| Identification | More | [Name]
Bis(tri-tert-butylphosphine)palladium(0) | [CAS]
53199-31-8 | [Synonyms]
BIS(TRI-T-BUTYLPHOSPHINE)PALLADIUM(0)
BIS(TRI-TERT-BUTYLPHOSPHINE)PALLADIUM
BIS(TRI-TERT-BUTYLPHOSPHINE)PALLADIUM (0)
Bis(tri-t-butylphosphine)palladium,
Bis(tri-tert-butylphosphin)palladium(0)
Bis(tri-t-butylphosphine)palladium(0),98%
Bis(tri-t-butyl)phosphino Pd0
Bis(tri-tert-butylphosphine)palladium(0), Pd 20.9%
Bis(tri-tert-butylphosphine)palladium (0) Reasonably stable for packaging and transfer.
Bis(tri-tert-butylphosphine)palladium (0), (Pd-116) Ampouled under argon | [EINECS(EC#)]
640-284-9 | [Molecular Formula]
C24H54P2Pd | [MDL Number]
MFCD03094580 | [Molecular Weight]
511.05 | [MOL File]
53199-31-8.mol |
| Chemical Properties | Back Directory | [Appearance]
Off white crystalline solid | [Melting point ]
>300 °C | [storage temp. ]
Freezer | [form ]
Crystals | [color ]
Off-white to orange-brown | [Water Solubility ]
insoluble | [Sensitive ]
Light, Air & Moisture Sensitive | [InChIKey]
XULQKWNZCKOVSU-UHFFFAOYSA-P | [CAS DataBase Reference]
53199-31-8(CAS DataBase Reference) | [Storage Precautions]
Store under nitrogen |
| Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S24/25:Avoid contact with skin and eyes . | [WGK Germany ]
3 | [TSCA ]
No | [HS Code ]
28439000 |
| Hazard Information | Back Directory | [Chemical Properties]
Off white crystalline solid | [Uses]
Catalyst for Suzuki coupling on a multisubstituted sp 3 -carbon (eq. 1) Catalyst for Stille coupling reaction of aryl chlorides 2 (eq. 2) Catalyst for Negishi coupling reaction 3 (eq. 3) Catalyst for Heck coupling to form tetrasubstituted olefins 4 (eq. 4) Catalyst for Buchwald-Hartwig amination of aryl halide 5 (eq. 5) Catalyst for carbonylation of aryl halides with carbamoylsilanes 6 (eq. 6) t -Bu 3 P) 2 catalyst. | [General Description]
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Find details here. |
| Questions And Answer | Back Directory | [Reaction]
- Introduced as an easier to handle Pd/P(t-Bu)3-based catalyst for the Negishi cross-coupling of aryl/vinyl chlorides.
- A versatile catalyst for the cross-coupling of aryl and vinyl chlorides.
- Catalyst for the amination of aryl chlorides and bromides using aqueous hydroxide bases.
- Useful catalyst for the cross-coupling of heteroaromatic carboxylic acids.
- Pd-catalyzed Newnan-Kwart rearrangement of O-aryl thiocarbamates.
- Cross-coupling of silanolates and halides.
- Elimination/isomerization of enol triflates derived from β-ketoesters.
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