
11 - Combustible Solids | [Hazard Classifications]
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3 |
|
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