ChemicalBook--->CAS DataBase List--->2946-61-4

2946-61-4

2946-61-4 Structure

2946-61-4 Structure
IdentificationMore
[Name]

DIMETHYL PHENYLPHOSPHONITE
[CAS]

2946-61-4
[Synonyms]

DIMETHOXYPHENYLPHOSPHINE
DIMETHYL PHENYLPHOSPHONITE
PHENYLDIMETHOXYPHOSPHINE
PHENYLPHOSPHOROUS ACID DIMETHYL ESTER
Phosphonous acid, phenyl-, dimethyl ester
Phosphorus, dimethoxy phenyl
Phenylphosphonous acid dimethyl ester
Dimethyl phenylphosphinite
Phenyldimethoxyphosphine,98%
Dimethoxyphenylphosphane
[EINECS(EC#)]

220-960-6
[Molecular Formula]

C8H11O2P
[MDL Number]

MFCD00008352
[Molecular Weight]

170.15
[MOL File]

2946-61-4.mol
Chemical PropertiesBack Directory
[Appearance]

clear colorless liquid
[Boiling point ]

77-79°C 7mm
[density ]

1.072 g/mL at 25 °C(lit.)
[refractive index ]

n20/D 1.529(lit.)
[Fp ]

>230 °F
[storage temp. ]

0-6°C
[form ]

liquid
[color ]

colorless
[Specific Gravity]

1.072
[Water Solubility ]

Miscible with alcohol. Immiscible with water.
[Sensitive ]

Air Sensitive
[BRN ]

1073018
[InChI]

InChI=1S/C8H11O2P/c1-9-11(10-2)8-6-4-3-5-7-8/h3-7H,1-2H3
[InChIKey]

LMZLQYYLELWCCW-UHFFFAOYSA-N
[SMILES]

C1=CC=C(P(OC)OC)C=C1
[CAS DataBase Reference]

2946-61-4(CAS DataBase Reference)
Safety DataBack Directory
[Hazard Codes ]

C
[Risk Statements ]

R34:Causes burns.
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
[RIDADR ]

UN 1760 8/PG 2
[WGK Germany ]

3
[HS Code ]

2931.90.6000
[HazardClass ]

8
[PackingGroup ]

II
Hazard InformationBack Directory
[Chemical Properties]

clear colorless liquid
[Uses]

Dimethyl phenylphosphonite is used in the preparation of phenyl-phosphonic acid dimethyl ester. It is used as a precursor for the preparation of dinitrosyltris(dimethyl phenylphosphonite)manganese(I) tetrafluoroborate.
[reaction suitability]

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
Spectrum DetailBack Directory
[Spectrum Detail]

DIMETHYL PHENYLPHOSPHONITE(2946-61-4)MS
DIMETHYL PHENYLPHOSPHONITE(2946-61-4)1HNMR
DIMETHYL PHENYLPHOSPHONITE(2946-61-4)13CNMR
DIMETHYL PHENYLPHOSPHONITE(2946-61-4)IR1
DIMETHYL PHENYLPHOSPHONITE(2946-61-4)Raman
Well-known Reagent Company Product InformationBack Directory
[Alfa Aesar]

Dimethyl phenylphosphonite, 98%(2946-61-4)
[Sigma Aldrich]

2946-61-4(sigmaaldrich)
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