| Identification | More | [Name]
4-Bromo-4'-hydroxybiphenyl | [CAS]
29558-77-8 | [Synonyms]
4-(4-BROMOPHENYL)PHENOL
4-(4-BROMPHENYL)-PHENOL
4-BROMO-4'-HYDROXYBIPHENYL
4'-BROMOBIPHENYL-4-OL
4-HYDROXY-4'-BROMOBIPHENYL
4'-Bromo-(1,1'-biphenyl)-4-ol
4-hydroxyl-4’-bromobiphenyl | [EINECS(EC#)]
608-376-3 | [Molecular Formula]
C12H9BrO | [MDL Number]
MFCD00059076 | [Molecular Weight]
249.1 | [MOL File]
29558-77-8.mol |
| Chemical Properties | Back Directory | [Appearance]
White or cream powder | [Melting point ]
164-166 °C(lit.)
| [Boiling point ]
355.5±17.0 °C(Predicted) | [density ]
1.4188 (rough estimate) | [refractive index ]
1.5130 (estimate) | [storage temp. ]
Sealed in dry,Room Temperature | [pka]
9.70±0.15(Predicted) | [Water Solubility ]
Soluble in water (partly), and methanol. | [CAS DataBase Reference]
29558-77-8(CAS DataBase Reference) |
| Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S37/39:Wear suitable gloves and eye/face protection . | [WGK Germany ]
3
| [HS Code ]
29081990 |
| Hazard Information | Back Directory | [Chemical Properties]
White or cream powder | [Uses]
A biphenyl starting material. 4?-Bromo-(1,1?-biphenyl)-4-ol is a useful intermediate. Vinylation of 4-bromo-4?-hydroxybiphenyl and ethyl acrylate using Pd (OAc) 2/PPh 3 catalyst was studied. Ethyl 4-(4?-hydroxyphenyl) cinnamate was formed as the vinylation product, while, 4-hydroxybiphenyl and ethyl cinnamate were formed as side products. Preparation of 4-cyano-4'-hydroxybiphenyl This was prepared from 4-bromo-4'-benzenesulphonyloxybiphenyl by first hydrolysing it to 4-bromo-4-hydroxybiphenyl using sodium hydroxide dissolved in a mixture of water and dioxan. The syntheses of the Nanocomposite dendrimers based on cyclic phosphazene cores: Amorphous materials, were accomplished by following a modified literature procedure by reacting phosphonitrilic chloride trimer with 4-bromophenol or 4-bromo-4?-hydroxybiphenyl, respectively, in the presence of K 2 CO 3 in tetrahydrofuran (THF). |
|
|