| Identification | Back Directory | [Name]
MAGNESIUM BROMIDE DIETHYL ETHERATE | [CAS]
29858-07-9 | [Synonyms]
MGBR2 NOET2
MAGNESIUM BROMIDE ETHYL ETHERATE
MAGNESIUM BROMIDE DIETHYL ETHERATE
Magnesium, dibromo1,1-oxybisethane-
Magnesium bromide ethyl etherate,99%
MagnesiuM broMide ethyl etherate 99%
MagnesiuM broMide ethyl etherate, 99% 25GR
MagnesiuM broMide ethyl etherate, 99% 100GR | [EINECS(EC#)]
-0 | [Molecular Formula]
C4H10Br2MgO | [MDL Number]
MFCD00064500 | [MOL File]
29858-07-9.mol | [Molecular Weight]
258.23 |
| Chemical Properties | Back Directory | [Appearance]
off-white to to beige crystalline powder/chunks | [Fp ]
95 °F
| [storage temp. ]
Flammables area | [form ]
Crystalline Powder/Chunks | [color ]
Off-white to to beige | [Water Solubility ]
Hydrolyzes in water. | [Sensitive ]
Moisture Sensitive | [BRN ]
4937320 | [InChI]
1S/C4H10O.2BrH.Mg/c1-3-5-4-2;;;/h3-4H2,1-2H3;2*1H;/q;;;+2/p-2 | [InChIKey]
JGZKUKYUQJUUNE-UHFFFAOYSA-L | [SMILES]
Br[Mg]Br.CCOCC |
| Hazard Information | Back Directory | [Chemical Properties]
off-white to to beige crystalline powder/chunks | [Uses]
Lewis acid for catalysis of Diels-Alder reactions of homochiral 2-sulfinylmaleates with cyclopentadiene. | [Uses]
The magnesium bromide diethyl etherate (MgBr2· OEt2)-methyl sulfide (Me2S) system is useful for the mild and chemo-selective deprotection of p-methoxybenzyl (PMB) ether. Lewis acid for catalysis of Diels-Alder reactions of homochiral 2-sulfinylmaleates with cyclopentadiene. Magnesium bromide diethyl etherate is used in the synthesis of silicon-containing azole derivatives. |
| Safety Data | Back Directory | [Symbol(GHS) ]
GHS02 | [Signal word ]
Danger | [Hazard statements ]
H228 | [Precautionary statements ]
P210-P240-P241-P280-P370+P378 | [Hazard Codes ]
F | [Risk Statements ]
11 | [Safety Statements ]
16-27-28-33-36/37/39 | [RIDADR ]
UN 1325 4.1/PG 2
| [WGK Germany ]
3
| [F ]
10-21 | [HazardClass ]
4.1 | [PackingGroup ]
III | [HS Code ]
28275900 | [Storage Class]
4.3 - Hazardous materials which set free flammable gases upon contact with water | [Hazard Classifications]
Flam. Sol. 1
Water-react 2 |
|
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