ChemicalBook--->CAS DataBase List--->286-62-4

286-62-4

286-62-4 Structure

286-62-4 Structure
IdentificationMore
[Name]

CYCLOOCTENE OXIDE
[CAS]

286-62-4
[Synonyms]

1,2-EPOXYCYCLOOCTANE
2-OXABICYCLO(6.1.0)NONANE
9-OXABICYCLO[6.1.0]NONANE
CYCLOOCTANE EPOXIDE
CYCLOOCTENE OXIDE
EPOXYCYCLOOCTANE
Cyclooctane, 1,2-epoxy-
Cyclooctane,1,2-epoxy-
Cycloocteneepoxide
Cyclooctenoxid
Epoxycyclooctane~2-Oxabicyclo[6.1.0]nonane
Cyclooctene oxide, GC 99%
1,2-EPOXYCYCLOOCTANE 97+%
9-Oxabicyclo[6.1.0]nonane, Epoxycyclooctane
[EINECS(EC#)]

206-010-3
[Molecular Formula]

C8H14O
[MDL Number]

MFCD00005164
[Molecular Weight]

126.2
[MOL File]

286-62-4.mol
Chemical PropertiesBack Directory
[Appearance]

COLOURLESS TO WHITE ADHERING CRYSTALS OR CHUNKS
[Melting point ]

53-56 °C(lit.)
[Boiling point ]

55 °C5 mm Hg(lit.)
[density ]

0.9090 (rough estimate)
[refractive index ]

1.4540 (estimate)
[Fp ]

133 °F
[storage temp. ]

2-8°C
[BRN ]

103543
[CAS DataBase Reference]

286-62-4(CAS DataBase Reference)
Safety DataBack Directory
[Hazard Codes ]

Xn
[Risk Statements ]

R22:Harmful if swallowed.
R36/38:Irritating to eyes and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S37/39:Wear suitable gloves and eye/face protection .
[RIDADR ]

UN 1325 4.1/PG 3
[WGK Germany ]

2
[F ]

10-21
[HazardClass ]

4.1
[PackingGroup ]

III
[HS Code ]

29109000
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Diethyl ether-->Magnesium sulfate-->Sodium acetate-->Peroxyacetic acid-->CYCLOOCTENE-->2-methyl-1-phenyl-2-propyl hydroperoxide-->1,2-Diphenylethane-->2-Methyl-1-phenyl-2-propanol
[Preparation Products]

octanedial-->1-Pentalenecarbonyl chloride, octahydro-, (1alpha,3abeta,6abeta)- (9CI)
Hazard InformationBack Directory
[Chemical Properties]

COLOURLESS TO WHITE ADHERING CRYSTALS OR CHUNKS
[Synthesis Reference(s)]

The Journal of Organic Chemistry, 43, p. 1689, 1978 DOI: 10.1021/jo00403a015
Tetrahedron Letters, 27, p. 2617, 1986 DOI: 10.1016/S0040-4039(00)84599-2
[Purification Methods]

It can be distilled in vacuum, and the solidified distillate can be sublimed in vacuum below 50o. It has a characteristic odour. [IR: Cope et al. J Am Chem Soc 74 5884 1952, cf trans-isomer: Cope et al. J Am Chem Soc 79 3905 1957, Reppe et al. Justus Liebigs Ann Chem 560 1 1948].
Spectrum DetailBack Directory
[Spectrum Detail]

CYCLOOCTENE OXIDE(286-62-4)MS
CYCLOOCTENE OXIDE(286-62-4)1HNMR
CYCLOOCTENE OXIDE(286-62-4)13CNMR
CYCLOOCTENE OXIDE(286-62-4)Raman
CYCLOOCTENE OXIDE(286-62-4)FT-IR
CYCLOOCTENE OXIDE(286-62-4)IR
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Cyclooctene oxide, 99%(286-62-4)
[Alfa Aesar]

Cyclooctene oxide, 99%(286-62-4)
[Sigma Aldrich]

286-62-4(sigmaaldrich)
[TCI AMERICA]

1,2-Epoxycyclooctane,>97.0%(GC)(286-62-4)
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