| Identification | More | [Name]
ETHYL ALPHA-BROMOPHENYLACETATE | [CAS]
2882-19-1 | [Synonyms]
ETHYL 2-(2-BROMOPHENYL)ACETATE
ETHYL 2-BROMOPHENYLACETATE
ETHYL A-BROMOPHENYLACETATE
ETHYL ALPHA-BROMOPHENYLACETATE
Benzeneacetic acid, alpha-bromo-, ethyl ester
benzeneaceticacid,.alpha.-bromo-,ethyl
benzeneaceticacid,.alpha.-bromo-,ethylester
benzeneaceticacid,.alpha.-bromo-,ethylester(asimpurity)
Ethyl bromo(phenyl)acetate
Ethyl 2-bromo-2-phenylacetate
a-Bromophenylacetic acid ethyl ester
ALPHA-BROMOPHENYLACETIC ACID ETHYL ESTER
à-bromophenylacetic acid ethyl ester
ethyl à-bromophenylacetate
Ethyl ɑ-bromophenylacetate, 97%
Bromophenylacetic acid ethyl ester
Phenylbromoacetic acid ethyl ester
α-Bromobenzeneacetic acid ethyl ester
α-Bromophenylacetic acid ethyl ester | [EINECS(EC#)]
220-735-2 | [Molecular Formula]
C10H11BrO2 | [MDL Number]
MFCD00013536 | [Molecular Weight]
243.1 | [MOL File]
2882-19-1.mol |
| Chemical Properties | Back Directory | [Boiling point ]
89-92 °C/0.9 mmHg (lit.) | [density ]
1.389 g/mL at 25 °C(lit.)
| [refractive index ]
n20/D >1.5390(lit.)
| [Fp ]
>230 °F
| [storage temp. ]
Inert atmosphere,2-8°C | [form ]
Liquid | [color ]
Clear colorless to yellow | [Water Solubility ]
Not miscible or difficult to mix in water. | [Sensitive ]
Moisture Sensitive | [InChI]
1S/C10H11BrO2/c1-2-13-10(12)9(11)8-6-4-3-5-7-8/h3-7,9H,2H2,1H3 | [InChIKey]
BKTKLDMYHTUESO-UHFFFAOYSA-N | [SMILES]
CCOC(=O)C(Br)c1ccccc1 | [CAS DataBase Reference]
2882-19-1(CAS DataBase Reference) | [EPA Substance Registry System]
Ethyl .alpha.-bromophenylacetate (2882-19-1) |
| Safety Data | Back Directory | [Hazard Codes ]
C | [Risk Statements ]
R34:Causes burns. | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) . | [RIDADR ]
UN 3265 8/PG 2
| [WGK Germany ]
3
| [HazardClass ]
8 | [PackingGroup ]
III | [HS Code ]
29163990 | [Storage Class]
8A - Combustible corrosive hazardous materials | [Hazard Classifications]
Eye Dam. 1
Skin Corr. 1B |
| Hazard Information | Back Directory | [Uses]
ETHYL ALPHA-BROMOPHENYLACETATE is used as an alkyl halide initiator in controlled/living radical polymerization of styrene and methyl methacrylate.
| [Application]
Ethyl α-bromophenylacetate (EBPA) may be used to synthesize α-ethoxycarbonyl-N,α-diphenylnitrone.
EBPA may be used as an initiator for the following:
polymerization of dimethyl(methacryloyloxymethyl) phosphonate
polymerization of methyl methacrylate (MMA)
polymerization of trimethylolpropane triacrylate(TMPTA) | [Synthesis Reference(s)]
Tetrahedron Letters, 13, p. 4067, 1972 DOI: 10.1016/S0040-4039(01)94239-X | [Precautions]
Moisture sensitive. Store away from oxidizing agents, air and water/moisture. Keep the container tightly closed and place it in a cool, dry and well ventilated condition. Store under inert gas.? |
|
| Company Name: |
J & K SCIENTIFIC LTD.
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| Telephone: |
18210857532 18210857532 |
| Website: |
https://www.jkchemical.com |
| Company Name: |
Alfa Aesar
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400-6106006 |
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http://chemicals.thermofisher.cn |
| Company Name: |
Energy Chemical
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400-0056266 |
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www.energy-chemical.com |
| Company Name: |
Shanghai Ennopharm Co., Ltd.
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| Telephone: |
+86 (21) 6435-5022 |
| Website: |
www.chemicalbook.com/ShowSupplierProductsList13640/0_EN.htm |
| Company Name: |
Sigma-Aldrich
|
| Telephone: |
021-61415566 800-8193336 |
| Website: |
https://www.sigmaaldrich.cn |
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