ChemicalBook--->CAS DataBase List--->3012-65-5

3012-65-5

3012-65-5 Structure

3012-65-5 Structure
IdentificationMore
[Name]

Ammonium citrate dibasic
[CAS]

3012-65-5
[Synonyms]

2-hydroxy-1,2,3-propanetricarboxylic acid triammonium salt
AMMONIUM CITRATE
AMMONIUM CITRATE, DIBASIC
AMMONIUM CITRATE TRIBASIC
AMMONIUM HYDROGENCITRATE
CITRIC ACID AMMONIUM SALT
CITRIC ACID, AMMONIUM SALT, DIBASIC
CITRIC ACID, DIAMMONIUM
CITRIC ACID, DIAMMONIUM, DIBASIC
CITRIC ACID DIAMMONIUM SALT
CITRIC ACID TRIAMMONIUM SALT
DI-AMMONIUM HYDROGEN CITRATE
TRI-AMMONIUM CITRATE
1,2,3-Propanetricarboxylicacid,2-hydroxy-,diammoniumsalt
2,3-propanetricarboxylicacid,2-hydroxy-diammoniumsalt
ammoniummonohydrogencitrate
diammoniumcitrate
diammoniumcitrate(secondary)
dibasicammoniumcitrate
diammonium hydrogen 2-hydroxypropane-1,2,3-tricarboxylate
[EINECS(EC#)]

222-394-5
[Molecular Formula]

C6H14N2O7
[MDL Number]

MFCD00013068
[Molecular Weight]

226.18
[MOL File]

3012-65-5.mol
Chemical PropertiesBack Directory
[Appearance]

Ammonium citrate (various forms) is a white powdery material with a slight ammonia-like odor.
[Melting point ]

185 °C (dec.)(lit.)
[Boiling point ]

100 °C(lit.)
[bulk density]

400-600kg/m3
[density ]

1.22 g/mL at 20 °C
[vapor density ]

1.8 (vs air)
[refractive index ]

1.4650 (estimate)
[storage temp. ]

Store at RT.
[solubility ]

H2O: 1 M at 20 °C, clear, colorless
[form ]

Solid
[color ]

White
[Odor]

Slight ammonia odor
[PH]

4.0-5.5 (25℃, 1M in H2O)
[PH Range]

5.2
[Stability:]

Stable.
[Water Solubility ]

Soluble in water. Slightiy soluble in alcohol.
[λmax]

λ: 260 nm Amax: ≤0.05
λ: 280 nm Amax: ≤0.03
[Merck ]

14,512
[BRN ]

4925760
[Cosmetics Ingredients Functions]

BUFFERING
CHELATING
[Cosmetic Ingredient Review (CIR)]

Ammonium citrate dibasic (3012-65-5)
[InChI]

1S/C6H8O7.2H3N/c7-3(8)1-6(13,5(11)12)2-4(9)10;;/h13H,1-2H2,(H,7,8)(H,9,10)(H,11,12);2*1H3
[InChIKey]

YXVFQADLFFNVDS-UHFFFAOYSA-N
[SMILES]

N.N.OC(=O)CC(O)(CC(O)=O)C(O)=O || N.N.OC(=O)CC(O)(CC(O)=O)C(O)=O
[LogP]

-2.840
[Uses]

Ammonium Citrate, Dibasic is a flavor enhancer and ph control agent. it is the diammonium salt of citric acid, being prepared by partially neutralizing citric acid with ammonia. it is used in nonal- coholic beverages and certain cheeses.
[CAS DataBase Reference]

3012-65-5(CAS DataBase Reference)
[EPA Substance Registry System]

3012-65-5(EPA Substance)
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H315-H319
[Precautionary statements ]

P264-P280-P302+P352-P305+P351+P338-P332+P313-P337+P313
[Hazard Codes ]

Xi
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
R36/37:Irritating to eyes and respiratory system .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
[RIDADR ]

UN 9087
[WGK Germany ]

3
[RTECS ]

GE7545000
[F ]

8
[TSCA ]

Yes
[REACH Registrations]

Active
[HazardClass ]

9
[HS Code ]

29212900
[Storage Class]

11 - Combustible Solids
[Hazard Classifications]

Eye Irrit. 2
Skin Irrit. 2
[Hazardous Substances Data]

3012-65-5(Hazardous Substances Data)
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Ammonia-->Citric acid
Hazard InformationBack Directory
[General Description]

Ammonium citrate is a white granular solid. AMMONIUM CITRATE, DIBASIC(3012-65-5) is soluble in water. The primary hazard is the threat to the environment. Immediate steps should be taken to limit its spread to the environment. AMMONIUM CITRATE, DIBASIC(3012-65-5) is used in pharmaceuticals, and in chemical analysis.
[Reactivity Profile]

Salts, basic, such as AMMONIUM CITRATE, are generally soluble in water. The resulting solutions contain moderate concentrations of hydroxide ions and have pH's greater than 7.0. They react as bases to neutralize acids. These neutralizations generate heat, but less or far less than is generated by neutralization of the bases in reactivity group 10 (Bases) and the neutralization of amines. They usually do not react as either oxidizing agents or reducing agents but such behavior is not impossible.
[Air & Water Reactions]

Water soluble.
[Health Hazard]

Inhalation causes respiratory irritation. Ingestion causes diarrhea. Contact with eyes causes mild irritation.
[Potential Exposure]

It is used to make pharmaceuticals; rust-proofing compounds and plasticizers; as a food additive; stabilizing agent.
[Fire Hazard]

Special Hazards of Combustion Products: Toxic ammonia gas may form in fire.
[First aid]

If this chemical gets into the eyes, remove any contact lenses at once and irrigate immediately for at least 15 minutes, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts the skin, remove contaminated clothing and wash immediately with soap and water. Seek medical attention immediately. If this chemical has been inhaled, remove from exposure, begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR if heart action has stopped. Transfer promptly to a medical facility. When this chemical has been swallowed, get medical attention. Give large quantities of water and induce vomiting. Do not make an unconscious person vomit.
[Shipping]

UN3077 Environmentally hazardous substances, solid, n.o.s., Hazard class: 9; Labels: 9-Miscellaneous hazardous material, Technical Name Required.
[Incompatibilities]

Contact with strong caustics causes the release of ammonia gas.
[Chemical Properties]

Ammonium citrate (various forms) is a white powdery material with a slight ammonia-like odor.
[Chemical Properties]

white crystalline powder
[Waste Disposal]

May be flushed to sewer with large volumes of water.
[Definition]

ChEBI: A citrate salt in which two of the three carboxy groups are deprotonated and associated with ammonium ions as counter-cations.
Spectrum DetailBack Directory
[Spectrum Detail]

Ammonium citrate dibasic(3012-65-5)MS
Ammonium citrate dibasic(3012-65-5)1HNMR
Ammonium citrate dibasic(3012-65-5)13CNMR
Ammonium citrate dibasic(3012-65-5)IR1
Ammonium citrate dibasic(3012-65-5)IR2
Ammonium citrate dibasic(3012-65-5)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Citric acid, diammonium salt(3012-65-5)
[Alfa Aesar]

Citric acid diammonium salt, ACS, 98.0-103.0%(3012-65-5)
[Sigma Aldrich]

3012-65-5(sigmaaldrich)
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