ChemicalBook--->CAS DataBase List--->325146-81-4

325146-81-4

325146-81-4 Structure

325146-81-4 Structure
IdentificationBack Directory
[Name]

Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II)
[CAS]

325146-81-4
[Synonyms]

Ru-BINAP
Ru(OAc)2[(R)-binap]
Diacetato[(R)-(+)-2,2'
-binaphthyl]ruthenium(II),Ru(OAc)2[(R)-binap].
Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II)
(R)-Ru(OAc)2(BINAP),Diacetato[(R)-(+)-2,2′-bis(diphenylphosphino)-1,1′binaphthyl]ruthenium(II)
Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) Ru(OAc)2[(R)-binap]
(OC-6-22)-Bis(acetato-κO,κO')[(1R)-[1,1'-binaphthalene]-2,2'-diylbis[diphenylphosphine-κP]]ruthenium
[Molecular Formula]

C48H38O4P2Ru
[MDL Number]

MFCD09753020
[MOL File]

325146-81-4.mol
[Molecular Weight]

841.83
Chemical PropertiesBack Directory
[Melting point ]

>100°C
[storage temp. ]

2-8°C
[form ]

Powder
[color ]

ocher to green
[Sensitive ]

air sensitive
[InChIKey]

XANQJWCSQJDBEA-UHFFFAOYSA-N
[SMILES]

CC1=O[Ru+2]23(O=C(C)[O-]2)(P(C2C=CC=CC=2)(C2C=CC=CC=2)C2=CC=C4C=CC=CC4=C2C2=C4C=CC=CC4=CC=C2P3(C2C=CC=CC=2)C2C=CC=CC=2)[O-]1
Hazard InformationBack Directory
[Chemical Properties]

Light yellow powder
[Uses]

(R)-Ru(OAc)2(BINAP) is a catalyst.
Safety DataBack Directory
[Symbol(GHS) ]


GHS07
[Signal word ]

Warning
[Hazard statements ]

H315-H319
[Precautionary statements ]

P264-P280-P302+P352-P337+P313-P305+P351+P338-P362+P364-P332+P313
[WGK Germany ]

3
[HS Code ]

28439000
Questions And AnswerBack Directory
[Reaction]

  1. Catalyst system that exhibits very high catalytic activity and enantioselectivity in the hydrogenation of a wide range of substrates.
  2. Catalyst used in the synthesis of β-amino acids by hydrogenation.
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