| Identification | Back Directory | [Name]
Diacetato[(R)-(+)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole] ruthenium(II) Ru(OAc)2[(R)-segphos] | [CAS]
944450-48-0 | [Synonyms]
(R)-Ru(OAc)2(SEGPHOS)
Diacetato[(R)-(+)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole] ruthenium(II) Ru(OAc)2[(R)-segphos]
Diacetato[(R)-(+)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II) Ru(OAc)2[(R)-segphos(R)] | [Molecular Formula]
C42H34O8P2Ru | [MDL Number]
MFCD09753024 | [MOL File]
944450-48-0.mol | [Molecular Weight]
831.76 |
| Chemical Properties | Back Directory | [Melting point ]
>100°C | [storage temp. ]
2-8°C | [form ]
Powder | [color ]
dark yellow | [Sensitive ]
air sensitive | [InChIKey]
OISNHBFITMBIMI-UHFFFAOYSA-N | [SMILES]
CC1=O[Ru+2]23(O=C(C)[O-]2)(P(C2C=CC=CC=2)(C2C=CC=CC=2)C2=CC=C4OCOC4=C2C2=C4OCOC4=CC=C2P3(C2C=CC=CC=2)C2C=CC=CC=2)[O-]1 |
| Questions And Answer | Back Directory | [Reaction]
- Highly active highly enantioselective catalyst for hydrogenation of functionalized ketones. The acetate salts are frequently used for hydrogenation of allyl alcohols, unsaturated carboxylic acids and reductive amination.
- Asymmetric hydrogenation of substituted allyl alcohols.
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