| Identification | Back Directory | [Name]
ETHYNYLMAGNESIUM CHLORIDE | [CAS]
65032-27-1 | [Synonyms]
Ethynylchloromagnesium
ETHYNYLMAGNESIUM CHLORIDE
Ethynyl MagesiuM chloride
MagnesiuM,chloroethynyl- (9CI)
Ethynylmagnesium chloride solution
Ethynylmagnesium chloride [0.5M in THF]
Ethynylmagnesium chloride solution 0.5 in THF
EthynylMagnesiuM chloride solution 0.5 M in THF
Ethynylmagnesium chloride, 0.6M solution in THF/Toluene
Ethynylmagnesium chloride, 1.1M solution in THF/toluene
EthynylMagnesiuM chloride, 0.5 M solution in THF, SpcSeal
EthynylMagnesiuM chloride, 0.5 M solution in THF, J&KSeal
ETHYNYLMAGNESIUM CHLORIDE, 0.5M SOLUTION IN TETRAHYDROFURAN
Ethynylmagnesium chloride0.6M solution in THF/TolueneAcroSeal§3
Ethynylmagnesium chloride, 0.6M solution in THF/Toluene, AcroSeal
EthynylMagnesiuM chloride, 0.6 M solution in THF/toluene, J&KSeal
EthynylMagnesiuM chloride, 0.6M solution in THF/Toluene, AcroSeal 800ML | [Molecular Formula]
C2HClMg | [MDL Number]
MFCD00075343 | [MOL File]
65032-27-1.mol | [Molecular Weight]
84.79 |
| Chemical Properties | Back Directory | [Appearance]
clear brown to dark brown solution | [density ]
0.921 g/mL at 25 °C
| [Fp ]
−17 °F
| [storage temp. ]
water-free area | [form ]
Liquid | [color ]
Clear brown to dark brown | [InChI]
1S/C2H.ClH.Mg/c1-2;;/h1H;1H;/q;;+1/p-1 | [InChIKey]
YEWNLGTVYUADOR-UHFFFAOYSA-M | [SMILES]
Cl[Mg]C#C |
| Hazard Information | Back Directory | [Chemical Properties]
clear brown to dark brown solution | [Uses]
Ethynylmagnesium chloride solution can be used:
- To synthesize 1-ethynyldeoxyribose derivatives which can further undergo Sonogashira coupling with various aryl, heteroaryl, and metallocenyl derivatives.
- In one of the key synthetic steps of substituted naphthostyrils.
- In the preparation of propargylic ester precursor for the synthesis of 1,3-dienylphosphonates.
| [reaction suitability]
reaction type: Grignard Reaction |
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