ChemicalBook--->CAS DataBase List--->29558-77-8

29558-77-8

29558-77-8 Structure

29558-77-8 Structure
IdentificationMore
[Name]

4-Bromo-4'-hydroxybiphenyl
[CAS]

29558-77-8
[Synonyms]

4-(4-BROMOPHENYL)PHENOL
4-(4-BROMPHENYL)-PHENOL
4-BROMO-4'-HYDROXYBIPHENYL
4'-BROMOBIPHENYL-4-OL
4-HYDROXY-4'-BROMOBIPHENYL
4'-Bromo-(1,1'-biphenyl)-4-ol
4-hydroxyl-4’-bromobiphenyl
[EINECS(EC#)]

608-376-3
[Molecular Formula]

C12H9BrO
[MDL Number]

MFCD00059076
[Molecular Weight]

249.1
[MOL File]

29558-77-8.mol
Chemical PropertiesBack Directory
[Appearance]

White or cream powder
[Melting point ]

164-166 °C(lit.)
[Boiling point ]

355.5±17.0 °C(Predicted)
[density ]

1.4188 (rough estimate)
[refractive index ]

1.5130 (estimate)
[storage temp. ]

Sealed in dry,Room Temperature
[form ]

powder to crystal
[pka]

9.70±0.15(Predicted)
[color ]

White to Almost white
[Water Solubility ]

Soluble in water (partly), and methanol.
[InChI]

InChI=1S/C12H9BrO/c13-11-5-1-9(2-6-11)10-3-7-12(14)8-4-10/h1-8,14H
[InChIKey]

ARUBXNBYMCVENE-UHFFFAOYSA-N
[SMILES]

C1(C2=CC=C(Br)C=C2)=CC=C(O)C=C1
[CAS DataBase Reference]

29558-77-8(CAS DataBase Reference)
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H315-H319-H335
[Precautionary statements ]

P280a-P304+P340-P405-P501a-P261-P305+P351+P338
[Hazard Codes ]

Xi
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S37/39:Wear suitable gloves and eye/face protection .
[WGK Germany ]

3
[HS Code ]

29081990
Hazard InformationBack Directory
[Chemical Properties]

White or cream powder
[Uses]

A biphenyl starting material. 4?-Bromo-(1,1?-biphenyl)-4-ol is a useful intermediate. Vinylation of 4-bromo-4?-hydroxybiphenyl and ethyl acrylate using Pd (OAc) 2/PPh 3 catalyst was studied. Ethyl 4-(4?-hydroxyphenyl) cinnamate was formed as the vinylation product, while, 4-hydroxybiphenyl and ethyl cinnamate were formed as side products. Preparation of 4-cyano-4'-hydroxybiphenyl This was prepared from 4-bromo-4'-benzenesulphonyloxybiphenyl by first hydrolysing it to 4-bromo-4-hydroxybiphenyl using sodium hydroxide dissolved in a mixture of water and dioxan. The syntheses of the Nanocomposite dendrimers based on cyclic phosphazene cores: Amorphous materials, were accomplished by following a modified literature procedure by reacting phosphonitrilic chloride trimer with 4-bromophenol or 4-bromo-4?-hydroxybiphenyl, respectively, in the presence of K 2 CO 3 in tetrahydrofuran (THF).
Spectrum DetailBack Directory
[Spectrum Detail]

4-Bromo-4'-hydroxybiphenyl(29558-77-8)MS
4-Bromo-4'-hydroxybiphenyl(29558-77-8)1HNMR
4-Bromo-4'-hydroxybiphenyl(29558-77-8)13CNMR
4-Bromo-4'-hydroxybiphenyl(29558-77-8)IR1
4-Bromo-4'-hydroxybiphenyl(29558-77-8)IR2
4-Bromo-4'-hydroxybiphenyl(29558-77-8)Raman
Well-known Reagent Company Product InformationBack Directory
[Alfa Aesar]

4-Bromo-4'-hydroxybiphenyl, 98%(29558-77-8)
[Sigma Aldrich]

29558-77-8(sigmaaldrich)
[TCI AMERICA]

4-Bromo-4'-hydroxybiphenyl,>99.0%(GC)(29558-77-8)
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