| Identification | More | [Name]
Bis(acetonitrile)dichloropalladium(II) | [CAS]
14592-56-4 | [Synonyms]
BIS(ACETONITRILE)DICHLOROPALLADATE (II)
BIS(ACETONITRILE)DICHLOROPALLADIUM(II)
BIS(ACETONITRILE)PALLADIUM(II) CHLORIDE
BIS(ACETONITRILE)PALLADIUM(II) DICHLORIDE
DICHLOROBIS(ACETONITRILE)PALLADIUM(II)
DICHLOROBIS(ACETONITRILE)PALLADIUM(III)
PALLADIUM-BIS-ACETONITRIL-DICHLORIDE
PALLADIUM DICHLOROBIS(ACETONITRILE)
PALLADIUM(II) CHLORIDE-DIACETONITRILE COMPLEX
TRANS-BIS(ACETONITRILE)PALLADIUM(II) CHLORIDE
TRANS-DICHLOROBIS(ACETONITRILE)PALLADIUM
bis(acetonitrile)dichloropalladium
bis (acetontrile) dichloropalladium (II)
BIS(ACETONITRILE)DICHLOROPALLADIUM(II), 99.99%
BIS(ACETONITRILE)DICHLOROPALLADIUM(II),99%
TRANS-BIS(ACETONITRILE) DICHLOROPALLADIUM(II)
BIS-(ACETONITRIL)DICHLOROPALLADIUM(II)
Dichlorobis(acetonitrile)palladium(II),99%
Palladium, bis(acetonitrile)dichloro-
Palladium(II)chloro-bis(acetonitrile) | [EINECS(EC#)]
238-637-3 | [Molecular Formula]
C4H6Cl2N2Pd | [MDL Number]
MFCD00013122 | [Molecular Weight]
259.43 | [MOL File]
14592-56-4.mol |
| Chemical Properties | Back Directory | [Appearance]
dark yellow powder | [Melting point ]
300 °C
| [storage temp. ]
Inert atmosphere,Room Temperature | [solubility ]
Soluble in acetonitrile, acetone, chloroform | [form ]
Fine Crystalline Powder | [color ]
Orange to rust-brown | [Water Solubility ]
insoluble | [Detection Methods]
SPECTRA CHEMICAL ANALYSIS | [InChI]
InChI=1S/2C2H3N.2ClH.Pd/c2*1-2-3;;;/h2*1H3;2*1H;/q;;;;+2/p-2 | [InChIKey]
RBYGDVHOECIAFC-UHFFFAOYSA-L | [SMILES]
C(#N)C.C(#N)C.[Pd](Cl)Cl | [CAS DataBase Reference]
14592-56-4(CAS DataBase Reference) |
| Safety Data | Back Directory | [Symbol(GHS) ]
GHS06 | [Signal word ]
Danger | [Hazard statements ]
H301+H311+H331 | [Precautionary statements ]
P280-P301+P310+P330-P302+P352+P312-P304+P340+P311 | [Hazard Codes ]
T,Xn | [Risk Statements ]
R23/24/25:Toxic by inhalation, in contact with skin and if swallowed .
R36/37/38:Irritating to eyes, respiratory system and skin .
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed . | [Safety Statements ]
S16:Keep away from sources of ignition-No smoking .
S27:Take off immediately all contaminated clothing .
S36/37:Wear suitable protective clothing and gloves .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S36:Wear suitable protective clothing .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . | [RIDADR ]
UN 3077 9/PG 3
| [WGK Germany ]
3
| [TSCA ]
No | [HazardClass ]
6.1 | [PackingGroup ]
III | [HS Code ]
28439090 | [Storage Class]
6.1C - Combustible acute toxic Cat.3
toxic compounds or compounds which causing chronic effects | [Hazard Classifications]
Acute Tox. 3 Dermal
Acute Tox. 3 Inhalation
Acute Tox. 3 Oral |
| Questions And Answer | Back Directory | [Reaction]
- Catalyst for the cyclization of δ-acetylenic carboxylic acids to butenolides.
- Catalyst for the aza-Michael reaction of carbamates with enones.
- Catalyst for the rearrangement of allylic imidates to allylic amides.
- Catalyst for the Nazarov cyclization of α-alkoxy dienones.
- Catalyst for the diamination of conjugated dienes.
- Three component Michael addition, cyclization, cross-coupling reaction.
- C-H activation of indoles.
- Catalyst used for the direct C-H arylation of isoxazoles at the 5 position.
|
| Hazard Information | Back Directory | [Chemical Properties]
dark yellow powder | [Physical properties]
Bis(acetonitrile)dichloropalladium(II) is a yellow-brown solid that is soluble in organic solvents. It is a reagent and a catalyst for reactions that require soluble Pd(II).The compound is similar to bis(benzonitrile)palladium dichloride. | [Uses]
suzuki reaction | [Application]
Synthesis of Oxindoles
To a dried screw-cap vial is added anilide (0.3 mmol), AgOCOCF3 (132.5 mg, 0.6 mmol), Bis(acetonitrile)dichloropalladium(II)
(3.5 mg, 0.015 mmol) and chlorobenzene. The reaction mixture is stirred
at 100-120 °C for 3-12 h in a pre-heated oil bath. After cooling to
room temperature, the reaction is diluted with EtOAc and filtered with a
glass filter. The filtrate is washed with 5% aqueous NaHCO3 and brine. The extract is dried over MgSO4 and concentrated in vacuo. The crude is purified by preparative TLC. | [Preparation]
Bis(acetonitrile)palladium dichloride is prepared by reacting two acetonitrile ligands and palladium(II) chloride.
| [General Description]
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Find details here. | [reaction suitability]
core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst |
|
| Company Name: |
J & K SCIENTIFIC LTD.
|
| Telephone: |
18210857532 18210857532 |
| Website: |
https://www.jkchemical.com |
| Company Name: |
Alfa Aesar
|
| Telephone: |
400-6106006 |
| Website: |
http://chemicals.thermofisher.cn |
| Company Name: |
Energy Chemical
|
| Telephone: |
400-0056266 |
| Website: |
www.energy-chemical.com |
| Company Name: |
Jia Xing Isenchem Co.,Ltd
|
| Telephone: |
0573-85285100 18627885956 |
| Website: |
https://www.chemicalbook.com/ShowSupplierProductsList14265/0_EN.htm |
|